Issue 3, 1989

Heat of solution and electric conductivity of electrolytes in water–tetrahydrofuran mixtures

Abstract

Integral heats of solution of sodium perchlorate (NaClO4) in water–tetrahydrofuran (THF) mixtures from 0 to 100 mol% THF have been measured. The electric conductivity of NaClO4 solutions in binary solvents containing from 0 to 80 mol% THF have also been measured, as have the conductivities of solutions of sodium chloride (NaCl) and sodium iodide (NaI) in mixtures containing from 0 to 35 mol% THF. Molar electro-conductivities, Walden products and association equilibria constants have been determined. Taking into account ion-pair association, standard enthalpies of solution have been recalculated.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1989,85, 479-483

Heat of solution and electric conductivity of electrolytes in water–tetrahydrofuran mixtures

S. Taniewska-Osińska, Z. Kozłowski, B. Nowicka, A. Bald and A. Szejgis, J. Chem. Soc., Faraday Trans. 1, 1989, 85, 479 DOI: 10.1039/F19898500479

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