Issue 18, 1995
From the journal:

Journal of the Chemical Society, Dalton Transactions

Structural characterisation of solution species implicated in the rhodium-catalysed carbonylation of methanol by Rh K-edge X-ray absorption spectroscopy

Neil A. Cruise  and  John Evans  

Abstract

Rhodium K-edge extended X-ray absorption fine structure (EXAFS) analysis has shown that [{Rh(COMe)I3(CO)}2]2– exists in tetrahydrofuran solution at –20 °C, but fragments above 0 °C to [Rh(COMe)I3(CO)(solv)]–; when solv = MeOH, the solution structure shows a substantial trans influence (0.2 Å) on the Rh–I bond trans to the Rh–COMe group.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9950003089
Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 3089-3091

Permissions

Request permissions

Structural characterisation of solution species implicated in the rhodium-catalysed carbonylation of methanol by Rh K-edge X-ray absorption spectroscopy

N. A. Cruise and J. Evans, J. Chem. Soc., Dalton Trans., 1995, 3089 DOI: 10.1039/DT9950003089

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements