Issue 15, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Enthalpies of formation of alkali-metal hexachloro-zirconates and -hafnates

Peter Gelbman  and  Alan D. Westland  

Abstract

Enthalpies of reaction have been determined by solution calorimetry for the process (i) where M′= Na, K, or Cs 2 M′Cl(c)+ MCl4(c)→ M′2[MCl6](c)(i) and M = Zr or Hf. Heats of formation for the complexes, ΔHf⊖(298 K), have been calculated using mean values of ΔHf⊖ for MCl4 taken from the literature. The reaction is marginally more favourable when M = Hf but both ZrCl4 and HfCl4 are somewhat better acceptors of chloride ion than is NbCl4 and both are markedly better acceptors than SnCl4.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9750001598
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 1598-1601

Permissions

Request permissions

Enthalpies of formation of alkali-metal hexachloro-zirconates and -hafnates

P. Gelbman and A. D. Westland, J. Chem. Soc., Dalton Trans., 1975, 1598 DOI: 10.1039/DT9750001598

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements