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For the first time, we present the detailed synthesis, photophysical, electrochemical, host–guest and charge transport properties of spiro[fluorene-9,9′-xanthene] (SFX) and carbazole macrocycle SPS-NR-02. The electron and hole transport values measured using the space charge limited current (SCLC) method resulted in ambipolar charge transport with an electron to hole mobility ratio of 0.39.

Graphical abstract: Ambipolar macrocycle derived from spiro-xanthene and carbazole: synthesis, structure–property relationships, electronic properties and host–guest investigation

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