Enhanced charge transport properties of an LFP/C/graphite composite as a cathode material for aqueous rechargeable lithium batteries†
Abstract
Electrodes that offer quick ion transport, a large surface area, and excellent electrical conductivity support high performance aqueous rechargeable lithium batteries. LiFePO4 (LFP) nanoparticles have been successfully coated with carbon by a chemical sol–gel route, and assembled on graphite by an ultrasonication method to acquire LFP/C/graphite. This LFP/C/graphite composite exhibits exceptional electrochemical performance at various current densities (1C to 20C). LFP/C/graphite delivers better capacity that is higher than that of LFP/C particles and high stability after 60 cycles at a current density of 1C for aqueous rechargeable lithium batteries as a cathode material. The graphite serves as a good volume buffer in improving the lithium performance of LFP/C/graphite during the charge/discharge process. The LFP/C/graphite composite shows high rate capability at 20C that returned to the initial capacity at 1C after 25 cycles with coulombic efficiency of 97%. Therefore, this effort presents a super low-cost route to fabricate high performance cathode materials in aqueous rechargeable lithium batteries and other energy storage appliances.
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