Issue 2, 2024
From the journal:

Dalton Transactions

Post-synthetic molecular modifications based on Schiff base condensation reactions for designing functional paddlewheel diruthenium(ii,ii) complexes†

Chisa Itoh,ab   Haruka Yoshino, ORCID logo ab   Taku Kitayama,ab   Wataru Kosaka ORCID logo ab  and  Hitoshi Miyasaka ORCID logo *ab  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Arama-ki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan

b Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan
E-mail: miyasaka@imr.tohoku.ac.jp

Abstract

A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes ([RuII,II2]) was developed by utilizing Schiff base condensation reactions of formyl-substituted benzoate-bridged [RuII,II2] complexes with various aromatic monoamines under mild conditions. Cyclic voltammetry and DFT calculations revealed that the attached Schiff base groups significantly affected the electronic states of the resulting [RuII,II2] complexes.

Graphical abstract: Post-synthetic molecular modifications based on Schiff base condensation reactions for designing functional paddlewheel diruthenium(ii,ii) complexes

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Article information

DOI
https://doi.org/10.1039/D3DT03535B
Article type
Communication
Submitted
23 Oct 2023
Accepted
04 Dec 2023
First published
05 Dec 2023

Dalton Trans., 2024,53, 444-448

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Post-synthetic molecular modifications based on Schiff base condensation reactions for designing functional paddlewheel diruthenium(II,II) complexes

C. Itoh, H. Yoshino, T. Kitayama, W. Kosaka and H. Miyasaka, Dalton Trans., 2024, 53, 444 DOI: 10.1039/D3DT03535B

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