Issue 94, 2023
From the journal:

Chemical Communications

Reply to the ‘Comment on “CO2 as oxidant: an unusual light-assisted catalyst free oxidation of aldehydes to acids under mild conditions”’ by S. R. Khan, S. Saini, K. Naresh, A. Kumari, V. Aniya, P. K. Khatri, A. Ray and S. L. Jain, Chem. Commun., 2022, 58, 2208

Shafiur Rehman Khan,a   Sandhya Saini,ab   K. Naresh,c   Alka Kumari,c   Vineet Aniya,c   Praveen K Khatri,a   Anjan Ray ORCID logo d  and  Suman L Jain ORCID logo *a  

* Corresponding authors

a Chemical & Material Sciences Division, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India
E-mail: suman@iip.res.in
Tel: +911352525788

b Academy of Scientific and Innovative Research, Ghaziabad, India

c Process Engineering Technology Transfer Division, CSIR-Indian Institute of Chemical Technology, Hyderabad-500007, India

d Director, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India

Abstract

Our recent Communication (S. R. Khan et al., Chem. Commun., 2022, 58, 2208) suggested that CO2 can be used as a potential oxidant under light irradiation without using any catalyst for the oxidation of aldehydes to acids at room temperature. The Comment based on the published literature on the catalytic oxidation of aromatic aldehydes by CO2 and thermodynamical data argued on the realism of the experimental data.

Graphical abstract: Reply to the ‘Comment on “CO2 as oxidant: an unusual light-assisted catalyst free oxidation of aldehydes to acids under mild conditions”’ by S. R. Khan, S. Saini, K. Naresh, A. Kumari, V. Aniya, P. K. Khatri, A. Ray and S. L. Jain, Chem. Commun., 2022, 58, 2208

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Article information

DOI
https://doi.org/10.1039/D3CC04389D
Article type
Comment
Submitted
05 Sep 2023
Accepted
24 Oct 2023
First published
02 Nov 2023

Chem. Commun., 2023,59, 14036-14039

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Reply to the ‘Comment on “CO2 as oxidant: an unusual light-assisted catalyst free oxidation of aldehydes to acids under mild conditions”’ by S. R. Khan, S. Saini, K. Naresh, A. Kumari, V. Aniya, P. K. Khatri, A. Ray and S. L. Jain, Chem. Commun., 2022, 58, 2208

S. R. Khan, S. Saini, K. Naresh, A. Kumari, V. Aniya, P. K. Khatri, A. Ray and S. L. Jain, Chem. Commun., 2023, 59, 14036 DOI: 10.1039/D3CC04389D

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