Issue 14, 2019
From the journal:

Chemical Communications

Synthesis of a dimeric phosphine-stabilized phosphidogermanium(i)–amidogermanium(ii) derivative†

Muhammad Luthfi Bin Ismaila  and  Cheuk-Wai So ORCID logo *a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
E-mail: CWSo@ntu.edu.sg

Abstract

The synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)–amidogermanium(II) derivative is described. The reaction of amidinato phosphinoamidosilylene [L{(Ar)(Ph2P)N}Si:] (1, L = PhC(NtBu)2, Ar = 2,6-iPr2C6H3) with GeCl2·dioxane afforded a phosphine-stabilized phosphidogermanium(I) dimer moiety in a mixed-valent germanium(I,II) compound [:Ge(Cl){N(Ar)PPh2}(Ph2P)Ge:]2 (3). The mechanism for the formation of 3 is also studied and reported.

Graphical abstract: Synthesis of a dimeric phosphine-stabilized phosphidogermanium(i)–amidogermanium(ii) derivative

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Article information

DOI
https://doi.org/10.1039/C8CC09454C
Article type
Communication
Submitted
28 Nov 2018
Accepted
16 Jan 2019
First published
17 Jan 2019

Chem. Commun., 2019,55, 2074-2077

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Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)–amidogermanium(II) derivative

M. L. Bin Ismail and C. So, Chem. Commun., 2019, 55, 2074 DOI: 10.1039/C8CC09454C

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