Issue 10, 2015

Design of a robust superhydrophobic surface: thermodynamic and kinetic analysis

Abstract

The design of a robust superhydrophobic surface is a widely pursued topic. While many investigations are limited to applications with high impact velocities (for raindrops of the order of a few meters per second), the essence of robustness is yet to be analyzed for applications involving quasi-static liquid transfer. To achieve robustness with high impact velocities, the surface parameters (geometrical details, chemistry) have to be selected from a narrow range of permissible values, which often entail additional manufacturing costs. From the dual perspectives of thermodynamics and mechanics, we analyze the significance of robustness for quasi-static drop impact, and present the range of permissible surface characteristics. For surfaces with a Young's contact angle greater than 90° and square micropillar geometry, we show that robustness can be enforced when an intermediate wetting state (sagged state) impedes transition to a wetted state (Wenzel state). From the standpoint of mechanics, we use available scientific data to prove that a surface with any topology must withstand a pressure of 117 Pa to be robust. Finally, permissible values of surface characteristics are determined, which ensure robustness with thermodynamics (formation of a sagged state) and mechanics (withstanding 117 Pa).

Graphical abstract: Design of a robust superhydrophobic surface: thermodynamic and kinetic analysis

Associated articles

Supplementary files

Article information

Article type
Paper
Submitted
15 Dec 2014
Accepted
14 Jan 2015
First published
15 Jan 2015

Soft Matter, 2015,11, 1998-2007

Author version available

Design of a robust superhydrophobic surface: thermodynamic and kinetic analysis

A. Sarkar and A. Kietzig, Soft Matter, 2015, 11, 1998 DOI: 10.1039/C4SM02787F

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