A general method to form a C(SP3)–SCF3 bond via copper-mediated oxidative trifluoromethylthiolation of unactivated alkenes with stable nucleophilic AgSCF3 was developed. This protocol provides a direct and efficient access to a series of trifluoromethylthiolated allylic compounds with broad functional group tolerance.
K. Zhang, J. Liu and F. Qing, Chem. Commun., 2014, 50, 14157 DOI: 10.1039/C4CC07062C
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