José A. Souto, Willian Lewis and Robert A. Stockman
Chem. Commun., 2014,50, 12630-12632
DOI:
10.1039/C4CC05751A,
Communication
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate.