Issue 20, 1982

Carbon-13 contact solvent shifts in radical anion solutions. Mechanism of spin density transfer to solvent

Abstract

Radical anion solutions in tetrahydrofuran exhibit negative 13C contact solvent shifts for both types of carbon; the phenomenon is strongly cation dependent, indicating that spin delocalisation takes place in the ternary complex (ArH)˙M+(R2O)n through the mediation of the cation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1168-1169

Carbon-13 contact solvent shifts in radical anion solutions. Mechanism of spin density transfer to solvent

C. G. Screttas and M. Micha-Screttas, J. Chem. Soc., Chem. Commun., 1982, 1168 DOI: 10.1039/C39820001168

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