Chloroform reacts with phenol or diethylaniline under u.v. irradiation to give benzaldehydes in fairly good yields; the reaction may be an example of photochemical cleavage of the C–Cl bond of chloroform.
K. Hirao and O. Yonemitsu, J. Chem. Soc., Chem. Commun., 1972, 812b DOI: 10.1039/C3972000812B
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