A new and convenient procedure for synthesis of homoallylic alcohols in generally good to excellent yields has been developed. The bismuth-mediated Barbier-type allylation of aldehydes (aromatic, aliphatic, alicyclic and heterocyclic) with allyl bromide has been carried out smoothly in water in the presence of fluoride ions.
K. Smith, S. Lock, G. A. El-Hiti, M. Wada and N. Miyoshi, Org. Biomol. Chem., 2004, 2, 935 DOI: 10.1039/B400179F
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