For the first time gas phase radicals have been observed, using the matrix isolation method, during methanol oxidation on a Pt/SiO2 catalyst. A method of identifying the radicals generated is suggested, which utilises the differing resistance of MeO· and MeO·2 radicals to photolysis using the full light of a high pressure mercury lamp.
I. V. Malakhova and V. K. Ermolaev, Mendeleev Commun., 1998, 8, 83 DOI: 10.1070/MC1998v008n03ABEH000911
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...