A 3D-printed parallel reactor enabling four simultaneous reactions under high magnetic fields was developed. Using this platform, magnetic-field effects on the McMurry coupling were studied, shifting the trans/cis ratio from 50 : 50 to 71 : 29 at 10 T.
In this study, a mechanochemical adaptation of the McMurry coupling reaction was developed to synthesize ethylenes using Zn/TiCl4/Et3N as reagents.
This perspective summarizes recent advances in synthetic strategies and insights into ring contraction effects on ring-contracted porphyrin-related macrocycles, including subporphyrins, triphyrins(2.1.1), and calix[3]pyrroles.
A simple and practical decarboxylative carbonyl olefination is described. This procedure explores the application of α-halo NHPI redox-active esters in organic chemistry.
A sequential dehydrogenation reaction of activated diarylmethane derivatives mediated by copper(II) pivalate was developed, for preparation of electron-deficient tetraphenylethene (TPE) derivatives.