James Eills, Dmitry Budker, Silvia Cavagnero, Eduard Y. Chekmenev, Stuart J. Elliott, Sami Jannin, Anne Lesage, Jörg Matysik, Thomas Meersmann, Thomas Prisner, Jeffrey A. Reimer, Hanming Yang and Igor V. Koptyug

Chem. Rev., 2023, 123, 1417
DOI: 10.1021/acs.chemrev.2c00534

Rational Design of Persistent Phosphorus-Centered Singlet Tetraradicals and Their Use in Small-Molecule Activation

Edgar Zander, Jonas Bresien, Vladimir V. Zhivonitko, Johannes Fessler, Alexander Villinger, Dirk Michalik and Axel Schulz

J. Am. Chem. Soc., 2023, 145, 14484
DOI: 10.1021/jacs.3c03928

Unconventional Parahydrogen-Induced Hyperpolarization Effects in Chemistry and Catalysis: From Photoreactions to Enzymes

Andrey N. Pravdivtsev, Ben J. Tickner, Stefan Glöggler, Jan-Bernd Hövener, Gerd Buntkowsky, Simon B. Duckett, Clifford R. Bowers and Vladimir V. Zhivonitko

ACS Catal., 2025, 15, 6386
DOI: 10.1021/acscatal.4c07870

Molecular Fragmentation as a Strategy to Access Hyperpolarized Compounds from Para‐Hydrogen

Philip L. Norcott

ChemPhysChem, 2025, 26
DOI: 10.1002/cphc.202500105

Trapping Highly Reactive Metal(H)2(η2‐H2) Species to Form Trihydride Complexes and Clusters

Ben. J. Tickner, Adrian C. Whitwood, Claire Condon, Carlos Platas‐Iglesias and Simon B. Duckett

Eur J Inorg Chem, 2024, 27
DOI: 10.1002/ejic.202400397

Parahydrogen-based NMR signal amplification by reversible exchange (SABRE): Recent advances and applications

Oleg G. Salnikov, Dudari B. Burueva, Ivan V. Skovpin and Igor V. Koptyug

Mendeleev Communications, 2023, 33, 583
DOI: 10.1016/j.mencom.2023.09.001

StereoPHIP: Stereoselective Parahydrogen‐Induced Polarization

Mai T. Huynh, Emily Buchanan, Sara Chirayil, Adeniyi M. Adebesin and Zoltan Kovacs

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202311669

Rescaling NMR for a Larger Deployment in Drug Discovery: Hyperpolarization and Benchtop NMR as Potential Game‐Changers

Matthias Bütikofer, Gabriela R. Stadler and Felix Torres

Chemistry Methods, 2024
DOI: 10.1002/cmtd.202400009

Mechanistic Insights into Molecular Crystalline Organometallic Heterogeneous Catalysis through Parahydrogen-Based Nuclear Magnetic Resonance Studies

Matthew R. Gyton, Cameron G. Royle, Simon K. Beaumont, Simon B. Duckett and Andrew S. Weller

J. Am. Chem. Soc., 2023, 145, 2619
DOI: 10.1021/jacs.2c12642

Butynes Hydrogenation with Parahydrogen over Immobilized Iridium Catalyst

D. B. Burueva, I. V. Skovpin, L. M. Kovtunova, E. S. Kononenko, V. I. Bukhtiyarov and I. V. Koptyug

Kinet Catal, 2024, 65, 754
DOI: 10.1134/S0023158424602705

StereoPHIP: Stereoselective Parahydrogen‐Induced Polarization

Mai T. Huynh, Emily Buchanan, Sara Chirayil, Adeniyi M. Adebesin and Zoltan Kovacs

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202311669

Parahydrogen‐Induced Polarization of 14N Nuclei

Oleg G. Salnikov, Ivan A. Trofimov, Zachary T. Bender, Alexandra I. Trepakova, Jingyan Xu, Garrett L. Wibbels, Roman V. Shchepin, Igor V. Koptyug and Danila A. Barskiy

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202402877

Iron-Catalyzed Parahydrogen Induced Polarization

Daniel C. Najera and Alison R. Fout

J. Am. Chem. Soc., 2023, 145, 21086
DOI: 10.1021/jacs.3c07735

Analysis of chemical exchange in iridium N-heterocyclic carbene complexes using heteronuclear parahydrogen-enhanced NMR

Charbel D. Assaf, Xin Gui, Oleg G. Salnikov, Arne Brahms, Nikita V. Chukanov, Ivan V. Skovpin, Eduard Y. Chekmenev, Rainer Herges, Simon B. Duckett, Igor V. Koptyug, Kai Buckenmaier, Rainer Körber, Markus Plaumann, Alexander A. Auer, Jan-Bernd Hövener and Andrey N. Pravdivtsev

Commun Chem, 2024, 7
DOI: 10.1038/s42004-024-01376-z

Parahydrogen‐Induced Polarization of 14N Nuclei

Oleg G. Salnikov, Ivan A. Trofimov, Zachary T. Bender, Alexandra I. Trepakova, Jingyan Xu, Garrett L. Wibbels, Roman V. Shchepin, Igor V. Koptyug and Danila A. Barskiy

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202402877

Heteronuclear Parahydrogen‐Induced Hyperpolarization via Side Arm Hydrogenation

Oleg G. Salnikov, Nikita V. Chukanov, Andrey N. Pravdivtsev, Dudari B. Burueva, Sergey V. Sviyazov, Kolja Them, Jan‐Bernd Hövener and Igor V. Koptyug

ChemPhysChem, 2025, 26
DOI: 10.1002/cphc.202401119

High H2 Solubility of Perfluorocarbon Solvents and Their Use in Reversible Polarization Transfer from para-Hydrogen

Callum A. Gater, Orry J. Mayne, Benjamin G. Collins, Kieren J. Evans, Eleanor M. E. Storr, Adrian C. Whitwood, Daniel P. Watts, Ben J. Tickner and Simon B. Duckett

J. Phys. Chem. Lett., 2025, 16, 510
DOI: 10.1021/acs.jpclett.4c03190

Understanding Heterogeneous Catalytic Hydrogenation by Parahydrogen-Induced Polarization NMR Spectroscopy

Weiyu Wang, Qiang Wang, Jun Xu and Feng Deng

ACS Catal., 2023, 13, 3501
DOI: 10.1021/acscatal.2c05659

Metal-Mediated Catalytic Polarization Transfer from para Hydrogen to 3,5-Dihalogenated Pyridines

Ben. J. Tickner, Marcus Dennington, Benjamin G. Collins, Callum A. Gater, Theo F. N. Tanner, Adrian C. Whitwood, Peter J. Rayner, Daniel P. Watts and Simon B. Duckett

ACS Catal., 2024, 14, 994
DOI: 10.1021/acscatal.3c05378

Fluorescence Quenching for Determination of Catalyst Concentration in the Parahydrogen‐Induced Polarization Method SABRE

Till Houben, Felix Mysegaes, John Z. Myers, Nicolas Kempf, Charbel D. Assaf, Andrey N. Pravdivtsev, Kai Buckenmaier, Rainer Körber and Markus Plaumann

ChemPhotoChem, 2024, 8
DOI: 10.1002/cptc.202400106

Base-Promoted Iridium-Catalyzed Deuteration and C–H Bond Activation of N-Heterocycles

Ben J. Tickner, Claire Condon, Victoria Annis, Richard J. Gammons, Adrian C. Whitwood and Simon B. Duckett

J. Org. Chem., 2025, 90, 8080
DOI: 10.1021/acs.joc.5c00174

Benzoquinone Enhances Hyperpolarization of Surface Alcohols with Para-Hydrogen

Philip L. Norcott

J. Am. Chem. Soc., 2023, 145, 9970
DOI: 10.1021/jacs.3c01593

Tailoring rhodium-based metal-organic layers for parahydrogen-induced polarization: achieving 20% polarization of 1H in liquid phase

Jiawei Chen, Qi Zhang, Tao Chen, Zeyu Zheng, Yuhang Song, Huichong Liu, Ziqiao Chen, Jing Wang, Haoshang Wang, Huijun Sun, Xinchang Wang, Zhong Chen, Cheng Wang and Zhongqun Tian

National Science Review, 2024, 12
DOI: 10.1093/nsr/nwae406