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Organophotoelectrochemical silylation cyclization for the synthesis of silylated 3-CF3-2-oxindoles

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An unusualtrans-hydrosilylation of prochiral 1,1-disubstituted cyclopropenes revealing the different nature of asymmetric palladium and rhodium catalysis

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Radical cascade silylation/cyclization of 1,7-dienes to access silyl-substituted benzo[b]azepin-2-ones

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Allylsilane as a versatile handle in photoredox catalysis

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Fe-catalyzed B–H and Si–H insertion reactions of gem-dihaloalkanes

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Visible light catalyzed arylsilylation of alkenes to construct silicon-containing 1,1-diaryl moieties

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Electrifying synthesis of organosilicon compounds – from electrosynthesis to electrocatalysis

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Recent Advances in Molecule Synthesis Involving C-C Bond Cleavage of Ketoxime Esters

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Photoredox Defluorinative Silylation of α-Trifluoromethyl Arylalkenes Using Silacarboxylic Acids as Silyl Radical Precursors

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Photocatalytic Alkynylation of Hydrosilanes via Hydrogen Atom Transfer

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J. Org. Chem., 2023, 88, 11675
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Visible light harvesting alkyne hydrosilylation mediated by pincer platinum complexes

Laura Ibáñez-Ibáñez, Ariadna Lázaro, Carmen Mejuto, Margarita Crespo, Cristian Vicent, Laura Rodríguez and Jose A. Mata

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Visible-Light-Mediated Radical Silyl-Oximation of Activated Alkenes Using tert-Butyl Nitrite and Silanes

Stefanie Plöger and Armido Studer

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Photocatalyzed regioselective hydrosilylation for the divergent synthesis of geminal and vicinal borosilanes

Degong Kong, Muliang Zhang, Yuchao Zhang, Zhenyang Yu, Hui Cao and Jie Wu

Nat Commun, 2023, 14
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Photocatalytic C–Si Bond Formations Using Pentacoordinate Silylsilicates as Silyl Radical Precursors: Synthetic Tricks Using Old Reagents

Yumo Zhao, Yi Wan, Qiyang Yuan, Jinlian Wei and Yongqiang Zhang

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Programmatic functionalization of multihydrosilanes by hydrogen-atom-transfer photocatalysis

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Progress in Visible-Light Promoted Transformations of Organosilicon Compounds

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Chinese Journal of Organic Chemistry, 2023, 43, 2720
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Free radical-promoted direct C–H silylation of pyrrolo[2,3-d]pyrimidine derivatives with hydrosilanes

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Radical cascade cyclization for the green and simple synthesis of silylated indolo[2,1-a]isoquinoline derivatives via visible light-mediated Si–H bonds activation

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Ruthenium-Catalyzed Dehydrogenative Intermolecular O-H/Si-H/C-H Silylation: Synthesis of (E)-Alkenyl Silyl-Ether and Silyl-Ether Heterocycle

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Photoredox Synthesis of Silyl Ethers via Radical Coupling of Ketones with Hydrosilanes and [1, 2]‐Brook Rearrangement

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Silyl Radical Generation from Silylboronic Pinacol Esters through Substitution with Aminyl Radicals

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Organoelectrophotocatalytic C–H Silylation of Heteroarenes

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2‐Silylated Dihydroquinazolinone as a Photocatalytic Energy Transfer Enabled Radical Hydrosilylation Reagent

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Chemistry A European J, 2023, 29
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Cross-Electrophile Silylation of Aryl Carboxylic Esters with Hydrochlorosilanes by SiH-Directed and Cr-Catalyzed Couplings

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ACS Catal., 2023, 13, 12062
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Chloride‐Promoted Photoelectrochemical C—H Silylation of Heteroarenes†

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Rhodium-Catalyzed Chemodivergent Synthesis of Organosilicons Enabled by Controllable C–Si Bond Activation

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ACS Catal., 2023, 13, 8516
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Palladium Catalyzed Selective 1,4‐Dihydrosilylation of Alkynones

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Asian J Org Chem, 2024
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Electrochemical Decarboxylative Silylation of α,β-Unsaturated Carboxylic Acids

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Org. Lett., 2023, 25, 4562
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Ligand-modulated nickel-catalyzed regioselective silylalkylation of alkenes

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Nat Commun, 2023, 14
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Silylacylation of Alkenes through N-Heterocyclic Carbene Catalysis

Huiwei Xu, Wanyao Zheng, Wen-Deng Liu, Yuqiao Zhou, Luqing Lin and Jiannan Zhao

Org. Lett., 2023, 25, 5579
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Research Progress in Transition-Metal-Free C—Si Bond Formation

Qiyang Li, Haiyan Zhang and Wenbo Liu

Chinese Journal of Organic Chemistry, 2023, 43, 3470
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Sulfonamide as Photoinduced Hydrogen Atom Transfer Catalyst for Organophotoredox Hydrosilylation and Hydrogermylation of Activated Alkenes

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Research of Visible Light/Lewis Base Dual Catalytic Defluorinative Silylation of Trifluoromethyl-Substituted Alkenes

Jiajie Zhu, Yi Wan, Qiyang Yuan, Jinlian Wei and Yongqiang Zhang

Chinese Journal of Organic Chemistry, 2023, 43, 3623
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Recent Advances in Electrochemical Silylation

Junyong Wang, Na Li, Jie Ke and Chuan He

Chinese Journal of Organic Chemistry, 2024, 44, 927
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Lithium Triethylborohydride (LiHBEt3)-Promoted Hydrosilylation of Allenes to Prepare (E)-Allylsilanes

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J. Org. Chem., 2023, 88, 12257
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Electrochemical Silylation of Electron‐Deficient Heterocycles Using N‐Hydroxyphthalimide as HAT Catalyst

Cong Jiang, Yujie Liao, Heng Li, Sumin Zhang, Ping Liu and Peipei Sun

Adv Synth Catal, 2023, 365, 1205
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Photoredox Metal‐Free Synthesis of Unnatural β‐Silyl‐α‐Amino Acids via Hydrosilylation

Guo‐Qin Wang, Ting Wang, Yue Zhang, Yuan‐Xia Zhou, Dan Yang, Pan Han and Lin‐Hai Jing

Chemistry An Asian Journal, 2023, 18
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Recent Advances on C—H Functionalization via Oxidative Electrophotocatalysis

Aman Hasil, Rui Chang and Juntao Ye

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Organic derivatives of group 14 elements: General aspects of synthesis, modern trends, and application prospects

Elena N. Nikolaevskaya, Mikhail A. Syroeshkin and Mikhail P. Egorov

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General Concepts and Recent Advances in the Electrochemical Transformation of Chloro‐ and Hydrosilanes

Alexander D. Beck, Stefan Haufe and Siegfried R. Waldvogel

ChemElectroChem, 2023, 10
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Recent Progress in Synthesis of Organosilanes Driven by Visible-Light

Fengjuan Chen, Luo Liu, Zilu Zhang and Wei Zeng

Chinese Journal of Organic Chemistry, 2023, 43, 3454
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Photopromoted Free Radical Silylation of 2-Aryl-2H-indazoles with Silanes

Yunfei Tian, Luping Zheng, Dongyu Guo, Yuyan Miao, Lijun Li, Weijun Fu and Zejiang Li

J. Org. Chem., 2023, 88, 16671
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Electrocatalytic Annulation–Iodosulfonylation of Indole‐Tethered 1,6‐Enynes to Access Pyrrolo[1,2‐a]indoles

Ya‐Yu Yuan, Xi Chen, Ji‐Yun Wang, Sheng‐Hu Yan, Yu‐Ting Wang, Yue Zhang, Jian‐Wu Liu and Hang‐Dong Zuo

Eur J Org Chem, 2024, 27
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Copper‐Catalyzed Radical Silylarylation of Activated Alkenes: Preparation of β‐Silyl Amide‐Pharmaceutical Hybrids

Fei Chen, Shi‐Yu Liu, Xiao Li, Jia‐Lu Jia, Yi Li, Xiao‐Lan Lu, Lin Jia, Yang Zheng, Zhongfei Yan, Gang Li, Yunhe Lv and Haojie Rong

Adv Synth Catal, 2024, 366, 1325
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Visible-Light-Driven Silyl or Germyl Radical Generation via Si–C or Ge–C Bond Homolysis

Bi-Xiao Li, Hiroshi Ishida, Chao Wang and Masanobu Uchiyama

Org. Lett., 2023, 25, 1765
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