Scrutinising ligand pre-reduction: unlocking pathways to mono-, homo-, and heterobimetallic naphthyridine diimine complexes

Adrian Jenner, Laura Neumüller, Hartmut Schubert, Cäcilia Maichle-Mössmer and Manfred Manßen

Inorg. Chem. Front., 2025
DOI: 10.1039/D5QI01216C

Reactive main group metal complexes of the neutral NNNN macrocycle, Me4TACD

Priyabrata Ghana, Louis J. Morris and Jun Okuda

Dalton Trans., 2025, 54, 10504
DOI: 10.1039/D4DT03357D

Ga+-catalyzed hydrosilylation? About the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+and silylium catalysis with perfluoroalkoxyaluminate anions

Antoine Barthélemy, Kim Glootz, Harald Scherer, Annaleah Hanske and Ingo Krossing

Chem. Sci., 2022, 13, 439
DOI: 10.1039/D1SC05331K

Strukturen, Bindungsanalyse und Reaktivität eines dikationischen Digallens und eines Diindens, die trans‐gefaltete Ditetrylene nachahmen

Antoine Barthélemy, Harald Scherer, Michael Daub, Alexis Bugnet and Ingo Krossing

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202311648

Ein Brønsted‐saures Galliumhydrid: Einfache Umwandlung von NNNN‐Makrocyclus‐geträgertem [GaI]+ in [GaIIIH]2+

Louis J. Morris, Priyabrata Ghana, Thayalan Rajeshkumar, Ambre Carpentier, Laurent Maron and Jun Okuda

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202114629

Activation of the GaI Cation for Bond Activation: from Oxidative Additions into C−Cl and H−P Bonds to Reversible Insertion into P4

Philipp Dabringhaus, Tim Heizmann and Ingo Krossing

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302212

Structures, Bonding Analyses and Reactivity of a Dicationic Digallene and Diindene Mimicking trans‐bent Ditetrylenes

Antoine Barthélemy, Harald Scherer, Michael Daub, Alexis Bugnet and Ingo Krossing

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202311648

Solvent‐Dependent Oxidative Addition and Reductive Elimination of H2 Across a Gallium‐Zinc Bond

Louis J. Morris, Thayalan Rajeshkumar, Akira Okumura, Laurent Maron and Jun Okuda

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202208855

Hydroboration and Deoxygenation of CO2 Mediated by a Gallium(I) Cation

Louis J. Morris, Pritam Mahawar and Jun Okuda

J. Org. Chem., 2023, 88, 5090
DOI: 10.1021/acs.joc.2c02229

Definition of the Pnictogen Bond: A Perspective

Arpita Varadwaj, Pradeep R. Varadwaj, Helder M. Marques and Koichi Yamashita

Inorganics, 2022, 10, 149
DOI: 10.3390/inorganics10100149

In situ formation of reactive (di)gallenes for bond activation

Philipp Dabringhaus, Harald Scherer and Ingo Krossing

Nat. Synth, 2024, 3, 732
DOI: 10.1038/s44160-024-00521-9

Oxidative Dissolution of Lanthanide Metals Ce and Ho in Molten GaCl3

Taylor V. Fetrow, Brenna K. Cashman, Stephanie H. Carpenter, Michael T. Janicke, Nickolas H. Anderson, Bonnie E. Klamm, Harris E. Mason and Aaron M. Tondreau

Inorg. Chem., 2024, 63, 9385
DOI: 10.1021/acs.inorgchem.3c02774

Direct Comparison of Subvalent, Polycationic Group 13 Cluster Compounds: Lessons learned on Isoelectronic DMPE Substituted Gallium and Indium Tetracation Salts

Antoine Barthélemy, Harald Scherer and Ingo Krossing

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201369

Catalytic reactions with low-valency ambiphilic gallium complexes

Djamila Azrou and Christophe Bour

Nat. Synth, 2024, 3, 679
DOI: 10.1038/s44160-024-00557-x

A Brønsted Acidic Gallium Hydride: Facile Interconversion of NNNN‐Macrocycle Supported [GaI]+ and [GaIIIH]2+

Louis J. Morris, Priyabrata Ghana, Thayalan Rajeshkumar, Ambre Carpentier, Laurent Maron and Jun Okuda

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202114629

Lösungsmittelabhängige oxidative Addition und reduktive Eliminierung von H2 an einer Gallium‐Zink‐Bindung

Louis J. Morris, Thayalan Rajeshkumar, Akira Okumura, Laurent Maron and Jun Okuda

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202208855