Metal/covalent–organic framework based thin film nanocomposite membranes for advanced separations

Lei Ge, Hengjie Song, Junyong Zhu, Yatao Zhang, Zhen Zhou and Bart Van der Bruggen

J. Mater. Chem. A, 2024, 12, 7975
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Mechanism insights into the role of the support mineralization layer toward ultrathin polyamide nanofilms for ultrafast molecular separation

Qiangqiang Song, Yuqing Lin, Takafumi Ueda, Titik Istirokhatun, Qin Shen, Kecheng Guan, Tomohisa Yoshioka and Hideto Matsuyama

J. Mater. Chem. A, 2021, 9, 26159
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Fast water transport through sub-5 nm polyamide nanofilms: the new upper-bound of the permeance–selectivity trade-off in nanofiltration

Pulak Sarkar, Solagna Modak, Santanu Ray, Vasista Adupa, K. Anki Reddy and Santanu Karan

J. Mater. Chem. A, 2021, 9, 20714
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Corolliform morphology thin film composite polyamide membrane constructed via Tröger's base PIM for enhancing nanofiltration separation performances

Tian-Hui Chen, Ting Su, Li Xia, Liu-Yang Gong, Bei-Na Dong and Li-Fen Liu

Desalination, 2023, 548, 116234
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In situ grown cyclodextrin metal-organic framework nanoparticles templated stripe nano-wrinkled polyamide nanofiltration membranes for efficient desalination and antibiotic removal

Jian Yu, Ling Zhang, Liguo Shen, Renjie Li, Dieling Zhao, Hongjun Lin, Yanchao Xu and Yang Jiao

Journal of Membrane Science, 2024, 694, 122413
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Fabrication of polyamide nanofiltration membrane with tannic acid/poly(sodium 4-styrenesulfonate) network-like interlayer for enhanced desalination performance

Pingyun Zheng, Lina Jiang, Qiugen Zhang, Qinglin Liu and Aimei Zhu

Journal of Colloid and Interface Science, 2024, 662, 707
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Thin Film Composite Nanofiltration Membrane Mediated by MOF Interlayer with Novel MOF Templating Technique for Water Treatment

Kamyar Kamali, Toraj Mohammadi and Soheil Zarghami

Ind. Eng. Chem. Res., 2025, 64, 16299
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Ternary deep eutectic solvent enhanced the diffusion control of amine monomer for highly permeable and anti-fouling polyamide nanofiltration membranes

Yufan Hao, Yao Fang, Longfei Zhang, Hao Jiang, Na Yang, Bin Jiang, Yongli Sun and Luhong Zhang

Separation and Purification Technology, 2024, 330, 125371
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Toward Enhancing Desalination and Heavy Metal Removal of TFC Nanofiltration Membranes: A Cost-Effective Interface Temperature-Regulated Interfacial Polymerization

Xiaoxiang Cheng, Cunxian Lai, Jinyu Li, Weiwei Zhou, Xuewu Zhu, Zihui Wang, Junwen Ding, Xinyu Zhang, Daoji Wu, Heng Liang and Congcong Zhao

ACS Appl. Mater. Interfaces, 2021, 13, 57998
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Plasma-enabled graphene quantum dot-based nanofiltration membranes for water purification and dye monitoring

Yi-Jui Yeh, Wei Lin, Wei-Hung Chiang and Kuo-Lun Tung

Journal of Membrane Science, 2023, 670, 121334
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Can lignin nanosphere be used as a recycled sacrificed template for constructing high performance loose nanofiltration membranes?

Jinsong He, Wenjie Liu, Fan Ni, Dong Tian, Yongjia Lei, Jianmei Zou, Yanzong Zhang, Fei Shen and Xiaochan An

Desalination, 2025, 597, 118348
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Tailored ultra-low pressure nanofiltration membranes for advanced drinking water treatment

Xiaoxiang Cheng, Cunxian Lai, Xuewu Zhu, Senlin Shao, Jingtao Xu, Fengxia Zhang, Jialin Song, Daoji Wu, Heng Liang and Xinsheng Luo

Desalination, 2023, 548, 116264
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Enhancing ion separation efficiency: Janus charged nanofiltration membrane fabricated via polyethyleneimine-manipulated interfacial polymerization

Ting Qi, Xianfu Chen, Tiandan Lu, Dongliang Jin, Rong Xu and Jing Zhong

Journal of Membrane Science, 2024, 706, 122930
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Distinct Efficacies of Interlayers in Tailoring Polyamide Nanofiltration Membrane Performance for Organic Micropollutant Removal: Dependent on Substrate Characteristics

Peng Cheng, Yanling Liu, Xinxin Wei, Kaiming Fan and Shengji Xia

Environ. Sci. Technol., 2024, 58, 14022
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MOF laminates functionalized polyamide self-cleaning membrane for advanced loose nanofiltration

Mengying Xu, Xiaoquan Feng, Zhe liu, Xinwei Han, Junyong Zhu, Jing Wang, Bart Van der Bruggen and Yatao Zhang

Separation and Purification Technology, 2021, 275, 119150
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Porous structure with stable superhydrophobic surface for high-performance atmospheric fog harvesting

Kaimin Deng, Xiangyi Zhang, Bo Yuan, Ziwei Deng, Xin Liu and Bin Shang

Journal of Environmental Chemical Engineering, 2022, 10, 108771
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Polyamide Nanofiltration Membranes from Surfactant‐Assembly Regulated Interfacial Polymerization: The Effect of Alkyl Chain

Ruolin Zhang, Yuzhang Zhu, Liufu Zhang, Yang Lu, Zhao Yang, Yatao Zhang and Jian Jin

Macro Chemistry & Physics, 2021, 222
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Strategic small molecule engineering: Unleashing the full potential of Kevlar aramid membrane in organic solvent nanofiltration

Yanqing Xu, Jiaqi Xiong, Qite Qiu, Chenfei Lin, Junbin Liao, Huiming Ruan and Jiangnan Shen

Chemical Engineering Journal, 2024, 495, 153260
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Unprecedented acid-tolerant ultrathin membranes with finely tuned sub-nanopores for energetic-efficient molecular sieving

Fan Yang, Yanqiu Zhang, Junhui Huang, Gang Gao, Jiaqi Zhu, Jun Ma and Lu Shao

Science Bulletin, 2023, 68, 29
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Highly permeable nanofilms with asymmetric multilayered structure engineered via amine-decorated interlayered interfacial polymerization

Qiangqiang Song, Yuqing Lin, Siyu Zhou, Titik Istirokhatun, Zheng Wang, Qin Shen, Zhaohuan Mai, Kecheng Guan and Hideto Matsuyama

Journal of Membrane Science, 2023, 670, 121377
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Preparation of high permeance thin-film composite nanofiltration membrane on macroporous ceramic support

Yuehua Zhang, Peng Xu, Xianfu Chen, Minghui Qiu and Yiqun Fan

Journal of Membrane Science, 2022, 663, 121076
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Solvent remelted nylon polyamide nanofibrous substrate that enhances thin-film composite membranes for organic solvent nanofiltration

Yi-Chen Wang, Wei-Jian Wang, Qian Wang, Zhen-Yuan Wang, Xiang-Yu Yan, Liu-Lin Zhao, Xue-Li Cao and Shi-Peng Sun

Separation and Purification Technology, 2022, 285, 120322
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Green resource utilization of textile and dyeing wastewater: Fabrication of a chlorine-resistant ZIF-L/PDA loose nanofiltration membrane via interfacial polymerization and its performance in dye/salt separation

Nan Yao, Shifeng Ji, Yunqing Xing, Jinchao Chen, Yanrui Cheng, Xiaonan Ruan, Jiaxin Chen, Zhuo Li, Yingjie Zhang, Chunmei Gao and Changbing Ye

Separation and Purification Technology, 2025, 377, 134193
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Comparative Analysis of Commercial and Novel High‐Pressure Membranes for Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) Removal

Razia Hasan, Jianfei Chen, Parnian Mojahednia, Seyed Hesam‐Aldin Samaei and Jinkai Xue

Water Environment Research, 2025, 97
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Ultrathin Sulfonated Mesoporous Interlayer Facilitates to Prepare Highly-Permeable Polyamide Nanofiltration Membranes

Miao Deng, Tengfei Pei, Peng Ge, Aimei Zhu, Qiugen Zhang and Qinglin Liu

SSRN Journal, 2021
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Engineering highly permeable thin-film composite nanofiltration membranes by strengthening the diffusion control of amine monomer via deep eutectic solvent

Yao Fang, Bin Jiang, Yufan Hao, Na Yang, Longfei Zhang, Congcong Zhang, Yongli Sun, Xiaoming Xiao and Luhong Zhang

Journal of Membrane Science, 2023, 678, 121689
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Surface and Interface Engineering of Polymer Membranes: Where We Are and Where to Go

Zhao-Yu Ma, Yu-Ren Xue, Hao-Cheng Yang, Jian Wu and Zhi-Kang Xu

Macromolecules, 2022, 55, 3363
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Scalable Preparation of Ultraselective and Highly Permeable Fully Aromatic Polyamide Nanofiltration Membranes for Antibiotic Desalination

Haohao Liu, Lijun Liang, Feng Tian, Xugang Xi, Yanqin Zhang, Peng Zhang, Xingzhong Cao, Yunxiang Bai, Chunfang Zhang and Liangliang Dong

Angew Chem Int Ed, 2024, 63
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Guanidyl-incorporated nanofiltration membranes toward superior Li+/Mg2+ selectivity under weakly alkaline environment

Shiyu Zhang, Runnan Zhang, Runlai Li, Zixuan Zhang, Yafei Li, Hao Deng, Junhui Zhao, Tianrun Gu, Mengying Long, Xiaoyao Wang, Sui Zhang and Zhongyi Jiang

Journal of Membrane Science, 2022, 663, 121063
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Facile morphological tuning of thin film composite membranes for enhanced desalination performance

Shabin Mohammed, Jamaliah Aburabie and Raed Hashaikeh

npj Clean Water, 2023, 6
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A zwitterionic copolymer-interlayered ultrathin nanofilm with ridge-shaped structure for ultrapermeable nanofiltration

Qiangqiang Song, Yuqing Lin, Takafumi Ueda, Qin Shen, Kueir-Rarn Lee, Tomohisa Yoshioka and Hideto Matsuyama

Journal of Membrane Science, 2022, 657, 120679
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Thin film composite polyesteramide membrane with the incorporation of rigidly-contorted binaphthol-based monomer for enhanced nanofiltration separation performance

Youcai Chen, Shao-Lu Li, Dandan Cheng, Jiaqi Li, Mengfan Wang, Qiyu Duan, Genghao Gong and Yunxia Hu

Separation and Purification Technology, 2023, 322, 124376
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Ultrathin sulfonated mesoporous interlayer facilitates to prepare highly-permeable polyamide nanofiltration membranes

Miao Deng, Tengfei Pei, Peng Ge, Aimei Zhu, Qiugen Zhang and Qinglin Liu

Journal of Membrane Science, 2022, 652, 120507
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Modeling nanovoid-enhanced water permeance of thin film composite membranes

Yaowen Hu, Fei Wang, Zhe Yang and Chuyang Y. Tang

Journal of Membrane Science, 2023, 675, 121555
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Highly chlorine resistant polyamide reverse osmosis membranes realized by interfacial polymerization at a free interface with a buffer layer

Qing Zhang, Zhenping Ma, Xin Jing, Hao-Yang Mi, Yuejun Liu and Songwei Li

Desalination and Water Treatment, 2021, 234, 361
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Nanofiltration Membranes with Crumpled Polyamide Films: A Critical Review on Mechanisms, Performances, and Environmental Applications

Senlin Shao, Fanxi Zeng, Li Long, Xuewu Zhu, Lu Elfa Peng, Fei Wang, Zhe Yang and Chuyang Y. Tang

Environ. Sci. Technol., 2022, 56, 12811
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Enhanced Mg2+/Li+ separation performance of polyelectrolyte multilayers nanofiltration membranes modified by trimethylamine N-oxide zwitterions

Yanling Chai, Jinchao Chen, Xiaofeng Fang, Fang Li and Xingran Zhang

Journal of Membrane Science, 2025, 713, 123293
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Zwitterionic Copolymer-Regulated Interfacial Polymerization for Highly Permselective Nanofiltration Membrane

Yuqing Lin, Xuesong Yao, Qin Shen, Takafumi Ueda, Yuki Kawabata, Jumpei Segawa, Kecheng Guan, Titik Istirokhatun, Qiangqiang Song, Tomohisa Yoshioka and Hideto Matsuyama

Nano Lett., 2021, 21, 6525
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Regulating interfacial polymerization via constructed 2D metal-organic framework interlayers for fabricating nanofiltration membranes with enhanced performance

Peng Cheng, Yanling Liu, Xiaoping Wang, Kaiming Fan, Pan Li and Shengji Xia

Desalination, 2022, 544, 116134
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Polyamide–based membranes with nanoscale homogeneity and asymmetric structure for ultrafast ion separation

Faizal Soyekwo, Changkun Liu, Hui Wen and Saleem Raza

Journal of Membrane Science, 2023, 685, 121921
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Porous Zn-TCPP interlayer with active reaction sites modulates membrane physicochemical properties to improve nanofiltration performance

Xiaojuan Wang, Shengjun Xu, Xinyan Wang, Yuhong Wang, Kaiwen Ge, Congjie Gao and Xueli Gao

Desalination, 2024, 576, 117354
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Thin-film nanocomposite (TFN) membrane technologies for the removal of emerging contaminants from wastewater

Bo Han and Jean-Christophe P. Gabriel

Journal of Cleaner Production, 2024, 480, 144043
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Enhanced performance of thin film nanocomposite (TFN) membranes by incorporating hydrophilic MOF-808 into the organic phase: Towards eliminating non-steroidal anti-inflammatory drugs (NSAIDs) from aqueous solutions

Sara Abdi and Masoud Nasiri

Desalination, 2025, 601, 118590
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A “grab-and-throw” access for monomer diffusion in interfacial polymerization process for high-efficiency polyamide membrane in water purification

Xiyue Cai, Yonggang li, Zhenyu Xi, Chen Yun, Lianghong Yin, Jing Guo, Yaohan Chen, Shenghai Li and Suobo Zhang

Journal of Membrane Science, 2025, 722, 123871
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High water permeable nanofiltration membranes via post pore expansion of polyamide thin layer introducing methoxycarbonyl groups

Daisuke Saeki, Hiroyuki Tsuchida, Takahiro Kawakatsu and Yukihisa Okumura

Separation and Purification Technology, 2025, 358, 130265
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Tannic acid-metal interlayers enhance permeance and antibiotics/NaCl separation efficiency of polyamide nanofiltration membranes

Yuehao Wen, Jingquan Wang, Jianfei Zhou and Hongguang Guo

Separation and Purification Technology, 2025, 360, 131174
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Janus Fabric with Asymmetric Wettability for Switchable Emulsion Separation and Controllable Droplets with Low Friction

Deke Li, Chenggong Xu, Jinxia Huang and Zhiguang Guo

Langmuir, 2023, 39, 1320
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Aminated substrate based thin film composite nanofiltration membrane with high separation performance by chemically inhibiting the intrusion of polyamide

Xiaosheng Ji, Ge Li, Guangyao Chen, Yukun Qian, Hongyu Jin, Zhikan Yao and Lin Zhang

Desalination, 2022, 532, 115724
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In-situ interfacial polymerization of polyamide TFN membranes by adding a diamino-silane coupling agent: Toward enhanced desalination performance

Huanhuan Wu, Qian Zhang, Bing Xu, Xin Liu, Yakai Lin, Nan Jiang, Hong Yao, Yuanhui Tang, Lin Wang, Lixin Yu, Zhenzhong Yang and Xiaolin Wang

Desalination, 2024, 580, 117508
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Polyelectrolyte-based nanofiltration membranes with exceptional performance in Mg2+/Li+ separation in a wide range of solution conditions

Rongrong He, Shanshan Xu, Ruoyu Wang, Bingyang Bai, Shihong Lin and Tao He

Journal of Membrane Science, 2022, 663, 121027
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Ag-based nanocapsule-regulated interfacial polymerization Enables synchronous nanostructure towards high-performance nanofiltration membrane for sustainable water remediation

Titik Istirokhatun, Yuqing Lin, Qin Shen, Kecheng Guan, Shengyao Wang and Hideto Matsuyama

Journal of Membrane Science, 2022, 645, 120196
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Ultrathin Membranes for Separations: A New Era Driven by Advanced Nanotechnology

Shiyu Zhang, Liang Shen, Hao Deng, Qinze Liu, Xinda You, Jinqiu Yuan, Zhongyi Jiang and Sui Zhang

Advanced Materials, 2022, 34
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Development of ultrathin polyamide nanofilm with enhanced inner-pore interconnectivity via graphene quantum dots-assembly intercalation for high-performance organic solvent nanofiltration

Qin Shen, Yuqing Lin, Pengfei Zhang, Jumpei Segawa, Yuandong Jia, Titik Istirokhatun, Xingzhong Cao, Kecheng Guan and Hideto Matsuyama

Journal of Membrane Science, 2021, 635, 119498
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Effect of functionalized nanodiamonds and surfactants mediation on the nanofiltration performance of polyamide thin-film nanocomposite membranes

T.M. Subrahmanya, Jing-Yang Lin, Januar Widakdo, Hannah Faye M. Austria, Owen-Setiawan, Yu-Hsuan Chiao, Tsung-Han Huang, Wei-Song Hung, Hideto Matsuyama, Kueir-Rarn Lee and Juin-Yih Lai

Desalination, 2023, 555, 116540
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Efficient removal of methylene blue dye from aqueous media via acrylic acid grafted Guggul gum-based hydrogel

Shabnum Saleem, Sonal Choudhary, Kashma Sharma, Vishal Sharma, Vaneet Kumar and Vijay Kumar

Polym. Bull., 2025, 82, 4099
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Double Polyamide Layers with CaCO3 Nanoparticles as Scaffolds for High Performance Nanofiltration Membranes

Jiqiao Liu, Quan Li, Yanhong Ji, Zhenyu Cui, Younas Mohammad, Jianxin Li and Benqiao He

ACS Appl. Nano Mater., 2022, 5, 8279
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Polyamide composite nanofiltration membrane modified by nanoporous TiO2 interlayer for enhanced water permeability

Mingzhu Chi, Pingyun Zheng, Mingxin Wei, Aimei Zhu, Lubin Zhong, Qiugen Zhang and Qinglin Liu

Journal of Industrial and Engineering Chemistry, 2022, 115, 230
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Guanidinium manipulated interfacial polymerization for polyamide nanofiltration membranes with ultra-high permselectivity

Shuting Xu, Jiahuan Liu, Jianqiang Wang, Haibo Lin, Qiu Han, Fu Liu and Chuyang Y. Tang

Journal of Membrane Science, 2023, 687, 122003
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Corolliform Morphology Thin Film Composite Polyamide Membrane Constructed Via Tröger's Base Pim for Enhancing Nanofiltration Separation Performances

Tian-Hui Chen, Ting Su, Li Xia, Liu-Yang Gong, Bei-Na Dong and Li-Fen Liu

SSRN Journal, 2022
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Alginate Hydrogel Assisted Controllable Interfacial Polymerization for High-Performance Nanofiltration Membranes

Zhao-Yu Ma, Yu-Ren Xue and Zhi-Kang Xu

Membranes, 2021, 11, 435
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Rationally regulating the PES substrate by introducing ZIF-8 with tunable shapes for optimal thin-film composite membrane

Jia Wang, Xuan Zhao, Hongqiang Qu, Jianzhong Xu and Jing Ma

Applied Surface Science, 2023, 615, 156181
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Scalable Preparation of Ultraselective and Highly Permeable Fully Aromatic Polyamide Nanofiltration Membranes for Antibiotic Desalination

Haohao Liu, Lijun Liang, Feng Tian, Xugang Xi, Yanqin Zhang, Peng Zhang, Xingzhong Cao, Yunxiang Bai, Chunfang Zhang and Liangliang Dong

Angewandte Chemie, 2024, 136
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Green β-cyclodextrin interlayered crumpled polyamide membranes for effective desalination

Jian Yu, Ling Zhang, Hongguang Sun, Renjie Li, Die Ling Zhao, Liguo Shen, Hongjun Lin, Yang Jiao and Yanchao Xu

Desalination, 2025, 599, 118467
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Catalytic template assisted interfacial polymerization for high‐performance acid‐resistant membrane preparation

Yang Cao, Yinhua Wan, Chulong Chen and Jianquan Luo

AIChE Journal, 2023, 69
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Catalyst-anchored secondary polymerization for highly permeable acid-resistant nanofiltration membrane preparation

Yang Cao, Yinhua Wan, Chulong Chen and Jianquan Luo

Journal of Membrane Science, 2023, 686, 121991
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Constructing highly rough skin layer of thin film (nano)composite polyamide membranes to enhance separation performance: A review

Dan Hu, Xiaomin Ren, Hongyan Fu, Yu Wang, Xudong Feng and Hehe Li

J of Applied Polymer Sci, 2022, 139
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A novel ZIF-L/PEI thin film nanocomposite membrane for removing perfluoroalkyl substances (PFASs) from water: Enhanced retention and high flux

Yujie Bi, Xiangmin Meng, Zhijun Tan, Qianqian Geng, Jixing Peng, Qiaozhi Yong, Xiaojie Sun, Mengmeng Guo and Xinping Wang

Science of The Total Environment, 2024, 925, 171727
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Design and fabrication of microporous polyesteramide composite membranes for high-performance molecule/ion fractionation

Binyu Zhou, Yuanfang Wang, Miaomiao Tian, Xueli Cao, Li Han, Shi-Peng Sun, Yatao Zhang, Junyong Zhu and Bart Van der Bruggen

Journal of Membrane Science, 2025, 124681
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Surfactants attached thin film composite (TFC) nanofiltration (NF) membrane via intermolecular interaction for heavy metals removal

Sun-Jie Xu, Qian Shen, Li-Han Luo, Yi-Hao Tong, Yu-Zhe Wu, Zhen-Liang Xu and Hai-Zhen Zhang

Journal of Membrane Science, 2022, 642, 119930
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Efficient dye desalination of nanofiltration membrane prepared by multi-arm amine-rich compound via interfacial polymerization

Yi Wang, Jian Dong, Liangliang Dong, Weifu Dong, Mingqing Chen and Dongjian Shi

Composites Communications, 2025, 56, 102339
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