Quasi-solid conductive gels with high thermoelectric properties and high mechanical stretchability consisting of a low cost and green deep eutectic solvent

Yinling Zhao, Hanlin Cheng, Yaoxiang Li, Jiancheng Rao, Shizhong Yue, Qiujian Le, Qi Qian, Zhuo Liu and Jianyong Ouyang

J. Mater. Chem. A, 2022, 10, 4222
DOI: 10.1039/D1TA09707E

Suppressing growth of lithium dendrites by introducing deep eutectic solvents for stable lithium metal batteries

Wentao Li, Wei Liu, Bendong Huang, Ziwei Cai, Hai Zhong, Fei Guo and Yaohua Mai

J. Mater. Chem. A, 2022, 10, 15449
DOI: 10.1039/D2TA03253H

Green production of ion-conductive and self-healable polymers by photoinduced radical polymerization of ternary deep eutectic monomers

Yuta Tanaka, Reina Shinohe, Shingo Yuki, Takuto Ohashi and Hideharu Mori

Polym. Chem., 2023, 14, 4538
DOI: 10.1039/D3PY00770G

Tetramethylurea dimer/lithium salt-based deep eutectics as a novel class of eutectic electrolytes

Hideyuki Ogawa, Yugo Sato and Hideharu Mori

Mater. Chem. Front., 2021, 5, 8078
DOI: 10.1039/D1QM01174J

Recent progress in nonflammable electrolytes and cell design for safe Li-ion batteries

Zi Ye, Jiayao Li and Zhejun Li

J. Mater. Chem. A, 2023, 11, 15576
DOI: 10.1039/D3TA01951A

Deep eutectic ion-conductive hybrids produced by combining hydroxyl-functionalized silsesquioxane and mono-/difunctional hydrogen bond acceptors

Tomohito Inoue, Sota Saito, Akihiro Nishioka and Hideharu Mori

Polym. Chem., 2025, 16, 2378
DOI: 10.1039/D5PY00192G

Dissolution mechanism of cellulose in a benzyltriethylammonium/urea deep eutectic solvent (DES): DFT-quantum modeling, molecular dynamics and experimental investigation

Omar Azougagh, Issam Jilal, Loubna Jabir, Hayat El-Hammi, Soumya Essayeh, Nor Mohammed, Nafea Achalhi, Ridouan El yousfi, Abderrahmane El Idrissi, Youssef El Ouardi, Katri Laatikainen, Mohamed Abou-Salama and Soufian El Barkany

Phys. Chem. Chem. Phys., 2023, 25, 22870
DOI: 10.1039/D3CP02335D

Polyeutectic-based stable and effective electrolytes for high-performance energy storage systems

Changkun Zhang, Zhihui Niu, Jiwoong Bae, Leyuan Zhang, Yu Zhao and Guihua Yu

Energy Environ. Sci., 2021, 14, 931
DOI: 10.1039/D0EE03100C

Synthesis of ion-conductive polymers by radical polymerization of deep eutectic monomers bearing quaternary ammonium groups with urea

Keiko Ajino, Ayaka Torii, Hideyuki Ogawa and Hideharu Mori

Polymer, 2020, 204, 122803
DOI: 10.1016/j.polymer.2020.122803

Eutectic Electrolytes with Doubly‐Bound Water for High‐Stability Zinc Anodes

Dong Han, Tianjiang Sun, RuoChen Zhang, Weijia Zhang, Tao Ma, Haihui Du, Qiaoran Wang, Dan He, Shibing Zheng and Zhanliang Tao

Adv Funct Materials, 2022, 32
DOI: 10.1002/adfm.202209065

Deep Eutectic Solvents: A Review Of Syntheses, Properties, and their Applications in Different Fields

Amin Zobeid, Fatemeh Abbasi and Sedigheh Azadi

AANBT, 2025, 6, 1
DOI: 10.18502/aanbt.v6i2.18615

Development of zinc nitrate hexahydrate salt (ZNH)/ethylene glycol (EG) binary composite deep eutectic electrolytes

Fentahun Adamu Getie, Delele Worku Ayele, Nigus Gabbiye Habtu, Temesgen Atnafu Yemata, Fantahun Aklog Yihun, Mehary Dagnaw Ambaw and Ababay Ketema Worku

International Journal of Electrochemical Science, 2024, 19, 100616
DOI: 10.1016/j.ijoes.2024.100616

Deep Eutectic Solvents for Boosting Electrochemical Energy Storage and Conversion: A Review and Perspective

Junxiong Wu, Qinghua Liang, Xiaoliang Yu, Qiu‐Feng Lü, Lianbo Ma, Xianying Qin, Guohua Chen and Baohua Li

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202011102

Synthesis of Superionic Conductive Li1+x+yAlxSiyTi2−xP3−yO12 Solid Electrolytes

Hyeonwoo Jeong, Dan Na, Jiyeon Baek, Sanggil Kim, Suresh Mamidi, Cheul-Ro Lee, Hyung-Kee Seo and Inseok Seo

Nanomaterials, 2022, 12, 1158
DOI: 10.3390/nano12071158

Simulation of Spreading and Interfacial Behavior of Deep Eutectic Electrolytes on Two Facets of Li Metal Electrodes: Improving Li Metal Batteries’ Performance

Tahereh Ghaed-Sharaf and Akbar Omidvar

ACS Appl. Energy Mater., 2025
DOI: 10.1021/acsaem.5c02385

Smart interfaces in Li-ion batteries: Near-future key challenges

Eleonora Pargoletti, Serena Arnaboldi, Giuseppe Cappelletti, Mariangela Longhi, Daniela Meroni, Alessandro Minguzzi, Patrizia Romana Mussini, Sandra Rondinini and Alberto Vertova

Electrochimica Acta, 2022, 415, 140258
DOI: 10.1016/j.electacta.2022.140258

Developing safe and high-performance lithium-ion batteries: Strategies and approaches

Guanjun Chen, Rui Tan, Chunlin Zeng, Yan Li, Zexin Zou, Hansen Wang, Chuying Ouyang, Jiayu Wan and Jinlong Yang

Progress in Materials Science, 2025, 154, 101516
DOI: 10.1016/j.pmatsci.2025.101516

Recent advances and design strategies of eutectic electrolytes for lithium metal batteries

Jiawei Chen, Hong Pan, Fang Wu, Bailing Zhou, Zhiyu Xue, Yifan Wang, Yong Xiang and Fei Li

Energy Storage Materials, 2025, 104567
DOI: 10.1016/j.ensm.2025.104567

Redefine the existence form and function of water in potassium carbonate-based deep eutectic electrolyte

Peng Zeng, Dongling Wu, Tao Wang, Penggao Liu and Dianzeng Jia

Fuel, 2024, 357, 129738
DOI: 10.1016/j.fuel.2023.129738

Phase regulation enabling dense polymer-based composite electrolytes for solid-state lithium metal batteries

Qian Wu, Mandi Fang, Shizhe Jiao, Siyuan Li, Shichao Zhang, Zeyu Shen, Shulan Mao, Jiale Mao, Jiahui Zhang, Yuanzhong Tan, Kang Shen, Jiaxing Lv, Wei Hu, Yi He and Yingying Lu

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-41808-3

Novel amide-based deep eutectic solvent electrolytes for high-performance lithium-ion batteries

Jia Qi He, Dian Chun Ju, Wen Kai Zou, Tian Yi Lv, Chun Yu Chen, Hui Li, Yi Zhuang and Bo Wen Li

Journal of Vacuum Science & Technology A, 2024, 42
DOI: 10.1116/6.0003452

Broadband NMR relaxometry of electrolytes for energy storage

C. C. Fraenza and S. G. Greenbaum

Chemical Physics Reviews, 2022, 3
DOI: 10.1063/5.0076580

Design of metal salt/amide-based deep eutectic monomers toward sustainable production of ion-conductive polymers by radical polymerization

Y. Tanaka, K. Ajino, H. Ogawa and H. Mori

Materials Today Chemistry, 2022, 26, 101033
DOI: 10.1016/j.mtchem.2022.101033

Deep Eutectic Solvents for Batteries and Fuel Cells: Biosubstitution, Advantages, Challenges, and Future Directions

Yonchen Hariyanto, Ying Ki Ng, Zhi Zhou Siew, Chu Yong Soon, Adrian C. Fisher, Leopold Kloyer, Chen Wai Wong and Eric Wei Chiang Chan

Energy Fuels, 2023, 37, 18395
DOI: 10.1021/acs.energyfuels.3c02870

Recent advances and various detection strategies of deep eutectic solvents for zinc air batteries

Fentahun Adamu Getie, Delele Worku Ayele, Nigus Gabbiye Habtu, Temesgen Atnafu Yemata, Fantahun Aklog Yihun, Ababay Ketema Worku and Minbale Admas Teshager

Heliyon, 2024, 10, e40383
DOI: 10.1016/j.heliyon.2024.e40383

Electrolytes from Alkoxyalkyl-substituted Imidazolium ionic liquids. Synthesis, characterization, properties and cell performance in LiFePO4 half-cells

Cristina Santamaría, Enrique Morales, J. Manuel Amarilla and Bernardo Herradón

Electrochimica Acta, 2024, 507, 145096
DOI: 10.1016/j.electacta.2024.145096

Eutectic Electrolytes Chemistry for Rechargeable Zn Batteries

Xuejun Lu, Evan J. Hansen, Guanjie He and Jian Liu

Small, 2022, 18
DOI: 10.1002/smll.202200550

Computer Simulations of Deep Eutectic Solvents: Challenges, Solutions, and Perspectives

Dmitry Tolmachev, Natalia Lukasheva, Ruslan Ramazanov, Victor Nazarychev, Natalia Borzdun, Igor Volgin, Maria Andreeva, Artyom Glova, Sofia Melnikova, Alexey Dobrovskiy, Steven A. Silber, Sergey Larin, Rafael Maglia de Souza, Mauro Carlos Costa Ribeiro, Sergey Lyulin and Mikko Karttunen

IJMS, 2022, 23, 645
DOI: 10.3390/ijms23020645

Effects of size on water vapour absorption and regeneration in lithium chloride nanocrystals

Abhinav Prakash, Nirmal Kumar Katiyar, Martha Y. Suarez-Villagran, John H. Miller, Leonardo D. Machado, C.S. Tiwary, Krishanu Biswas and Kamanio Chattopadhyay

Materials Today Communications, 2023, 36, 106388
DOI: 10.1016/j.mtcomm.2023.106388

An account on the deep eutectic solvents-based electrolytes for rechargeable batteries and supercapacitors

Rangaswamy Puttaswamy, Chanchal Mondal, Dibyendu Mondal and Debasis Ghosh

Sustainable Materials and Technologies, 2022, 33, e00477
DOI: 10.1016/j.susmat.2022.e00477

Green Batteries: A Sustainable Approach Towards Next-Generation Batteries

Annu, Bairi Sri Harisha, Manesh Yewale, Bhargav Akkinepally and Dong Kil Shin

Batteries, 2025, 11, 258
DOI: 10.3390/batteries11070258

A siloxane-based self-healing gel electrolyte with deep eutectic solvents for safe quasi-solid-state lithium metal batteries

Yuxin Chen, Canhui Ling, Kecheng Long, Xinsheng Liu, Pengfei Xiao, Ying-Zhi Yu, Weifeng Wei, Xiaobo Ji, Wenyan Tang, Gui-Chao Kuang and Libao Chen

Chemical Engineering Journal, 2024, 488, 150888
DOI: 10.1016/j.cej.2024.150888

Suppressing Growth of Lithium Dendrites by Introducing Deep Eutectic Solvents for Stable Lithium Metal Batteries

Wentao Li, Huijuan Lin, Bendong Huang, Wei Liu, Ziwei Cai, Hai Zhong, Fei Guo and Yaohua Mai

SSRN Journal, 2022
DOI: 10.2139/ssrn.4051868

Nonaqueous Rechargeable Aluminum Batteries: Progresses, Challenges, and Perspectives

Jiguo Tu, Wei-Li Song, Haiping Lei, Zhijing Yu, Li-Li Chen, Mingyong Wang and Shuqiang Jiao

Chem. Rev., 2021, 121, 4903
DOI: 10.1021/acs.chemrev.0c01257

Deep Eutectic Solvents Based on N-Methyltrifluoroacetamide and Lithium Bis(trifluoromethanesulfonyl)imide as New Electrolytes with Low Viscosity and High Ionic Conductivity

Guihong Lyu, Carsten Korte and Jiangshui Luo

Materials, 2025, 18, 2048
DOI: 10.3390/ma18092048

Li−N Interaction Induced Deep Eutectic Gel Polymer Electrolyte for High Performance Lithium‐Metal Batteries

Xiaopeng Pei, Yiju Li, Ting Ou, Xuechen Liang, Yun Yang, Erna Jia, Ying Tan and Shaojun Guo

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202205075

Deep eutectic solvent electrolytes based on trifluoroacetamide and LiPF6 for Li-metal batteries

Lorenzo Mezzomo, Nicolò Pianta, Irene Ostroman, Niv Aloni, Diana Golodnitsky, Emanuel Peled, Piercarlo Mustarelli and Riccardo Ruffo

Journal of Power Sources, 2023, 561, 232746
DOI: 10.1016/j.jpowsour.2023.232746

Recent Advancements in Devising Computational Strategies for Dual‐Ion Batteries

Sandeep Das, Surya Sekhar Manna and Biswarup Pathak

ChemSusChem, 2023, 16
DOI: 10.1002/cssc.202201405

Probing the potential of type V Deep eutectic solvents as sustainable electrolytes

Giselle de Araujo Lima e Souza, Emilia Pelegano-Titmuss, Miguel Muñoz, Burcu Gurkan, Maria Enrica di Pietro, Andrea Mele, Phillip Stallworth and Steven Greenbaum

Journal of Molecular Liquids, 2024, 416, 126526
DOI: 10.1016/j.molliq.2024.126526

Physicochemical Properties and Empirical Polarity Parameters of Lithium Salt-Based Deep Eutectic Solvents

Manish Kumar, Rajat Chauhan and Siddharth Pandey

J. Chem. Eng. Data, 2025, 70, 2358
DOI: 10.1021/acs.jced.5c00153

Rapid Thermal Shutdown of Deep‐Eutectic‐Polymer Electrolyte Enabling Overheating Self‐Protection of Lithium Metal Batteries

Zengqi Zhang, Gang Li, Xiaofan Du, Lang Huang, Guohong Kang, Jianjun Zhang, Zili Cui, Tao Liu, Ling Ni, Yongcheng Jin and Guanglei Cui

Advanced Science, 2024, 11
DOI: 10.1002/advs.202409628

Deep eutectic solvent-based sustainable electrochemical lithium batteries – Prospects, challenges, and life cycle engineering

Lavanya Priyadarshini Ramalingam, Balasubramanian Ramalingam, Senthilkumar Rathnasamy and Parkavi Kathirvelu

Sustainable Energy Technologies and Assessments, 2025, 73, 104136
DOI: 10.1016/j.seta.2024.104136

Deep eutectic silsesquioxane hybrids with quaternary ammonium/urea derivatives: synthesis and physicochemical and ion-conductive properties

Y. Tanizaki, Y. Maeda, Y. Sasaki, H. Ogawa and H. Mori

Materials Today Chemistry, 2021, 20, 100455
DOI: 10.1016/j.mtchem.2021.100455

Unravelling the prospects of electrolytes containing ionic liquids and deep eutectic solvents for next generation lithium batteries

Shivani, Ramesh Chand Thakur, Akhil Thakur, Akshay Sharma and Renuka Sharma

Journal of Energy Chemistry, 2025, 105, 482
DOI: 10.1016/j.jechem.2025.01.060

Sustainable Production of Ion‐Conductive Polyelectrolytes by Ultrafast Photopolymerization of Lithium, Sodium, and Potassium Salts/Amide‐Based Deep Eutectic Monomers

Reina Shinohe, Maëlan Canet, Yuya Sasaki, Seigou Kawaguchi and Hideharu Mori

Macromol. Rapid Commun., 2025, 46
DOI: 10.1002/marc.202401024

Facile Assembly of C–N Bond-Containing Polymer Electrolytes Enabled by Lithium Salt-Catalyzed Aza-Michael Addition

Jirong Wang, Chi Zhang, Yong Zhang, Gong Chen, Rinaldo Poli, Xiaolin Xie and Zhigang Xue

Macromolecules, 2023, 56, 2484
DOI: 10.1021/acs.macromol.2c02230

Electrochemical preparation of Al- Li alloy from Urea-LiCl molten salt at 353–393 K

Bingliang Gao, Zhiwei Liu and Yifan Deng

Front. Chem., 2023, 11
DOI: 10.3389/fchem.2023.1159780

Deep eutectic solvent with film-forming fluoroethylene carbonate as a nonflammable electrolyte for lithium metal batteries

Wentao Li, Wei Liu, Ziwei Cai, Bendong Huang, Hai Zhong and Yaohua Mai

Journal of Energy Storage, 2023, 68, 107766
DOI: 10.1016/j.est.2023.107766

Polymerizable Deep Eutectic Solvent-Based Polymer Electrolyte for Advanced Dendrite-Free, High-Rate, and Long-Life Li Metal Batteries

Xiaoxin Liang, Cunsheng Liu, Songyi Liao, Selina X. Yao and Minghui He

ACS Appl. Mater. Interfaces, 2024, 16, 4661
DOI: 10.1021/acsami.3c15889

Binary glycerol-based deep eutectic solvents containing zinc nitrate hexahydrate salt for rechargeable zinc air batteries applications with enhanced properties

Fentahun Adamu Getie, Delele Worku Ayele, Nigus Gabbiye Habtu, Fantahun Aklog Yihun, Temesgen Atnafu Yemata, Mehary Dagnaw Ambaw and Ababay Ketema Worku

Heliyon, 2023, 9, e17810
DOI: 10.1016/j.heliyon.2023.e17810

Microstructural Evolution of Zinc‐Ion Species from Aqueous to Hydrated Eutectic Electrolyte for Zn‐Ion Batteries

Long Su, Fei Lu, Yanrui Li, Xia Li, Liangdan Chen, Yanan Gao, Liqiang Zheng and Xinpei Gao

ChemSusChem, 2023, 16
DOI: 10.1002/cssc.202300285

Intermolecular Vibrational and Orientational Dynamics of Deep Eutectic Solvents Composed of Lithium Bis(trifluoromethylsulfonyl)amide and Organic Amides Revealed by Dynamic Kerr Effect Spectroscopy

Maharoof Koyakkat and Hideaki Shirota

J. Phys. Chem. B, 2025, 129, 4023
DOI: 10.1021/acs.jpcb.4c08623

Li−N Interaction Induced Deep Eutectic Gel Polymer Electrolyte for High Performance Lithium‐Metal Batteries

Xiaopeng Pei, Yiju Li, Ting Ou, Xuechen Liang, Yun Yang, Erna Jia, Ying Tan and Shaojun Guo

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202205075

Deep eutectics and analogues as electrolytes in batteries

Maria Enrica Di Pietro and Andrea Mele

Journal of Molecular Liquids, 2021, 338, 116597
DOI: 10.1016/j.molliq.2021.116597

Lithium-ion hopping weakens thermal stability of LiPF6 carbonate electrolytes

Kee Sung Han, Mal-Soon Lee, Namhyung Kim, Daiwon Choi, Sujong Chae, Jaegeon Ryu, GiovanniMaria Piccini, Roger Rousseau and Edwin C. Thomsen

Cell Reports Physical Science, 2024, 5, 101768
DOI: 10.1016/j.xcrp.2023.101768

The ion behavior and storage mechanism of 2D MoO3 layer structure in an air-stable hydrated eutectic electrolyte for aluminum-ion energy storage

Feng Hao Hsu, Su Yang Hsu, Ramesh Subramani, Tsung Chia Cheng, Bo Hao Chen, Jeng Lung Chen, Jin Ming Chen and Kueih Tzu Lu

Journal of Energy Storage, 2024, 84, 110693
DOI: 10.1016/j.est.2024.110693

Molecular insight into the structure and dynamics of LiTf2N/deep eutectic solvent: an electrolyte for Li-ion batteries

Kishant Kumar, Anand Bharti and Rudra Kumar

Molecular Simulation, 2021, 47, 1477
DOI: 10.1080/08927022.2021.1983178

Methyl Carbamate‐Lithium Salt Deep Eutectic Electrolyte for Lithium‐Ion Batteries

Nathaniel Z. Hardin, Zachary Duca, Adam Imel and Patrick A. Ward

ChemElectroChem, 2022, 9
DOI: 10.1002/celc.202200628

Development of Lithium Ion Conducting Liquid: Methylurea-Based Eutectic Electrolytes for Lithium Batteries

Nanako ITO, Tomooki HOSAKA, Ryoichi TATARA, Zachary T. GOSSAGE and Shinichi KOMABA

Electrochemistry, 2025, 93, 027018
DOI: 10.5796/electrochemistry.25-00003

Applying Classical, Ab Initio, and Machine-Learning Molecular Dynamics Simulations to the Liquid Electrolyte for Rechargeable Batteries

Nan Yao, Xiang Chen, Zhong-Heng Fu and Qiang Zhang

Chem. Rev., 2022, 122, 10970
DOI: 10.1021/acs.chemrev.1c00904

Recent advances in deep eutectic solvents for next-generation lithium batteries: Safer and greener

Kaixuan Zhou, Xinke Dai, Peihua Li, Long Zhang, Xiaoming Zhang, Chunxia Wang, Jiawei Wen, Guoyong Huang and Shengming Xu

Progress in Materials Science, 2024, 146, 101338
DOI: 10.1016/j.pmatsci.2024.101338

Rational design of the temperature-responsive nonflammable electrolyte for safe lithium-ion batteries

Zi Ye, Chen-chen Zheng, Zhi-jie Tan and Zhejun Li

Energy Storage Materials, 2024, 73, 103790
DOI: 10.1016/j.ensm.2024.103790

Recent Progress of Urea-Based Deep Eutectic Solvents as Electrolytes in Battery Technology: A Critical Review

Mohamed Ammar, Sherif Ashraf, Diego Alexander Gonzalez-casamachin, Damilola Tomi Awotoye and Jonas Baltrusaitis

Batteries, 2024, 10, 45
DOI: 10.3390/batteries10020045

Eutectic electrolytes composed of trifluoroacetamides and lithium bis(fluorosulfonyl)amide

Kazuki Yoshii, Yuta Maeyoshi, Takuya Uto and Toshiyuki Moriuchi

Journal of Molecular Liquids, 2025, 426, 127369
DOI: 10.1016/j.molliq.2025.127369

Synergistic Long‐ and Short‐Range Sodium‐Ion Transport Pathways for Enhanced Low‐Temperature Performance in Ceramic‐DEE‐Polymer Electrolytes

Shuanglin Wu, Feng Tang, Kun Zhang, Leibing Zhang and Fenglin Huang

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202501107

Decoding lithium solvation in deep eutectic Solvents: The Future of Next-Gen battery electrolytes

Mehdi Shakourian-Fard, Hamid Reza Ghenaatian, Samaneh Pasban and Ganesh Kamath

Chemical Engineering Science, 2025, 310, 121553
DOI: 10.1016/j.ces.2025.121553

Weak-Interaction Environment in a Composite Electrolyte Enabling Ultralong-Cycling High-Voltage Solid-State Lithium Batteries

Ke Yang, Jiabin Ma, Yuhang Li, Junyu Jiao, Shizhe Jiao, Xufei An, Guiming Zhong, Likun Chen, Yuyuan Jiang, Yang Liu, Danfeng Zhang, Jinshuo Mi, Jie Biao, Boyu Li, Xing Cheng, Shaoke Guo, Yuetao Ma, Wei Hu, Shichao Wu, Jiaxin Zheng, Ming Liu, Yan-Bing He and Feiyu Kang

J. Am. Chem. Soc., 2024
DOI: 10.1021/jacs.4c00976