Advances, practical applications, and future prospects of layered perovskite oxides (LnBaCo2O5+δ) for electrocatalysis reactions

Tian Xia, Ziwei Dong, Yingnan Dou, Qiang Li, Jingping Wang, Liping Sun, Ruiping Deng, Lihua Huo and Hui Zhao

Mater. Chem. Front., 2026, 10, 565
DOI: 10.1039/D5QM00518C

Effective oxygen reduction on A-site substituted LaCuO3−δ: toward air electrodes for SOFCs based on perovskite-type copper oxides

Anna Niemczyk, Zhihong Du, Anna Olszewska, Mateusz Marzec, Marta Gajewska, Konrad Świerczek, Hailei Zhao, Bisham Poudel and Bogdan Dabrowski

J. Mater. Chem. A, 2019, 7, 27403
DOI: 10.1039/C9TA09244G

An innovative approach to design SOFC air electrode materials: high entropy La1−xSrx(Co,Cr,Fe,Mn,Ni)O3−δ(x= 0, 0.1, 0.2, 0.3) perovskites synthesized by the sol–gel method

Juliusz Dąbrowa, Anna Olszewska, Andreas Falkenstein, Christian Schwab, Maria Szymczak, Marek Zajusz, Maciej Moździerz, Andrzej Mikuła, Klaudia Zielińska, Katarzyna Berent, Tomasz Czeppe, Manfred Martin and Konrad Świerczek

J. Mater. Chem. A, 2020, 8, 24455
DOI: 10.1039/D0TA06356H

In silico design and experimental validation of a high-entropy perovskite oxide for SOFC cathodes

Jyotsana Kala, Vicky Dhongde, Subhrajyoti Ghosh, Madhulika Gupta, Suddhasatwa Basu, Brajesh Kumar Mani and M. Ali Haider

J. Mater. Chem. A, 2025, 13, 21916
DOI: 10.1039/D4TA08251F

Enhancing Oxygen Reduction Activity and CO2 Tolerance by a Bismuth Doping Strategy for Solid Oxide Fuel Cell Cathodes

Fangjun Jin, Xiaowei Liu, Yunfeng Tian and Yihan Ling

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202400519

Facet- and defect-dependent activity of perovskites in catalytic evolution of sulfate radicals

Yuxian Wang, Zhaoxu Chi, Chunmao Chen, Chao Su, Daoqing Liu, Ya Liu, Xiaoguang Duan and Shaobin Wang

Applied Catalysis B: Environmental, 2020, 272, 118972
DOI: 10.1016/j.apcatb.2020.118972

Versatile Application of Redox Processes for REBaCoMnO5+δ (RE: La, Pr, Nd, Sm, Gd, and Y) Oxides

Anna Olszewska, Konrad Świerczek, Wojciech Skubida, Zhihong Du, Hailei Zhao and Bogdan Dabrowski

J. Phys. Chem. C, 2019, 123, 48
DOI: 10.1021/acs.jpcc.8b08585

Exploring the Role of Manganese on Structural, Transport, and Electrochemical Properties of NASICON-Na3Fe2–yMny(PO4)3–Cathode Materials for Na-Ion Batteries

Katarzyna Walczak, Bartłomiej Gędziorowski, Andrzej Kulka, Wojciech Zając, Magdalena Ziąbka, Rafał Idczak, Vinh Hung Tran and Janina Molenda

ACS Appl. Mater. Interfaces, 2019, 11, 43046
DOI: 10.1021/acsami.9b10184

Tremendous oxygen capacity, defect equilibration and thermodynamic stability of PrBaMn2-xCoxO6–δ solid solutions

V.S. Kudyakova, B.V. Politov, O.V. Merkulov and A.Yu. Suntsov

Materials Research Bulletin, 2022, 149, 111717
DOI: 10.1016/j.materresbull.2021.111717

Unveiling the Electrocatalytic Activity of the GdBa0.5Sr0.5Co2–xCuxO5+δ (x ≥ 1) Oxygen Electrodes for Solid Oxide Cells

Keyun Li, Konrad Świerczek, Piotr Winiarz, Agnieszka Brzoza-Kos, Anna Stępień, Zhihong Du, Yang Zhang, Kun Zheng, Kacper Cichy, Anna Niemczyk and Yevgeniy Naumovich

ACS Appl. Mater. Interfaces, 2023, 15, 39578
DOI: 10.1021/acsami.3c08667

A study of the novel Cu-based materials as a potential air electrode for high-temperature reversible solid oxide cells

Krystian Machaj, Piotr Winiarz, Anna Niemczyk, Yevgeniy Naumovich, Ryszard Kluczowski, Keyun Li, Kun Zheng and Konrad Świerczek

International Journal of Hydrogen Energy, 2024, 95, 1222
DOI: 10.1016/j.ijhydene.2024.07.383

In situneutron powder diffraction studies

Damian Goonetilleke and Neeraj Sharma

Physical Sciences Reviews, 2021, 6
DOI: 10.1515/psr-2018-0155

Development of novel air electrode materials for the SOFC and SOEC technologies

Anna Niemczyk, Konrad Świerczek, M. Dudek, W. Suwała, S. Łopata and J. Leszczyński

E3S Web Conf., 2019, 108, 01019
DOI: 10.1051/e3sconf/201910801019

A Highly Efficient Bifunctional Electrode Fashioned with In Situ Exsolved NiFe Alloys for Reversible Solid Oxide Cells

Junil Choi, Minho Kim, Song Kyu Kang, Jihoon Kim, Jungseub Ha, Hyun Ho Shin, Taiho Park and Won Bae Kim

ACS Sustainable Chem. Eng., 2022, 10, 7595
DOI: 10.1021/acssuschemeng.2c01360

Medium-Entropy perovskites Sr(FeαTiβCoγMnζ)O3- as promising cathodes for intermediate temperature solid oxide fuel cell

Leyu Shen, Zhihong Du, Yang Zhang, Xu Dong and Hailei Zhao

Applied Catalysis B: Environmental, 2021, 295, 120264
DOI: 10.1016/j.apcatb.2021.120264

Alloy exsolution in co-doped PrBaMn2-xTMxO5+δ (TM = Co and/or Ni) obtained by mechanochemistry

F.J. Gotor, M.J. Sayagués, J. Zamudio-García, D. Marrero-López and F.J. Garcia-Garcia

Journal of Power Sources, 2024, 623, 235395
DOI: 10.1016/j.jpowsour.2024.235395

Fluorine doping for the enhanced electrochemical performance of SrCo0·8Ti0·2O3-based perovskite cathode for Solid Oxide Cells

Zhihong Du, Xu Dong, Tong Wang, Konrad Świerczek and Hailei Zhao

International Journal of Hydrogen Energy, 2025, 99, 35
DOI: 10.1016/j.ijhydene.2024.12.192

LaFeO3 porous hollow micro-spindles for NO2 sensing

Xiao-Dong Zhang, Wen-Lu Zhang, Ze-Xing Cai, Yuan-Kai Li, Yusuke Yamauchi and Xin Guo

Ceramics International, 2019, 45, 5240
DOI: 10.1016/j.ceramint.2018.11.221

SmBa0.5Sr0.5CoCuO5+δ and Sm0.5Ba0.25Sr0.25Co0.5Cu0.5O3-δ oxygen electrode materials for Solid Oxide Fuel Cells: Crystal structure and morphology influence on the electrocatalytic activity

Piotr Winiarz, Ewa A. Sroczyk, Agnieszka Brzoza-Kos, Paweł Czaja, Katarzyna Kapusta and Konrad Świerczek

Acta Materialia, 2024, 277, 120186
DOI: 10.1016/j.actamat.2024.120186

Evaluation of calcium codoping in double perovskite PrBaCo2O5+ as cathode material for IT-SOFCs

Wei Xia, Xianglin Liu, Fangjun Jin, Xuelin Jia, Yu Shen and Jinhua Li

Electrochimica Acta, 2020, 364, 137274
DOI: 10.1016/j.electacta.2020.137274

Mn-rich SmBaCo0.5Mn1.5O5+δ double perovskite cathode material for SOFCs

Anna Olszewska, Yang Zhang, Zhihong Du, Mateusz Marzec, Konrad Świerczek, Hailei Zhao and Bogdan Dabrowski

International Journal of Hydrogen Energy, 2019, 44, 27587
DOI: 10.1016/j.ijhydene.2019.08.254

Enhancing Electrochemical Performance of Reversible Solid Oxide Cells with Double Element-Deficient Pr0.97Ba0.97Co1.5Fe0.5O5+δ Oxygen Electrodes

Xurui Huang, Fengyuan Yu, Ying Yang, Peng Dai, Yuan Tang, Jun Jiang, Keying Feng, Mengyun Zhang, Yunfeng Tian and Bo Chi

Energy Fuels, 2024, 38, 21432
DOI: 10.1021/acs.energyfuels.4c03955

Promoting bifunctional electrocatalytic activity and redox kinetics of praseodymium-based perovskite ceramic for electrochemical energy conversion and storage

Ping Li, Jianwei Du, Chen Li, Qiyu Yang, Junkai Zhang, Fei Yan, Xiaofeng Tong and Ligang Wang

Sustainable Energy Technologies and Assessments, 2024, 72, 104067
DOI: 10.1016/j.seta.2024.104067

Properties of Solid Oxide Fuel Cells Based on A-Site Cation-Deficient Double Perovskite Y1–XBa0.5Sr0.5Fe2O6–δ Fiber Materials

Guofeng Wang, Lizhong Wang and Jianbo Liu

Journal of Nanoelectronics and Optoelectronics, 2024, 19, 811
DOI: 10.1166/jno.2024.3637

High-performance, high-entropy perovskite cathodes for low-temperature solid-oxide fuel cells

Juliusz Dąbrowa, Klaudia Zielińska, Marek Zajusz, Margarita Nowakowska, Maria Szymczak, Maciej Moździerz, Andrzej Mikuła, Keyun Li, Paweł Czaja, Christian Schwab, Andreas Falkenstein, Manfred Martin and Konrad Świerczek

Applied Catalysis B: Environment and Energy, 2026, 391, 126571
DOI: 10.1016/j.apcatb.2026.126571

Facile synthesis of uniform LaSrCoO4 using amino acid-derived surfactant and its utilization as an excellent cathode material for intermediate temperature solid oxide fuel cell

Fang Meng, Chenmin Sun, Jincen Shi, Hongjie Zhang, Bin Xu and Yuanhua Ding

International Journal of Hydrogen Energy, 2019, 44, 1122
DOI: 10.1016/j.ijhydene.2018.11.015

ReBaCo2-xMnxO5+δ (Re: rare earth element) layered perovskites for application as cathodes in Solid Oxide Fuel Cells

Anna Olszewska, Konrad Świerczek, M. Dudek, W. Suwała, S. Łopata and J. Leszczyński

E3S Web Conf., 2019, 108, 01020
DOI: 10.1051/e3sconf/201910801020

High-Entropy Perovskite as a High-Performing Chromium-Tolerant Cathode for Solid Oxide Fuel Cells

Zhongqiu Li, Bo Guan, Fang Xia, Jiuyuan Nie, Wenyuan Li, Liang Ma, Wei Li, Lingfeng Zhou, Yi Wang, Hanchen Tian, Jian Luo, Yan Chen, Matthew Frost, Ke An and Xingbo Liu

ACS Appl. Mater. Interfaces, 2022, 14, 24363
DOI: 10.1021/acsami.2c03657

High-entropy approach to double perovskite cathode materials for solid oxide fuel cells: Is multicomponent occupancy in (La,Pr,Nd,Sm,Gd)BaCo2O5+δ affecting physicochemical and electrocatalytic properties?

Juliusz Dąbrowa, Anna Stępień, Maria Szymczak, Marek Zajusz, Paweł Czaja and Konrad Świerczek

Front. Energy Res., 2022, 10
DOI: 10.3389/fenrg.2022.899308

Effects of rare earth doping on electrochemical properties of NdBaCo2O6- cathode materials

Yu Anbo, Xia Tian, Sun Liping, Li Qiang, Huo Lihua and Zhao Hui

Journal of Alloys and Compounds, 2020, 837, 155563
DOI: 10.1016/j.jallcom.2020.155563

Mn-doping induced phase segregation of air electrodes enables high-performance and durable reversible protonic ceramic cells

Xiaofeng Chen, Yixuan Huang, Wanbin Lin, Jiaojiao Xia, Xirui Zhang, Wenjie Gong, Chuqian Jian, Hao Liu, Jiacheng Zeng, Jiang Liu and Yu Chen

Chinese Journal of Catalysis, 2026, 81, 333
DOI: 10.1016/S1872-2067(25)64907-2

Peculiar Properties of Electrochemically Oxidized SmBaCo2−xMnxO5+δ (x = 0; 0.5 and 1) A-Site Ordered Perovskites

Anna Olszewska, Konrad Świerczek and Anna Niemczyk

Crystals, 2020, 10, 205
DOI: 10.3390/cryst10030205

Enhanced oxygen mobility by doping Yb in BaGd1-xYbxMn2O5+δ double perovskite-structured oxygen storage materials

Kun Zheng

Solid State Ionics, 2019, 335, 103
DOI: 10.1016/j.ssi.2019.03.001

Stable and active nanofiber electrodes tuned via a negative thermal expansion strategy for designing high-performance solid oxide fuel cells

Piotr Winiarz, Jakub Lach, Yihan Ling, Marta Gajewska, Ming Chen, Mateusz Marzec and Kun Zheng

Applied Catalysis B: Environment and Energy, 2026, 382, 125950
DOI: 10.1016/j.apcatb.2025.125950

Influence of Doping on the Transport Properties of Y1−xLnxMnO3+δ (Ln: Pr, Nd)

Kacper Cichy and Konrad Świerczek

Crystals, 2021, 11, 510
DOI: 10.3390/cryst11050510

SrCo0.8Ti0.1Ta0.1O3-δ perovskite: A new highly active and durable cathode material for intermediate-temperature solid oxide fuel cells

Hongxia Gu, Meigui Xu, Yufei Song, Chuan Zhou, Chao Su, Wei Wang, Ran Ran, Wei Zhou and Zongping Shao

Composites Part B: Engineering, 2021, 213, 108726
DOI: 10.1016/j.compositesb.2021.108726

Positive effects of calcium-doping on the cathode performance of layered perovskite Eu1-Ca BaCo2O5+ for intermediate-temperature solid oxide fuel cells

Wanbo Xiang, Jingping Wang, Shuli Li, Tian Xia and Guixiang Wang

Journal of Alloys and Compounds, 2019, 801, 220
DOI: 10.1016/j.jallcom.2019.06.143

LaMnO3/Co3O4 nanocomposite for enhanced triethylamine sensing properties

Jian Zhang, Yanping Chen, Ling Li, Xue Chen, Wenya An, Xiujuan Qian and Yuye Tao

Journal of Rare Earths, 2024, 42, 733
DOI: 10.1016/j.jre.2023.05.007

Synthesis of samarium orthoferrite-based perovskite nanoparticles as a turn-on fluorescent probe for trace level detection of picric acid

Zohreh Kayhomayun, Kamal Ghani and Kiomars Zargoosh

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2022, 281, 121627
DOI: 10.1016/j.saa.2022.121627

Preparation of SmBa0.5Sr0.5Fe2-XZnXO5+δ Nanofiber-Based Cathodes for Their Application in Solid Oxide Fuel Cells

Hong Shi, Lanhang Zhang, Lizhong Wang and Shihao Yu

Journal of Nanoelectronics and Optoelectronics, 2025, 20, 469
DOI: 10.1166/jno.2025.3757

Multicomponent Gd1−xSmxBa0.5Sr0.5CoCuO5+δ double perovskites as oxygen electrodes for solid oxide cells: Effect of chemical composition and electrospun morphology

Jacek Winiarski, Piotr Winiarz and Konrad Świerczek

Int J Miner Metall Mater, 2025, 32, 2628
DOI: 10.1007/s12613-025-3262-z

Probing Zr Substituting Effects on the Oxygen Reduction Reaction of Fe-Based Double Perovskite Cathodes for Solid Oxide Fuel Cells

Chengzhi Sun, Yu Kong, Yongchao Niu, Xiaoju Yin and Naiqing Zhang

ACS Appl. Energy Mater., 2022, 5, 4486
DOI: 10.1021/acsaem.1c04080

Synthesis and Properties of the Gallium-Containing Ruddlesden-Popper Oxides with High-Entropy B-Site Arrangement

Juliusz Dąbrowa, Jan Adamczyk, Anna Stępień, Marek Zajusz, Karolina Bar, Katarzyna Berent and Konrad Świerczek

Materials, 2022, 15, 6500
DOI: 10.3390/ma15186500

High-Performance and CO2-Durable Composite Cathodes toward Electrocatalytic Oxygen Reduction: Ce0.8Sm0.2O1.9 Nanoparticle-Decorated Double Perovskite EuBa0.5Sr0.5Co2O5+δ

Lu Xing, Tian Xia, Qiang Li, Hui Zhao, Liping Sun and Li-Hua Huo

ACS Sustainable Chem. Eng., 2019, 7, 17907
DOI: 10.1021/acssuschemeng.9b04533