Selective solvent conditions influence sequence development and supramolecular assembly in step-growth copolymerization

Ryan L. Hamblin, Nhu Q. Nguyen and Kateri H. DuBay

Soft Matter, 2022, 18, 943
DOI: 10.1039/D1SM01571K

Ultra-low volume oxygen tolerant photoinduced Cu-RDRP

Evelina Liarou, Athina Anastasaki, Richard Whitfield, Carmelo E. Iacono, Georgios Patias, Nikolaos G. Engelis, Arkadios Marathianos, Glen R. Jones and David M. Haddleton

Polym. Chem., 2019, 10, 963
DOI: 10.1039/C8PY01720D

Recent advances in the synthesis and shell-sheddable disassembly of acid/glutathione-degradable block copolymer nanoassemblies for drug delivery

Brandon Andrade-Gagnon and Jung Kwon Oh

Polym. Chem., 2024, 15, 3709
DOI: 10.1039/D4PY00660G

Progress, challenges and future directions of heterocycles as building blocks in iterative methodologies towards sequence-defined oligomers and polymers

Stephen A. Hill, Robert Steinfort and Laura Hartmann

Polym. Chem., 2021, 12, 4439
DOI: 10.1039/D1PY00425E

Tuning dispersity of linear polymers and polymeric brushes grown from nanoparticles by atom transfer radical polymerization

Rongguan Yin, Zongyu Wang, Michael R. Bockstaller and Krzysztof Matyjaszewski

Polym. Chem., 2021, 12, 6071
DOI: 10.1039/D1PY01178B

Sequence-regulated vinyl polymers via iterative atom transfer radical additions and acyclic diene metathesis polymerization

Masato Miyajima, Kotaro Satoh and Masami Kamigaito

Polym. Chem., 2021, 12, 423
DOI: 10.1039/D0PY01564D

Predicting self-assembly of sequence-controlled copolymers with stochastic sequence variation

Kaleigh A. Curtis, Antonia Statt and Wesley F. Reinhart

Soft Matter, 2025, 21, 2143
DOI: 10.1039/D4SM01219D

Bottom-up design of model network elastomers and hydrogels from precise star polymers

Guido Creusen, Ardeshir Roshanasan, Javier Garcia Lopez, Kalina Peneva and Andreas Walther

Polym. Chem., 2019, 10, 3740
DOI: 10.1039/C9PY00731H

Discrete multifunctional sequence-defined oligomers with controlled chirality

Jie Li, Maxime Leclercq, Mathieu Fossepré, Mathieu Surin, Karine Glinel, Alain M. Jonas and Antony E. Fernandes

Polym. Chem., 2020, 11, 4040
DOI: 10.1039/D0PY00537A

Tailoring polymer dispersity and shape of molecular weight distributions: methods and applications

Richard Whitfield, Nghia P. Truong, Daniel Messmer, Kostas Parkatzidis, Manon Rolland and Athina Anastasaki

Chem. Sci., 2019, 10, 8724
DOI: 10.1039/C9SC03546J

‘Sacrificial’ supramolecular assembly and pressure-induced polymerization: toward sequence-defined functionalized nanothreads

Margaret C. Gerthoffer, Sikai Wu, Bo Chen, Tao Wang, Steven Huss, Shalisa M. Oburn, Vincent H. Crespi, John V. Badding and Elizabeth Elacqua

Chem. Sci., 2020, 11, 11419
DOI: 10.1039/D0SC03904G

Controlled polymers: accessing new platforms for material synthesis

Keri L. Kaligian and Melissa M. Sprachman

Mol. Syst. Des. Eng., 2019, 4, 144
DOI: 10.1039/C8ME00095F

Recent advances in the self-assembly of sparsely grafted amphiphilic copolymers in aqueous solution

Yusuke Sakamoto and Tomoki Nishimura

Polym. Chem., 2022, 13, 6343
DOI: 10.1039/D2PY01018F

Sequential and alternating RAFT single unit monomer insertion: model trimers as the guide for discrete oligomer synthesis

Ruizhe Liu, Lei Zhang, Zixuan Huang and Jiangtao Xu

Polym. Chem., 2020, 11, 4557
DOI: 10.1039/D0PY00390E

Enhanced synthesis of multiblock copolymers via acid-triggered RAFT polymerization

Maria-Nefeli Antonopoulou, Nghia P. Truong and Athina Anastasaki

Chem. Sci., 2024, 15, 5019
DOI: 10.1039/D4SC00399C

Sequence-defined oligoampholytes using hydrolytically stable vinyl sulfonamides: design and UCST behaviour

Chiel Mertens, Resat Aksakal, Nezha Badi and Filip E. Du Prez

Polym. Chem., 2021, 12, 4193
DOI: 10.1039/D1PY00662B

The challenges of controlling polymer synthesis at the molecular and macromolecular level

Karen Hakobyan, Jiangtao Xu and Markus Müllner

Polym. Chem., 2022, 13, 5431
DOI: 10.1039/D1PY01581H

SI-PET-RAFT in flow: improved control over polymer brush growth

Andriy R. Kuzmyn, Martijn van Galen, Barend van Lagen and Han Zuilhof

Polym. Chem., 2023, 14, 3357
DOI: 10.1039/D3PY00488K

Bromoform-assisted aqueous free radical polymerisation: a simple, inexpensive route for the preparation of block copolymers

Helena J. Hutchins-Crawford, Padarat Ninjiaranai, Matthew J. Derry, Robert Molloy, Brian J. Tighe and Paul D. Topham

Polym. Chem., 2021, 12, 4317
DOI: 10.1039/D1PY00672J

Chemical recycling of bromine-terminated polymers synthesized by ATRP

Stella Afroditi Mountaki, Richard Whitfield, Kostas Parkatzidis, Maria-Nefeli Antonopoulou, Nghia P. Truong and Athina Anastasaki

RSC Appl. Polym., 2024, 2, 275
DOI: 10.1039/D3LP00279A

How does the single unit monomer insertion technique promote kinetic analysis of activation and initiation in photo-RAFT processes?

Lei Zhang, Ruizhe Liu, Zixuan Huang and Jiangtao Xu

Polym. Chem., 2021, 12, 581
DOI: 10.1039/D0PY01413C

A sequential native chemical ligation – thiol-Michael addition strategy for polymer–polymer ligation

Alexander Rajakanthan, Patrick A. J. M. de Jongh, James S. Town, Paul Wilson and Kristian Kempe

Polym. Chem., 2019, 10, 5242
DOI: 10.1039/C9PY01198F

Analysis of sequence-defined oligomers through Advanced Polymer Chromatography™ – mass spectrometry hyphenation

Marie-Theres Berg, Chiel Mertens, Filip Du Prez, Thomas D. Kühne, Artjom Herberg and Dirk Kuckling

RSC Adv., 2020, 10, 35245
DOI: 10.1039/D0RA06419J

PET-RAFT single unit monomer insertion of β-methylstyrene derivatives: RAFT degradation and reaction selectivity

Lei Zhang, Ruizhe Liu, Shiyang Lin and Jiangtao Xu

Chem. Commun., 2021, 57, 10759
DOI: 10.1039/D1CC03927J

Multiblock copolymer synthesisviaRAFT emulsion polymerization

Glenn K.K. Clothier, Thiago R. Guimarães, Steven W. Thompson, Julia Y. Rho, Sébastien Perrier, Graeme Moad and Per B. Zetterlund

Chem. Soc. Rev., 2023, 52, 3438
DOI: 10.1039/D2CS00115B

Quasi-monodisperse polymer libraries via flash column chromatography: correlating dispersity with glass transition

Joris J. Haven and Tanja Junkers

Polym. Chem., 2019, 10, 679
DOI: 10.1039/C8PY01603H

Precisely synthesized segmented polyurethanes toward block sequence-controlled drug delivery

Yuanqing Song, Chuandong Sun, Chenxu Tian, Hao Ming, Yanjun Wang, Wenkai Liu, Nan He, Xueling He, Mingming Ding, Jiehua Li, Feng Luo, Hong Tan and Qiang Fu

Chem. Sci., 2022, 13, 5353
DOI: 10.1039/D1SC06457F

Sequence-defined nucleobase containing oligomers via reversible addition–fragmentation chain transfer single monomer addition

Lowie Maes, Daniel Massana Roqeuro, Louis M. Pitet, Peter Adriaensens and Tanja Junkers

Polym. Chem., 2020, 11, 2027
DOI: 10.1039/C9PY01853K

Precise control of single unit monomer radical addition with a bulky tertiary methacrylate monomer toward sequence-defined oligo- or poly(methacrylate)s via the iterative process

Dongyoung Oh, Mitsuo Sawamoto and Makoto Ouchi

Polym. Chem., 2019, 10, 1998
DOI: 10.1039/C9PY00096H

Elucidation of the properties of discrete oligo(meth)acrylates

Joris J. Haven, Jeroen De Neve, Andres Castro Villavicencio and Tanja Junkers

Polym. Chem., 2019, 10, 6540
DOI: 10.1039/C9PY01494B

Accelerating copolymer inverse design using monte carlo tree search

Tarak K. Patra, Troy D. Loeffler and Subramanian K. R. S. Sankaranarayanan

Nanoscale, 2020, 12, 23653
DOI: 10.1039/D0NR06091G

Direct comparison of solution and solid phase synthesis of sequence-defined macromolecules

Joshua O. Holloway, Katharina S. Wetzel, Steven Martens, Filip E. Du Prez and Michael A. R. Meier

Polym. Chem., 2019, 10, 3859
DOI: 10.1039/C9PY00558G

Effect of backbone flexibility on covalent template-directed synthesis of linear oligomers

Diego Núñez-Villanueva and Christopher A. Hunter

Org. Biomol. Chem., 2022, 20, 8285
DOI: 10.1039/D2OB01627C

Advances and opportunities in synthesis of flame retardant polymers via reversible deactivation radical polymerization

Agata Hochół, Monika Flejszar and Paweł Chmielarz

Polymer Degradation and Stability, 2023, 214, 110414
DOI: 10.1016/j.polymdegradstab.2023.110414

Discreteness and dispersity in the design of polymeric materials

Alessio Lo Bocchiaro, Carlos Pavón, Francesca Lorandi and Edmondo M. Benetti

Progress in Polymer Science, 2025, 167, 101992
DOI: 10.1016/j.progpolymsci.2025.101992

Continuous color tuning of single-fluorophore emission via polymerization-mediated through-space charge transfer

Suiying Ye, Tian Tian, Andrew J. Christofferson, Sofia Erikson, Jakub Jagielski, Zhi Luo, Sudhir Kumar, Chih-Jen Shih, Jean-Christophe Leroux and Yinyin Bao

Sci. Adv., 2021, 7
DOI: 10.1126/sciadv.abd1794

An Arbitrarily Regulated Monomer Sequence in Multi‐Block Copolymer Synthesis by Frustrated Lewis Pairs

Yi Wan, Jianghua He and Yuetao Zhang

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202218248

Rapid and Scalable Access to Sequence‐Controlled DHDM Multiblock Copolymers by FLP Polymerization

Yun Bai, Huaiyu Wang, Jianghua He and Yuetao Zhang

Angew Chem Int Ed, 2020, 59, 11613
DOI: 10.1002/anie.202004013

Sequence‐defined Pareto frontier of a copolymer structure

Ashwin A. Bale, Sachin M. B. Gautham and Tarak K. Patra

Journal of Polymer Science, 2022, 60, 2100
DOI: 10.1002/pol.20220088

Theoretical Design of Photofunctional Molecular Aggregates for Optical Properties: An Inverse Design Approach

Takafumi Shiraogawa and Masahiro Ehara

J. Phys. Chem. C, 2020, 124, 13329
DOI: 10.1021/acs.jpcc.0c01730

Self-assembly of ABCBA Linear Pentablock Terpolymers

Lei Guo, Junting Xu and Binyang Du

Polymer Reviews, 2024, 64, 1
DOI: 10.1080/15583724.2023.2178008

1H PFG‐NMR Diffusion Study on a Sequence‐Defined Macromolecule: Confirming Monodispersity

Xiaoai Guo, Katharina S. Wetzel, Susanne C. Solleder, Sebastian Spann, Michael A. R. Meier, Manfred Wilhelm, Burkhard Luy and Gisela Guthausen

Macro Chemistry & Physics, 2019, 220
DOI: 10.1002/macp.201900155

Effect of Film Thickness on the Self-Assembly of CBABC Symmetric Pentablock Terpolymer Melts under 1D Confinement: A Dissipative Particle Dynamic Study

Yingying Guo

Materials, 2023, 16, 6862
DOI: 10.3390/ma16216862

Reversing RAFT Polymerization: Near-Quantitative Monomer Generation Via a Catalyst-Free Depolymerization Approach

Hyun Suk Wang, Nghia P. Truong, Zhipeng Pei, Michelle L. Coote and Athina Anastasaki

J. Am. Chem. Soc., 2022, 144, 4678
DOI: 10.1021/jacs.2c00963

Controlled Ring-Opening Polymerization of O-Carboxyanhydrides to Synthesize Functionalized Poly(α-Hydroxy Acids)

Xiaoqian Wang, Ai Lin Chin and Rong Tong

Organic Materials, 2021, 03, 041
DOI: 10.1055/s-0040-1722698

Solution Self‐Assembly of Branched Macromolecules Obtained via Iterative OPE Synthesis and the Passerini Three‐Component Reaction

Sandra Wegelin and Michael A. R. Meier

Macro Chemistry & Physics, 2024, 225
DOI: 10.1002/macp.202300337

Polymer Nanoparticles with Uniform Monomer Sequences for Sequence‐Specific Peptide Recognition

Yusuke Saito, Ryutaro Honda, Sotaro Akashi, Hinata Takimoto, Masanori Nagao, Yoshiko Miura and Yu Hoshino

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202206456

Information propagation through enzyme-free catalytic templating of DNA dimerization with weak product inhibition

Javier Cabello-Garcia, Rakesh Mukherjee, Wooli Bae, Guy-Bart V. Stan and Thomas E. Ouldridge

Nat. Chem., 2025, 17, 1179
DOI: 10.1038/s41557-025-01831-x

Microphase Separation Behavior of Poly(4‐Vinylpyridine)‐b‐Poly(Styrene)‐b‐Poly(Ethylene Oxide)‐b‐Poly(Styrene)‐b‐Poly(4‐Vinylpyridine) Pentablock Terpolymers in Bulk

Lei Guo, Ruohan Zhang, Junting Xu and Binyang Du

Journal of Polymer Science, 2026, 64, 1120
DOI: 10.1002/pol.20251217

Effects of Cyclic Glycopolymers Molecular Mobility on their Interactions with Lectins

Wenkang Jin, Masanori Nagao, Yusuke Kumon, Hikaru Matsumoto, Yu Hoshino and Yoshiko Miura

ChemPlusChem, 2024, 89
DOI: 10.1002/cplu.202400136

Investigating the Effect of End-Group, Molecular Weight, and Solvents on the Catalyst-Free Depolymerization of RAFT Polymers: Possibility to Reverse the Polymerization of Heat-Sensitive Polymers

Hyun Suk Wang, Nghia P. Truong, Glen R. Jones and Athina Anastasaki

ACS Macro Lett., 2022, 11, 1212
DOI: 10.1021/acsmacrolett.2c00506

Precise Polymer Synthesis by Autonomous Self‐Optimizing Flow Reactors

Maarten Rubens, Jeroen H. Vrijsen, Joachim Laun and Tanja Junkers

Angew Chem Int Ed, 2019, 58, 3183
DOI: 10.1002/anie.201810384

Streamlining the Generation of Advanced Polymer Materials Through the Marriage of Automation and Multiblock Copolymer Synthesis in Emulsion

Glenn K. K. Clothier, Thiago R. Guimarães, Steven W. Thompson, Shaun C. Howard, Benjamin W. Muir, Graeme Moad and Per B. Zetterlund

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202320154

Electronically Governed ROMP: Expanding Sequence Control for Donor–Acceptor Conjugated Polymers

Stephen J. Koehler, Jinzhen Hu and Elizabeth Elacqua

Synlett, 2020, 31, 1435
DOI: 10.1055/s-0040-1707180

Multifactor Control of Vinyl Monomer Sequence, Molecular Weight, and Tacticity via Iterative Radical Additions and Olefin Metathesis Reactions

Masato Miyajima, Kotaro Satoh, Takahiro Horibe, Kazuaki Ishihara and Masami Kamigaito

J. Am. Chem. Soc., 2020, 142, 18955
DOI: 10.1021/jacs.0c09289

Unusual Radical Copolymerization of Suprabulky Methacrylate with N-Hydroxysuccinmide Acrylate: Facile Syntheses of Alternating-Rich Copolymers of Methacrylic Acid and N-Alkyl Acrylamide

Dongyoung Oh, Yousuke Furuya and Makoto Ouchi

Macromolecules, 2019, 52, 8577
DOI: 10.1021/acs.macromol.9b01807

Polymer Nanoparticles with Uniform Monomer Sequences for Sequence‐Specific Peptide Recognition

Yusuke Saito, Ryutaro Honda, Sotaro Akashi, Hinata Takimoto, Masanori Nagao, Yoshiko Miura and Yu Hoshino

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202206456

Toward the Rational Design of Organic Catalysts for Organocatalysed Atom Transfer Radical Polymerisation

Zhilei Wang, Chenyu Wu and Wenjian Liu

Polymers, 2024, 16, 323
DOI: 10.3390/polym16030323

Characteristic System Time Scales Can Influence the Collective Sequence Development of Nematically Ordered Copolymers

Ryan L. Hamblin, Zhongmin Zhang and Kateri H. DuBay

Macromolecules, 2024, 57, 9984
DOI: 10.1021/acs.macromol.4c01047

A Support-Free Strategy to Synthesize Sequence-Defined Macromolecules Using Solvent-Resistant Nanofiltration

Zahra Bozorgmehr, Janine Peeters, Wout Milis, Laurens A. J. Rutgeerts, Nezha Badi, Xiaoyu Tan, Cédric Van Goethem, Sareh Rezaei Hosseinabadi, Filip E. Du Prez, Guy Koeckelberghs and Ivo F. J. Vankelecom

Precision Chemistry, 2026
DOI: 10.1021/prechem.5c00409

SIRT3-activating, biodegradable poly-honokiol with high drug loading for thoracic aortic dissection therapy

Xi’nan Qiao, Daquan Wang, Hanzhao Zhu, Bin Zhang, He Sun, Jiali Wang, Gang Tan, Liqing Jiang, Xiangyan Peng, Liyun Zhang, Longteng Wang, Siyu Han, Lingjie Meng and Weixun Duan

Journal of Advanced Research, 2025
DOI: 10.1016/j.jare.2025.11.028

Quantitative preparation of multiblock glycopolymers bearing glycounits at the terminal segments by aqueous reversible addition–fragmentation chain transfer polymerization of acrylamide monomers

Masanori Nagao, Yu Hoshino and Yoshiko Miura

J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 857
DOI: 10.1002/pola.29344

Reversible On/Off Switching of Lactide Cyclopolymerization with a Redox-Active Formazanate Ligand

Folkert de Vries and Edwin Otten

ACS Catal., 2022, 12, 4125
DOI: 10.1021/acscatal.1c05689

Protein‐Inspired Control over Synthetic Polymer Folding for Structured Functional Nanoparticles in Water

Stefan Wijker and Anja R. A. Palmans

ChemPlusChem, 2023, 88
DOI: 10.1002/cplu.202300260

Single-Molecule Polypeptoid Stretching Reveals the Effects of Charge Sequence on Chain Conformation

Hoang P. Truong, Shawn Mengel, Beihang Yu, Rachel A. Segalman and Omar A. Saleh

Macromolecules, 2023, 56, 8558
DOI: 10.1021/acs.macromol.3c01221

Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization

Kotaro Satoh, Kenta Ishizuka, Tsuyoshi Hamada, Masato Handa, Tomohiro Abe, Satoshi Ozawa, Masato Miyajima and Masami Kamigaito

Macromolecules, 2019, 52, 3327
DOI: 10.1021/acs.macromol.9b00676

Micellar Organocatalysis Using Smart Polymer Supports: Influence of Thermoresponsive Self-Assembly on Catalytic Activity

Xiaoqian Yu, Artjom Herberg and Dirk Kuckling

Polymers, 2020, 12, 2265
DOI: 10.3390/polym12102265

Streamlining the Generation of Advanced Polymer Materials Through the Marriage of Automation and Multiblock Copolymer Synthesis in Emulsion

Glenn K. K. Clothier, Thiago R. Guimarães, Steven W. Thompson, Shaun C. Howard, Benjamin W. Muir, Graeme Moad and Per B. Zetterlund

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202320154

High Molecular Weight Uniform Polymers Encoding Octal Sequences by Passerini Iterative Exponential Growth

Valene Wang, Su Bin Park, Soo Jeong Lee, Mo Beom Koo and Kyoung Taek Kim

J. Am. Chem. Soc., 2025, 147, 780
DOI: 10.1021/jacs.4c13528

Lighting Up the Non‐conjugated Polymers in Full Color via Domino‐Effect Triggered Emission

Jie Liu, Huacan Wu, Bo Chen, Chuang Zhang, Mengdi Zuo, Jialong Hu, Yu Dong, Donghui Wang, Shiyu Feng and Weiguo Huang

Advanced Materials, 2026, 38
DOI: 10.1002/adma.202510125

Ring-Opening Alternating Copolymerization of O-Carboxyanhydrides of Lactic Acid and Malic Acid Using Hafnium Alkoxide Initiators with Different Stereo Selectivities and Activities

Zhaowei Jia, Sicheng Chen, Jinxing Jiang, Xiaoyang Mao, Xiaobo Pan and Jincai Wu

Inorg. Chem., 2020, 59, 10353
DOI: 10.1021/acs.inorgchem.0c01499

Progress in ATRP-derived materials for biomedical applications

Mohsen Khodadadi Yazdi, Payam Zarrintaj, Mohammad Reza Saeb, Masoud Mozafari and Sidi A. Bencherif

Progress in Materials Science, 2024, 143, 101248
DOI: 10.1016/j.pmatsci.2024.101248

Achieving Comprehensive Toughening of Polylactide through a Monomer-Enabled Hierarchical Design Based on Asymmetric Cyclic Diesters

Yeqi Du, Guanyu Liu, Linyao Zhou, Jinbo Hu, Wenbo Wang, Xinchao Bian, Ranlong Duan and Xuesi Chen

Macromolecules, 2026, 59, 5545
DOI: 10.1021/acs.macromol.5c03165

Post-polymerization modification of Poly(vinylcyclopropanes): A potential route to periodic copolymers

Denis H. Seuyep Ntoukam, Hatice Mutlu and Patrick Theato

European Polymer Journal, 2020, 122, 109319
DOI: 10.1016/j.eurpolymj.2019.109319

N-substituted 1,8-naphtalene imide-based (macro)initiator for investigation of photochemically induced ATRP process

Mária Gurská, Anita Eckstein-Andicsová, Jana Nováčiková and Jaroslav Mosnáček

European Polymer Journal, 2025, 228, 113789
DOI: 10.1016/j.eurpolymj.2025.113789

One-Pot Nonisocyanate Synthesis of Sequence-Controlled Poly(hydroxy urethane)s from a Bis(six-membered cyclic carbonate) and Two Different Diamines

Naoki Ousaka and Takeshi Endo

Macromolecules, 2021, 54, 2059
DOI: 10.1021/acs.macromol.1c00045

Yttrium‐Mediated Ring‐Opening Copolymerization of Oppositely Configurated 4‐Alkoxymethylene‐β‐Propiolactones: Effective Access to Highly Alternated Isotactic Functional PHAs

Romain Ligny, Sophie M. Guillaume and Jean‐François Carpentier

Chemistry A European J, 2019, 25, 6412
DOI: 10.1002/chem.201900413

Opportunities, Challenges, and Pitfalls in Making, Characterizing, and Understanding Polymer Brushes

Christian W. Pester, Harm-Anton Klok and Edmondo M. Benetti

Macromolecules, 2023, 56, 9915
DOI: 10.1021/acs.macromol.3c01292

Molecular Bottle Brushes with Positioned Selenols: Extending the Toolbox of Oxidative Single Polymer Chain Folding with Conformation Analysis by Atomic Force Microscopy

Emmanuelle Schué, Alexey Kopyshev, Jean‐François Lutz and Hans G. Börner

Journal of Polymer Science, 2020, 58, 154
DOI: 10.1002/pola.29496

Using Nitroxides To Model the Ion Mobility Behavior of Nitroxide-Ended Oligomers: A Bottom-up Approach To Predict Mobility Separation

Isaure Sergent, Thibault Schutz, Laurence Oswald, Georgette Obeid, Jean-François Lutz and Laurence Charles

J. Am. Soc. Mass Spectrom., 2024, 35, 534
DOI: 10.1021/jasms.3c00393

Protecting-Group-Free Iterative Exponential Growth Method for Synthesizing Sequence-Defined Polymers

Zi Li, Xiangzhu Ren, Peng Sun, Hao Ding, Shumu Li, Yilin Zhao and Ke Zhang

ACS Macro Lett., 2021, 10, 223
DOI: 10.1021/acsmacrolett.0c00812

Programmable Macrocyclic Enoate-Mediated Regioselective ROMP for Sequence-Controlled Polymer Synthesis

Ying Wang, Yiyang Liang, Jianhua Tang, Xin Min, Zhenyang Luo and Ye Sha

ACS Macro Lett., 2025, 14, 1114
DOI: 10.1021/acsmacrolett.5c00468

Mimicking DNA Functions with Abiotic, Sequence-Defined Polymers

Samuel C. Leguizamon and Timothy F. Scott

Polymer Reviews, 2022, 62, 626
DOI: 10.1080/15583724.2021.2014519

Engineering the atomic structure of sequence-defined peptoid polymers and their assemblies

Sunting Xuan and Ronald N. Zuckermann

Polymer, 2020, 202, 122691
DOI: 10.1016/j.polymer.2020.122691

Deconstructing Oligomer Distributions: Discrete Species and Artificial Distributions

Jeroen De Neve, Joris J. Haven, Simon Harrisson and Tanja Junkers

Angew Chem Int Ed, 2019, 58, 13869
DOI: 10.1002/anie.201906842

A Transformable and Bulky Methacrylate Monomer That Enables the Synthesis of an MMA‐nBA Alternating Copolymer: Sequence‐Dependent Self‐Healing Properties

Haiwang Lai, Changming Jin, Junsu Park, Ryohei Ikura, Yoshinori Takashima and Makoto Ouchi

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202218597

Understanding dispersity control in photo‐atom transfer radical polymerization: Effect of degree of polymerization and kinetic evaluation

Manon Rolland, Victoria Lohmann, Richard Whitfield, Nghia P. Truong and Athina Anastasaki

Journal of Polymer Science, 2021, 59, 2502
DOI: 10.1002/pol.20210319

The current science of sequence-defined macromolecules

Karen Hakobyan, Benjamin B. Noble and Jiangtao Xu

Progress in Polymer Science, 2023, 147, 101754
DOI: 10.1016/j.progpolymsci.2023.101754

Role of N-substituents of maleimides on penultimate unit effect for sequence control during radical copolymerization

Suguru Terada and Akikazu Matsumoto

Polym J, 2019, 51, 1137
DOI: 10.1038/s41428-019-0227-y

Adjacent cationic–aromatic sequences yield strong electrostatic adhesion of hydrogels in seawater

Hailong Fan, Jiahui Wang, Zhen Tao, Junchao Huang, Ping Rao, Takayuki Kurokawa and Jian Ping Gong

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-13171-9

Sequence-Defined Synthetic Polymers for New-Generation Functional Biomaterials

Zhengyu Deng, Qiangqiang Shi, Jiajia Tan, Jinming Hu and Shiyong Liu

ACS Materials Lett., 2021, 3, 1339
DOI: 10.1021/acsmaterialslett.1c00358

Visible Light Photoiniferter Polymerization for Dispersity Control in High Molecular Weight Polymers

Qingchi Ma, Greg G. Qiao and Zesheng An

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202314729

Correlation between Self-Folding Behavior of Amphiphilic Polymers and Their Molecular Flexibility

Masanori Nagao and Yoshiko Miura

ACS Macro Lett., 2023, 12, 733
DOI: 10.1021/acsmacrolett.3c00182

A Transformable and Bulky Methacrylate Monomer That Enables the Synthesis of an MMA‐nBA Alternating Copolymer: Sequence‐Dependent Self‐Healing Properties

Haiwang Lai, Changming Jin, Junsu Park, Ryohei Ikura, Yoshinori Takashima and Makoto Ouchi

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202218597

Solvent‐Dependent Sequence‐Controlled Copolymerization of Lactones: Tailoring Material Properties from Robust Plastics to Tough Elastomers

Chaoqun Weng, Xiao Li and Xiaoyan Tang

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202415388

Precise Polymer Synthesis by Autonomous Self‐Optimizing Flow Reactors

Maarten Rubens, Jeroen H. Vrijsen, Joachim Laun and Tanja Junkers

Angewandte Chemie, 2019, 131, 3215
DOI: 10.1002/ange.201810384

Unraveling Sequence Effect on Glass Transition Temperatures of Discrete Unconjugated Oligomers

Ruizhe Liu, Chao Yang, Zixuan Huang, Rohan French, Zi Gu, Jianli Cheng, Kunkun Guo and Jiangtao Xu

Macromol. Rapid Commun., 2022, 43
DOI: 10.1002/marc.202100666

Recent Developments and Future Challenges in Controlled Radical Polymerization: A 2020 Update

Kostas Parkatzidis, Hyun Suk Wang, Nghia P. Truong and Athina Anastasaki

Chem, 2020, 6, 1575
DOI: 10.1016/j.chempr.2020.06.014

Regulation from gradient to near periodic sequence during anionic copolymerization of styrene and dimethyl-[4-(1-phenyl-vinyl)phenyl]silane (DPE-SiH)

Xuwen Li, Li Han, Ruixue Zhang, Chao Li, Songbo Zhang, Hongyuan Bai, Xuefei Wang, Bo Wang and Hongwei Ma

Polymer, 2022, 244, 124663
DOI: 10.1016/j.polymer.2022.124663

Visible Light Photoiniferter Polymerization for Dispersity Control in High Molecular Weight Polymers

Qingchi Ma, Greg G. Qiao and Zesheng An

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202314729

Glycomacromolecules: Addressing challenges in drug delivery and therapeutic development

Will Stuart-Walker and Clare S. Mahon

Advanced Drug Delivery Reviews, 2021, 171, 77
DOI: 10.1016/j.addr.2021.01.018

Development of Sequence‐Controlled, Degradable, and Cytocompatible Oligomers with Explicit Fragmentation Pathways

Yili Yang, Keman Yu, Feiyue Xing, Yingshan Zhou and Pu Xiao

Macromol. Rapid Commun., 2023, 44
DOI: 10.1002/marc.202200788

No Sacrifice No Gain: Construction of Cleavable Bridged Macrobicyclic Olefins for Precision Polymers

Zhen Yu, Li Wang, Li Liu, Meng Wang and Hong Yang

Synlett, 2022, 33, 1607
DOI: 10.1055/a-1874-3463

Low ppm CuBr-Triggered Atom Transfer Radical Polymerization under Mild Conditions

Richard Whitfield, Kostas Parkatzidis, Kate G.E. Bradford, Nghia P. Truong, Dominik Konkolewicz and Athina Anastasaki

Macromolecules, 2021, 54, 3075
DOI: 10.1021/acs.macromol.0c02519

Engineering discrete synthetic macromolecules for biomedical applications

Aizong Shen, Lei Zhang, Yanbo Xie, Xueyu Zhu, Jinming Hu and Shiyong Liu

Nano Today, 2023, 48, 101728
DOI: 10.1016/j.nantod.2022.101728

Solvent‐Dependent Sequence‐Controlled Copolymerization of Lactones: Tailoring Material Properties from Robust Plastics to Tough Elastomers

Chaoqun Weng, Xiao Li and Xiaoyan Tang

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202415388

Periodically Functionalized Sequence‐Regulated Vinyl Polymers via Iterative Atom Transfer Radical Additions and Acyclic Diene Metathesis Polymerization

Masato Miyajima, Kotaro Satoh and Masami Kamigaito

Macro Chemistry & Physics, 2022, 223
DOI: 10.1002/macp.202100426

Controlling size, shape, and charge of nanoparticles via low-energy miniemulsion and heterogeneous RAFT polymerization

Victoria Lohmann, Manon Rolland, Nghia P. Truong and Athina Anastasaki

European Polymer Journal, 2022, 176, 111417
DOI: 10.1016/j.eurpolymj.2022.111417

Radical-promoted single-unit monomer insertion (SUMI) [aka. reversible-deactivation radical addition (RDRA)]

Cyrille Boyer, Masami Kamigaito, Kotaro Satoh and Graeme Moad

Progress in Polymer Science, 2023, 138, 101648
DOI: 10.1016/j.progpolymsci.2023.101648

Rapid and Scalable Access to Sequence‐Controlled DHDM Multiblock Copolymers by FLP Polymerization

Yun Bai, Huaiyu Wang, Jianghua He and Yuetao Zhang

Angewandte Chemie, 2020, 132, 11710
DOI: 10.1002/ange.202004013

Sequence- and stereo-defined macromolecules: Properties and emerging functionalities

Roza Szweda

Progress in Polymer Science, 2023, 145, 101737
DOI: 10.1016/j.progpolymsci.2023.101737

Engineering precise sequence-defined polymers for advanced functions

Qiangqiang Shi, Zhengyu Deng, Mingxuan Hou, Xianglong Hu and Shiyong Liu

Progress in Polymer Science, 2023, 141, 101677
DOI: 10.1016/j.progpolymsci.2023.101677

Low-Dispersity Polymers in Ab Initio Emulsion Polymerization: Improved MacroRAFT Agent Performance in Heterogeneous Media

Robert A. E. Richardson, Thiago R. Guimarães, Murtaza Khan, Graeme Moad, Per B. Zetterlund and Sébastien Perrier

Macromolecules, 2020, 53, 7672
DOI: 10.1021/acs.macromol.0c01311

Evolutions of precision radical polymerizations from metal-catalyzed radical addition: living polymerization, step-growth polymerization, and monomer sequence control

Masami Kamigaito

Polym J, 2022, 54, 1391
DOI: 10.1038/s41428-022-00680-6

Reversible Deactivation Radical Copolymerization: Synthesis of Copolymers with Controlled Unit Sequence

E. V. Chernikova and K. O. Mineeva

Polym. Sci. Ser. C, 2022, 64, 1
DOI: 10.1134/S1811238222200024

Block Random Copolymers of Styrene and Acrylic Acid: Synthesis and Properties

K. O. Mineeva, E. I. Medentseva, A. V. Plutalova, N. S. Serkhacheva, A. V. Bol’shakova, E. A. Lysenko and E. V. Chernikova

Polym. Sci. Ser. B, 2021, 63, 821
DOI: 10.1134/S156009042106018X

Installing a Single Monomer within Acrylic Polymers Using Photoredox Catalysis

Jared G. Baker, Richard Zhang and C. Adrian Figg

J. Am. Chem. Soc., 2024, 146, 106
DOI: 10.1021/jacs.3c12221

Accelerated Continuous Flow Depolymerization of Poly(Methyl Methacrylate)

Katharina S. C. Jäger, Gayathri Dev Ammini, Pieter-Jan Voorter, Priya Subramanian, Anil Kumar, Athina Anastasaki and Tanja Junkers

J. Am. Chem. Soc., 2025, 147, 594
DOI: 10.1021/jacs.4c12455

Concurrent control over sequence and dispersity in multiblock copolymers

Maria-Nefeli Antonopoulou, Richard Whitfield, Nghia P. Truong, Dries Wyers, Simon Harrisson, Tanja Junkers and Athina Anastasaki

Nat. Chem., 2022, 14, 304
DOI: 10.1038/s41557-021-00818-8

Controlled radical depolymerization: Structural differentiation and molecular weight control

Hyun Suk Wang, Kostas Parkatzidis, Tanja Junkers, Nghia P. Truong and Athina Anastasaki

Chem, 2024, 10, 388
DOI: 10.1016/j.chempr.2023.09.027

Simply Prepared Dual-Initiating Bis-Phosphonium Ylide-Based Lewis Pairs for Efficient Synthesis of Alkyl (Meth)acrylates (Co)polymers

Conglei Liu, Wuchao Zhao, Lincai Li, Zhikang Chen, Yiling Zhao, Yuetao Zhang and Hongping Zhu

Macromolecules, 2024, 57, 110
DOI: 10.1021/acs.macromol.3c02042

Tailoring Hierarchical Structure and Rare Earth Affinity of Compositionally Identical Polymers via Sequence Control

Peter A. Dykeman-Bermingham, Matthew P. Bogen, Supraja S. Chittari, Savannah F. Grizzard and Abigail S. Knight

J. Am. Chem. Soc., 2024, 146, 8607
DOI: 10.1021/jacs.4c00440

Comparison of the spatial statistics of random and defined-sequence photoresist films

William D. Hinsberg and Frances A. Houle

J. Micro/Nanopattern. Mats. Metro., 2024, 23
DOI: 10.1117/1.JMM.23.4.044601

Regioregular Alternating Polychalcogenophenes‐Block‐Poly(3‐hexylthiophene): Synthesis, Structural Characterizations, Molecular Properties, and Transistors

Yung‐Jing Xue, Huai‐Hsuan Liu, Kuo‐Hsiu Huang, Kuang‐Yi Cheng, Chia‐Lin Tsai, Chia‐Shing Wu and Yen‐Ju Cheng

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202500277

An Arbitrarily Regulated Monomer Sequence in Multi‐Block Copolymer Synthesis by Frustrated Lewis Pairs

Yi Wan, Jianghua He and Yuetao Zhang

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202218248

Highly Regioselective Ring-Opening Polymerization of Cyclic Diester for Alternating Sequence-Controlled Copolymer Synthesis of Mandelic Acid and Glycolic Acid

Yaru Wang, Zhaowei Jia, Jinxing Jiang, Xiaoyang Mao, Xiaobo Pan and Jincai Wu

Macromolecules, 2019, 52, 7564
DOI: 10.1021/acs.macromol.9b01515

Fabrication of Bioinspired Hydrogels: Challenges and Opportunities

Hailong Fan and Jian Ping Gong

Macromolecules, 2020, 53, 2769
DOI: 10.1021/acs.macromol.0c00238

Well-Defined Conjugated Macromolecules Based on Oligo(Arylene Ethynylene)s in Sensing

Agata Krywko-Cendrowska, Dawid Szweda and Roza Szweda

Processes, 2020, 8, 539
DOI: 10.3390/pr8050539

Hierarchical Nanomaterials Assembled from Peptoids and Other Sequence-Defined Synthetic Polymers

Zhiliang Li, Bin Cai, Wenchao Yang and Chun-Long Chen

Chem. Rev., 2021, 121, 14031
DOI: 10.1021/acs.chemrev.1c00024

Versatile Triphenylphosphine-Containing Polymeric Catalysts and Elucidation of Structure–Function Relationships

Matthew A. Sanders, Supraja S. Chittari, Nicole Sherman, Jack R. Foley and Abigail S. Knight

J. Am. Chem. Soc., 2023, 145, 9686
DOI: 10.1021/jacs.3c01092

Oxygen-Enhanced Atom Transfer Radical Polymerization through the Formation of a Copper Superoxido Complex

Kostas Parkatzidis, Nghia P. Truong, Richard Whitfield, Chiara E. Campi, Benjamin Grimm-Lebsanft, Sören Buchenau, Michael A. Rübhausen, Simon Harrisson, Dominik Konkolewicz, Siegfried Schindler and Athina Anastasaki

J. Am. Chem. Soc., 2023, 145, 1906
DOI: 10.1021/jacs.2c11757

Embedding Peptides into Synthetic Polymers: Radical Ring-Opening Copolymerization of Cyclic Peptides

Federica Sbordone, Juliet Veskova, Bailey Richardson, Phuong Thi Do, Aaron Micallef and Hendrik Frisch

J. Am. Chem. Soc., 2023, 145, 6221
DOI: 10.1021/jacs.2c12517

Fate of the RAFT End-Group in the Thermal Depolymerization of Polymethacrylates

Florian Häfliger, Nghia P. Truong, Hyun Suk Wang and Athina Anastasaki

ACS Macro Lett., 2023, 12, 1207
DOI: 10.1021/acsmacrolett.3c00418

From Sequence‐Defined Macromolecules to Macromolecular Pin Codes

Joshua O. Holloway, Filip Van Lijsebetten, Nezha Badi, Hannes A. Houck and Filip E. Du Prez

Advanced Science, 2020, 7
DOI: 10.1002/advs.201903698

Deconstructing Oligomer Distributions: Discrete Species and Artificial Distributions

Jeroen De Neve, Joris J. Haven, Simon Harrisson and Tanja Junkers