Hyeongcheol Ham, Seohyun Shin, Gi Hoon Ko, Sang Hoon Han, Gi Uk Han, Chanyoung Maeng, Tae Hyeon Kim, Hee Chan Noh, Kyungsup Lee, Hanjoong Kim, Heejin Yang and Phil Ho Lee

J. Org. Chem., 2021, 86, 15153
DOI: 10.1021/acs.joc.1c01804

Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation

Furong Lin, Jing-Lu Yu, Yunjun Shen, Shuo-Qing Zhang, Bernhard Spingler, Jiyong Liu, Xin Hong and Simon Duttwyler

J. Am. Chem. Soc., 2018, 140, 13798
DOI: 10.1021/jacs.8b07872

Direct Nucleophilic Substitution Reaction of Cage B−H Bonds by Grignard Reagents: A Route to Regioselective B4‐Alkylation of o‐Carboranes

Cen Tang, Jiji Zhang and Zuowei Xie

Angew Chem Int Ed, 2017, 56, 8642
DOI: 10.1002/anie.201702347

Rh-Catalyzed Regioselective Dialkylation of Cage B–H bonds in o-Carboranes: Oxidative Heck Reactions via an Enol Isomerization

Qian Wang, Song Tian, Chuyi Zhang, Jiangwei Li, Zhixuan Wang, Yongmei Du, Ling Zhou and Jian Lu

Org. Lett., 2019, 21, 8018
DOI: 10.1021/acs.orglett.9b03009

Palladium Catalyzed Selective B(3)–H Activation/Oxidative Dehydrogenative Coupling for the Synthesis of Bis(o-carborane)s

Ji Wu, Ke Cao, Cai-Yan Zhang, Tao-Tao Xu, Xin-Yu Wen, Bo Li and Junxiao Yang

Inorg. Chem., 2020, 59, 17340
DOI: 10.1021/acs.inorgchem.0c02638

Transition Metal Catalyzed Direct Amination of the Cage B(4)–H Bond in o-Carboranes: Synthesis of Tertiary, Secondary, and Primary o-Carboranyl Amines

Hairong Lyu, Yangjian Quan and Zuowei Xie

J. Am. Chem. Soc., 2016, 138, 12727
DOI: 10.1021/jacs.6b07086

Transition Metal Complexes of a Monocarba‐closo‐dodecaborate Ligand via B–H Activation

Yunjun Shen, Jiyong Liu, Tosaporn Sattasatchuchana, Kim K. Baldridge and Simon Duttwyler

Eur J Inorg Chem, 2017, 2017, 4420
DOI: 10.1002/ejic.201700677

Direct Nucleophilic Substitution Reaction of Cage B−H Bonds by Grignard Reagents: A Route to Regioselective B4‐Alkylation of o‐Carboranes

Cen Tang, Jiji Zhang and Zuowei Xie

Angewandte Chemie, 2017, 129, 8768
DOI: 10.1002/ange.201702347

Coordination Chemistry of Carborane Clusters: Metal-Boron Bonds in Carborane, Carboranyl, and Carboryne Complexes

Bennett J. Eleazer and Dmitry V. Peryshkov

Comments on Inorganic Chemistry, 2018, 38, 79
DOI: 10.1080/02603594.2018.1465939

Direct B–H Functionalization of Icosahedral Carboranes via Hydrogen Atom Transfer

Hongyuan Ren, Ping Zhang, Jingkai Xu, Wenli Ma, Deshuang Tu, Chang-sheng Lu and Hong Yan

J. Am. Chem. Soc., 2023, 145, 7638
DOI: 10.1021/jacs.3c01314

Synthesis of Polyhedral Borane Cluster Fused Heterocycles via Transition Metal Catalyzed B-H Activation

Ke Cao, Cai-Yan Zhang, Tao-Tao Xu, Ji Wu, Xin-Yu Wen, Wen-Jun Jiang, Mao Chen and Junxiao Yang

Molecules, 2020, 25, 391
DOI: 10.3390/molecules25020391

Recent Advance in Transition Metal‐Catalyzed Carboxylic Acid Guided B−H Functionalization of Carboranes

Qian Wang, Bifu Liu, Kejun Feng and A. Stephen K. Hashmi

Adv Synth Catal, 2022, 364, 4174
DOI: 10.1002/adsc.202201183

Catalytic Cage BH Functionalization of Carboranes via “Cage Walking” Strategy

Chenyang Guo, Zaozao Qiu and Zuowei Xie

ACS Catal., 2021, 11, 2134
DOI: 10.1021/acscatal.0c05639

Boron-substituted 1,2,3-triazoles (microreview)

Nazariy T. Pokhodylo and Khryestyna Ye. Pitkovych

Chem Heterocycl Comp, 2021, 57, 737
DOI: 10.1007/s10593-021-02976-6

Synthesis of o‐carboranyl‐acyl‐substituted diazo compounds from B(4)‐acylmethyl carboranes and 2‐azido‐1,3‐dimethylimidazolinium hexafluorophosphate

Chanyoung Maeng, Gi Hoon Ko, Kyungsup Lee, Hee Chan Noh, Dae Su Park and Phil Ho Lee

Bulletin Korean Chem Soc, 2023, 44, 693
DOI: 10.1002/bkcs.12708

Pd‐Catalyzed Selective Bifunctionalization of 3‐Iodo‐o‐Carborane by Pd Migration

Yixiu Ge, Jie Zhang, Zaozao Qiu and Zuowei Xie

Angew Chem Int Ed, 2020, 59, 4851
DOI: 10.1002/anie.201914500

One‐Pot Process to Carborano‐Coumarin via Catalytic CascadeDehydrogenative Cross‐Coupling

Yik Ki Au, Hairong Lyu, Yangjian Quan and Zuowei Xie

Chin. J. Chem., 2020, 38, 383
DOI: 10.1002/cjoc.201900475

Catalytic Cascade Dehydrogenative Cross-Coupling of BH/CH and BH/NH: One-Pot Process to Carborano-Isoquinolinone

Yik Ki Au, Hairong Lyu, Yangjian Quan and Zuowei Xie

J. Am. Chem. Soc., 2019, 141, 12855
DOI: 10.1021/jacs.9b06204

RhIII‐Catalyzed Functionalization of closo‐Dodecaborates by Selective B−H Activation: Bypassing Competitive C−H Activation

Yuanbin Zhang, Tao Wang, Lingyao Wang, Yuji Sun, Furong Lin, Jiyong Liu and Simon Duttwyler

Chemistry A European J, 2018, 24, 15812
DOI: 10.1002/chem.201803455

Selective B(4)−H Activation of an o‐Carboranylthioamide Based on a Palladium Precursor

Yin‐Ping Wang, Long Zhang, Yue‐Jian Lin, Zhen‐Hua Li and Guo‐Xin Jin

Chemistry A European J, 2017, 23, 1814
DOI: 10.1002/chem.201603851

Recent advances in B–H functionalization of icosahedral carboranes and boranes by transition metal catalysis

Simon Duttwyler

Pure and Applied Chemistry, 2018, 90, 733
DOI: 10.1515/pac-2017-1202

Catalytic Regioselective Cage B(8)–H Arylation of o-Carboranes via “Cage-Walking” Strategy

Hairong Lyu, Jie Zhang, Jingting Yang, Yangjian Quan and Zuowei Xie

J. Am. Chem. Soc., 2019, 141, 4219
DOI: 10.1021/jacs.9b00302

Recent advances in boron chemistry

Cheng Chen, Zhengwei Ding, Yan Gao, Yi Jing, Yong-An Luo, Xingxing Ma, Xuenian Chen, Pengfei Li, Zaozao Qiu, Qiuling Song, Xiao-Ye Wang and Zuowei Xie

Sci. China Chem., 2025
DOI: 10.1007/s11426-025-2886-2

Functional Group Directed B–H Activation of Polyhedral Boron Hydrides by Transition Metal Complexes (Review)

I. B. Sivaev

Russ. J. Inorg. Chem., 2021, 66, 1289
DOI: 10.1134/S0036023621090151

Post‐Functionalization of Organoboranes by Cu‐Catalyzed Azide Alkyne [3+2]‐Cycloaddition Reaction

Mélanie Bonnard, Sandra Pinet, Laurent Chabaud and Mathieu Pucheault

Eur J Org Chem, 2024
DOI: 10.1002/ejoc.202400580

Rhodium‐Catalyzed Regioselective Hydroxylation of Cage B−H Bonds of o‐Carboranes with O2 or Air

Hairong Lyu, Yangjian Quan and Zuowei Xie

Angewandte Chemie, 2016, 128, 12019
DOI: 10.1002/ange.201605880

Metal‐Free Oxidative B−N Coupling of nido‐Carborane with N‐Heterocycles

Zhongming Yang, Weijia Zhao, Wei Liu, Xing Wei, Meng Chen, Xiao Zhang, Xiaolei Zhang, Yong Liang, Changsheng Lu and Hong Yan