Arpal Pal, Naga D. Koduri, Zhiguo Wang, Erika Lopez Quiroz, Alexandra Chong, Matthew Vuong, Nisha Rajagopal, Michael Nguyen, Kenneth P. Roberts and Syed R. Hussaini

Tetrahedron Letters, 2017, 58, 586
DOI: 10.1016/j.tetlet.2017.01.004

Catalyst-Dependent Chemoselectivity in the Dirhodium-Catalyzed Cyclization Reactions Between Enodiazoacetamide and Nitrosoarene: A Theoretical Study

Yan Zhang, Yongsheng Yang, Ruyu Zhu, Xingyu Wang and Ying Xue

Front. Chem., 2019, 7
DOI: 10.3389/fchem.2019.00586

Chiral Phosphoric Acid Catalyzed (4+1) Annulation of 3‐Diazooxindoles/4‐Diazooxisoquinolines with para‐Quinone Methides to Access Chiral Spiro[dihydrobenzofuran‐2,3′‐oxindoles/2,4′‐oxisoquinolines]

You‐Cai Wu, Bao‐Dong Cui, Yan Long, Wen‐Yong Han, Nan‐Wei Wan, Wei‐Cheng Yuan and Yong‐Zheng Chen

Adv Synth Catal, 2021, 363, 1702
DOI: 10.1002/adsc.202001309

Highly Enantioselective Synthesis of Multifunctionalized Dihydrofurans by Copper-Catalyzed Asymmetric [4 + 1] Cycloadditions of α-Benzylidene-β-ketoester with Diazo Compound

Jiao-Long Zhou, Li-Jia Wang, Hao Xu, Xiu-Li Sun and Yong Tang

ACS Catal., 2013, 3, 685
DOI: 10.1021/cs400019u

Access to C4-Functionalized Quinolines via Copper-Catalyzed Tandem Annulation of Alkynyl Imines with Diazo Compounds

Ruifeng Zhu, Guolin Cheng, Chunqi Jia, Lulu Xue and Xiuling Cui

J. Org. Chem., 2016, 81, 7539
DOI: 10.1021/acs.joc.6b01227

A Carbene‐Extended ATRA Reaction

Guojiao Wu, Jennifer Börger and Axel Jacobi von Wangelin

Angew Chem Int Ed, 2019, 58, 17241
DOI: 10.1002/anie.201909872

Thermally induced reaction of diazoamides with isatins: A complementary approach to the 3,3′-bioxindole derivatives

Yang Zheng, Ming Bao, Lihua Qiu and Xinfang Xu

Tetrahedron Letters, 2017, 58, 3390
DOI: 10.1016/j.tetlet.2017.07.053

DFT Studies on Cu-Catalyzed Cross-Coupling of Diazo Compounds with Trimethylsilylethyne and tert-Butylethyne: Formation of Alkynes for Trimethylsilylethyne while Allenes for tert-Butylethyne

Ting Wang, Meiyan Wang, Sheng Fang and Jing-yao Liu

Organometallics, 2014, 33, 3941
DOI: 10.1021/om4010803

Understanding the Remarkable Stability of Well‐Defined Dinuclear Copper(I) Carbene Complexes

Roel L. M. Bienenmann, Marianne R. de Vries, Martin Lutz and Daniël L. J. Broere

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202400283

Recent Progress on Copper-Catalyzed C–C Bond Formation via C(sp2)–H Insertions Using Diazo and Related Compounds

Satabdi Bera, Subhenira Jana and Rajarshi Samanta

Synthesis, 2024, 56, 29
DOI: 10.1055/a-2134-0352

Palladium-Catalyzed C–H Functionalization of Acyldiazomethane and Tandem Cross-Coupling Reactions

Fei Ye, Shuanglin Qu, Lei Zhou, Cheng Peng, Chengpeng Wang, Jiajia Cheng, Mohammad Lokman Hossain, Yizhou Liu, Yan Zhang, Zhi-Xiang Wang and Jianbo Wang

J. Am. Chem. Soc., 2015, 137, 4435
DOI: 10.1021/ja513275c

Regioselective and Stereospecific Copper-Catalyzed Deoxygenation of Epoxides to Alkenes

Jingxun Yu, Yu Zhou, Zhenyang Lin and Rongbiao Tong

Org. Lett., 2016, 18, 4734
DOI: 10.1021/acs.orglett.6b02405

Construction of fluorinated pyrazole derivatives via a one-pot tandem C–H insertion/electrophilic fluorination reaction

Kai Zhang, Gang Zhao and Weiguo Cao

Tetrahedron, 2014, 70, 5659
DOI: 10.1016/j.tet.2014.06.065

Grignard reagent dictated copper(I) phosphines catalyzed reductive coupling of diazo compounds: The chemistry beyond carbene generation

Packirisamy Kuzhalmozhi Madarasi and Chinnappan Sivasankar

Applied Organom Chemis, 2022, 36
DOI: 10.1002/aoc.6522

Photochemical “Cut and Sew” Transformations of Ethynylbenziodoxolone Reagents and Diazo Compounds

Mengting Cao, Yikun Ren, Ruoyu Zhang, Huayan Xu, Pengfei Cheng, Hao Xu, Yuanqing Xu and Pan Li

Org. Lett., 2023, 25, 6300
DOI: 10.1021/acs.orglett.3c02141

Copper(I)‐Catalysed Domino Coupling and Cyclisation Reaction: A Mild, Expedient Route for the Synthesis of Indene and Dihydronaphthalene Derivatives

Gullapalli Kumaraswamy and Guniganti Balakishan

Eur J Org Chem, 2015, 2015, 3141
DOI: 10.1002/ejoc.201500284

Biosynthesis of Copper Nanoparticles Supported on Zeolite Y and its Application in Catalytic C‐N Cross Coupling Reactions between Amines and Aryl halides

Anasdass Jaculin Raiza, Kannaiyan Pandian and Rajendran Ganesh Kumar

ChemistrySelect, 2019, 4, 1964
DOI: 10.1002/slct.201804003

Manganese Catalyzed Regioselective C–H Alkylation: Experiment and Computation

Chengming Wang, Bholanath Maity, Luigi Cavallo and Magnus Rueping

Org. Lett., 2018, 20, 3105
DOI: 10.1021/acs.orglett.8b01179

Recent Advances in Enantioselective Photochemical Reactions of Stabilized Diazo Compounds

Ting-Bi Hua, Qing-Qing Yang and You-Quan Zou

Molecules, 2019, 24, 3191
DOI: 10.3390/molecules24173191

Gold vs Light: Chemodivergent Reactivity of Diazoesters toward 2H-Azirine-2-carboxylic Acids

Gleb D. Titov, Grigory I. Antonychev, Mikhail S. Novikov, Alexander F. Khlebnikov, Elizaveta V. Rogacheva, Liudmila A. Kraeva and Nikolai V. Rostovskii

Org. Lett., 2023, 25, 2707
DOI: 10.1021/acs.orglett.3c00823

A Computational Study on the Photochemical O–H Functionalization of Alcohols with Diazoacetates

Chao Pei and Rene M. Koenigs

J. Org. Chem., 2022, 87, 6832
DOI: 10.1021/acs.joc.2c00513

A catalyst-free N–H insertion/Mannich-type reaction cascade of α-nitrodiazoesters

Ting Yang, Hao Zhuang, Xichen Lin, Jia-Ning Xiang, John D. Elliott, Lianghui Liu and Feng Ren

Tetrahedron Letters, 2013, 54, 4159
DOI: 10.1016/j.tetlet.2013.05.131

Application of Aromatic Substituted 2,2,2-Trifluoro Diazoethanes in Organic Reactions

Cai Zhang

COC, 2022, 26, 639
DOI: 10.2174/1385272826666220516113815

Well‐Defined, Versatile and Recyclable Half‐Sandwich Nickelacarborane Catalyst for Selective Carbene‐Transfer Reactions

Linghua Wang, Saima Perveen, Yizhao Ouyang, Shuai Zhang, Jiao Jiao, Gang He, Yong Nie and Pengfei Li

Chemistry A European J, 2021, 27, 5754
DOI: 10.1002/chem.202005014

Visible-Light-Induced Catalysis: A Regioselectivity Switch between [2+1] and [2+2] Cycloaddition of Diazocarbonyls with Olefins

Huixin Qiu, Lirong Wen and Jian Lv

Synthesis, 2022, 54, 3739
DOI: 10.1055/a-1786-6496

Copper‐Catalyzed Formation of α‐Alkoxycycloalkenones from N‐Tosylhydrazones

Naijing Su, Juliana A. Theorell, Donald J. Wink and Tom G. Driver

Angewandte Chemie, 2015, 127, 13134
DOI: 10.1002/ange.201505993

[4+1] Cycloaddition of Enaminothiones and Aldehyde N‐Tosylhydrazones Toward 3‐Aminothiophenes

Zhuqing Liu, Ping Wu, Yuan He, Ting Yang and Zhengkun Yu

Adv Synth Catal, 2018, 360, 4381
DOI: 10.1002/adsc.201801028

Photo‐Induced Homologation of Carbonyl Compounds for Iterative Syntheses

Hua Wang, Shun Wang, Vincent George, Galder Llorente and Burkhard König

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202211578

Catalyst- and Substituent-Controlled Regio- and Stereoselective Synthesis of Indolyl Acrylates by Lewis-Acid-Catalyzed Direct Functionalization of 3-Formylindoles with Diazo Esters

Sana Jamshaid, Shreedhar Devkota and Yong Rok Lee

Org. Lett., 2021, 23, 2140
DOI: 10.1021/acs.orglett.1c00277

RhIII‐Catalyzed CH Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal‐Ion Detection

Ju Hyun Kim, Tobias Gensch, Dongbing Zhao, Linda Stegemann, Cristian A. Strassert and Frank Glorius

Angew Chem Int Ed, 2015, 54, 10975
DOI: 10.1002/anie.201504757

Reactivity and Selectivity in Catalytic Reactions of Enoldiazoacetamides. Assessment of Metal Carbenes as Intermediates

Yongming Deng, Changcheng Jing, Hadi Arman and Michael P. Doyle

Organometallics, 2016, 35, 3413
DOI: 10.1021/acs.organomet.6b00648

Diazo‐ and Transition‐Metal‐Free CH Insertion: A Direct Synthesis of β‐Lactams

Luis F. R. Gomes, Luís F. Veiros, Nuno Maulide and Carlos A. M. Afonso

Chemistry A European J, 2015, 21, 1449
DOI: 10.1002/chem.201404990

Copper-Catalyzed Cycloadditions of Diazo Compounds with Imidazolidines/Hexahydropyrimidines for the Syntheses of N-Heterocycles

Yuqi Zhu, Liangliang Yang, Xue Zhang, Wendi Xu, Jieyin He, Haiyang Wang, Ming Lang and Shiyong Peng

Org. Lett., 2022, 24, 6443
DOI: 10.1021/acs.orglett.2c02561

Copper‐Catalyzed Difunctionalization of Terminal Alkynes with Diazo Esters and Amines to Construct β‐Enamino Esters

Bao Gao and Hanmin Huang

Adv Synth Catal, 2016, 358, 4075
DOI: 10.1002/adsc.201600883

Copper‐Catalyzed Formation of α‐Alkoxycycloalkenones from N‐Tosylhydrazones

Naijing Su, Juliana A. Theorell, Donald J. Wink and Tom G. Driver

Angew Chem Int Ed, 2015, 54, 12942
DOI: 10.1002/anie.201505993

Chemoselective Carbophilic Addition of α‐Diazoesters through Ligand‐Controlled Gold Catalysis

Yumeng Xi, Yijin Su, Zhaoyuan Yu, Boliang Dong, Edward J. McClain, Yu Lan and Xiaodong Shi

Angew Chem Int Ed, 2014, 53, 9817
DOI: 10.1002/anie.201404946

A Terminal Rh Methylidene from Activation of CH2Cl2

Travis J. Morrow, Jordan R. Gipper, William E. Christman, Navamoney Arulsamy and Elliott B. Hulley

Organometallics, 2020, 39, 2356
DOI: 10.1021/acs.organomet.0c00031

Synthesis of the [6‐5‐5‐3] Tetracyclic Core of Cryptotrione

Nan Hu, Jun‐Ting Liang, Yong‐Bin Xie, Chuang‐Chuang Li, Yu‐Tao He and Ya‐Jian Hu

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500399

Carbene Bridging C–H Activation: Facile Isocoumarin Synthesis Through Palladium‐Catalyzed Reaction of 2‐Pseudohalobenzaldehydes with Aryl Diazoesters

Chao Yan, Yinghua Yu, Bo Peng and Xueliang Huang

Eur J Org Chem, 2020, 2020, 723
DOI: 10.1002/ejoc.201901738

Copper-Carbene-Triggered Electrophilic Cyclization of o-Hydroxyarylenaminones with 3-Diazoindolin-2-imines: Synthesis of 3-Indolyl-4H-chromen-4-ones and Pyrido[2,3-b:6,5-b′]diindoles

Jing Qian, Zhenwei Lin, Zaibin Wang, Zhixing Peng, Li Wu, Ping Lu and Yanguang Wang

J. Org. Chem., 2019, 84, 6395
DOI: 10.1021/acs.joc.9b00755

Progress in Catalytic Asymmetric Protonation

Sylvain Oudeyer, Jean‐François Brière and Vincent Levacher

Eur J Org Chem, 2014, 2014, 6103
DOI: 10.1002/ejoc.201402213

Copper‐Catalyzed Regioselective Cascade Alkylation and Cyclocondensation of Quinoline N‐Oxides with Diazo Esters: Direct Access to Conjugated π‐Systems

Aniruddha Biswas, Ujjwal Karmakar, Arun Pal and Rajarshi Samanta

Chemistry A European J, 2016, 22, 13826
DOI: 10.1002/chem.201602493

Copper-enalcarbenoids: Rapid access to 1,7-disubstituted indoles via [4+2] benzannulation between diazoenals and N-substituted pyrroles

Bapurao Sudam Lad, Pratap Kumar Mandal, Rahul Chakrawarti and Sreenivas Katukojvala

Tetrahedron Letters, 2024, 151, 155331
DOI: 10.1016/j.tetlet.2024.155331

A New Reactivity Mode for the Diazo Group: Diastereoselective 1,3‐Aminoalkylation Reaction of β‐Amino‐α‐Diazoesters To Give Triazolines

Alexey Kuznetsov, Anton V. Gulevich, Donald J. Wink and Vladimir Gevorgyan

Angew Chem Int Ed, 2014, 53, 9021
DOI: 10.1002/anie.201404352

Rhodium(II)‐Catalyzed Formal [4+1]‐Cycloaddition of Pyridotriazoles and Propargyl Alcohols: Synthesis of 2,5‐Dihydrofurans

Xinxin Lv, Haijian Yang, Taoda Shi, Dong Xing, Xinfang Xu and Wenhao Hu

Adv Synth Catal, 2019, 361, 1265
DOI: 10.1002/adsc.201801497

Synthesis of Aryldiazoacetates through Palladium(0)‐Catalyzed Deacylative Cross‐Coupling of Aryl Iodides with Acyldiazoacetates

Fei Ye, Chengpeng Wang, Yan Zhang and Jianbo Wang

Angewandte Chemie, 2014, 126, 11809
DOI: 10.1002/ange.201407653

Cu(I)-catalyzed reaction of diazo compounds with terminal alkynes: a direct synthesis of trisubstituted furans

Mohammad Lokman Hossain, Fei Ye, Yan Zhang and Jianbo Wang

Tetrahedron, 2014, 70, 6957
DOI: 10.1016/j.tet.2014.07.086

“Sandwich” Diimine‐Copper Catalysts for C−H Functionalization by Carbene Insertion

Kristine Klimovica, Julius X. Heidlas, Irvin Romero, Thanh V. Le and Olafs Daugulis

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202200334

Reaction of Diazo Compounds with Difluorocarbene: An Efficient Approach towards 1,1‐Difluoroolefins

Zhikun Zhang, Weizhi Yu, Chenggui Wu, Chengpeng Wang, Yan Zhang and Jianbo Wang

Angewandte Chemie, 2016, 128, 281
DOI: 10.1002/ange.201509711

Iron: A Worthy Contender in Metal Carbene Chemistry

Vasco F. Batista, Diana C. G. A. Pinto and Artur M. S. Silva

ACS Catal., 2020, 10, 10096
DOI: 10.1021/acscatal.0c02776

Synergistic Rh(II)- and Zn(II)-Catalyzed [3 + 3] Annulation of Diazoenals and α-Hydroxy Ketones for the Direct Synthesis of 2H-Pyrans, A Gateway Toward γ-Pyrones

Pratap Kumar Mandal and Sreenivas Katukojvala

Org. Lett., 2024, 26, 9227
DOI: 10.1021/acs.orglett.4c03329

Synthesis of Pyrrolidines and Pyrrolizidines with α‐Pseudoquaternary Centers by Copper‐Catalyzed Condensation of α‐Diazodicarbonyl Compounds and Aryl γ‐Lactams

Sébastien Goudedranche, Céline Besnard, Léo Egger and Jérôme Lacour

Angew Chem Int Ed, 2016, 55, 13775
DOI: 10.1002/anie.201607574

Chiral Primary Amine-Catalyzed Divergent Coupling of α-Substituted Acrylaldehydes with α-Diazoesters

Zaikun Xue, Yao Li and Sanzhong Luo

ACS Catal., 2020, 10, 10989
DOI: 10.1021/acscatal.0c02405

Copper (I)‐BOX Catalyzed Asymmetric 3‐Component Reaction for the Synthesis of Trifluoromethylated Propargylic Ethers and Anilines**

Nieves P. Ramirez and Jerome Waser

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202305776

Cobalt(II)–tetraphenylporphyrin-catalysed carbene transfer from acceptor–acceptor iodonium ylides via N-enolate–carbene radicals

Roel F. J. Epping, Mees M. Hoeksma, Eduard O. Bobylev, Simon Mathew and Bas de Bruin

Nat. Chem., 2022, 14, 550
DOI: 10.1038/s41557-022-00905-4

α-Aminocarbene-Mediated Si–H Insertion: Deoxygenative Silylation of Aromatic Amides with Silanes

Jiwen Jiao, Wenhan Yang and Xiaoming Wang

J. Org. Chem., 2023, 88, 594
DOI: 10.1021/acs.joc.2c02649

In‐situ Utilization of Non‐Stabilized Diazoalkanes from (3+2) Cycloaddition of Linear N,N‐Disilyl Enamines and Azides

Vinh Do Cao, Sinjae Lee and Seewon Joung

Adv Synth Catal, 2024, 366, 114
DOI: 10.1002/adsc.202301213

Enantioselective Copper‐Catalyzed Intramolecular Phenolic OH Bond Insertion: Synthesis of Chiral 2‐Carboxy Dihydrobenzofurans, Dihydrobenzopyrans, and Tetrahydrobenzooxepines

Xiao‐Guang Song, Shou‐Fei Zhu, Xiu‐Lan Xie and Qi‐Lin Zhou

Angewandte Chemie, 2013, 125, 2615
DOI: 10.1002/ange.201209455

Aminoquinoline-Based Tridentate (NNN)-Copper Catalyst for C–N Bond-Forming Reactions from Aniline and Diazo Compounds

Mohsen Teimouri, Selvam Raju, Edward Acheampong, Allison N. Schmittou, Bruno Donnadieu, David O. Wipf, Brad S. Pierce, Sean L. Stokes and Joseph P. Emerson

Molecules, 2024, 29, 730
DOI: 10.3390/molecules29030730

Rhodium(I)-Catalyzed O–H Insertions onO-Protected α-Diazo-β-Hydroxyesters

Ophélie Montiège, Florian Rouzier, Jérôme Lhoste, Catherine Gaulon-Nourry, Anne-Sophie Castanet and Anne-Caroline Chany

J. Org. Chem., 2024, 89, 3194
DOI: 10.1021/acs.joc.3c02652

Carbene Radicals in Transition-Metal-Catalyzed Reactions

Roel F.J. Epping, David Vesseur, Minghui Zhou and Bas de Bruin

ACS Catal., 2023, 13, 5428
DOI: 10.1021/acscatal.3c00591

Catalyst-Controlled Regiodivergence in Rearrangements of Indole-Based Onium Ylides

Vaishnavi N. Nair, Volga Kojasoy, Croix J. Laconsay, Wang Yeuk Kong, Dean J. Tantillo and Uttam K. Tambar

J. Am. Chem. Soc., 2021, 143, 9016
DOI: 10.1021/jacs.1c00283

Recent advances in transition-metal-catalyzed asymmetric reactions of diazo compounds with electron-rich (hetero-) arenes

Yi-Pan Li, Zi-Qi Li and Shou-Fei Zhu

Tetrahedron Letters, 2018, 59, 2307
DOI: 10.1016/j.tetlet.2018.04.055

Cu-Catalyzed Asymmetric Carbene Insertion into N–H, O–H, and S–H Bonds: Challenging the Existing Mechanistic Dogma

Arushi Tyagi, Kriti Gupta and Garima Jindal

JACS Au, 2025, 5, 4879
DOI: 10.1021/jacsau.5c00807

Formal Insertion of a Metal Carbene Complex into a σ‐Carbon‐Carbon Bond. Gold‐Catalyzed Synthesis of 3H‐Indoles

Darío Allegue, Diego Sampedro, Alfredo Ballesteros and Javier Santamaría

Adv Synth Catal, 2024, 366, 1989
DOI: 10.1002/adsc.202400252

Chemospecific Intramolecular Buchner Reaction Catalyzed by Copper(II) Acetylacetonate

Shanyan Mo and Jiaxi Xu

ChemCatChem, 2014, 6, 1679
DOI: 10.1002/cctc.201400014

Copper‐Catalyzed Oxidative Amidation for the Synthesis of α‐Ketoamides from α‐Diazoketones with Amines Using Oxygen as Oxidant

Jianlan Zhang, Youyu Zhu, Jiangtao Cai, Jia Jia, Guoyang Liu, Yongqiang Dang, Xuesong Wang and Yating Zhang

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200264

Reactivity of Vinyl Phosphonate Containing Diazoesters: Formation, Reactivity, and Utility

Jin Wang and Jon D. Rainier

Org. Lett., 2015, 17, 266
DOI: 10.1021/ol5033514

RhIII‐katalysierte C‐H‐Aktivierung mit Pyridotriazolen: direkter Zugang zu Fluorophoren zur Metallerkennung

Ju Hyun Kim, Tobias Gensch, Dongbing Zhao, Linda Stegemann, Cristian A. Strassert and Frank Glorius

Angewandte Chemie, 2015, 127, 11126
DOI: 10.1002/ange.201504757

Synthesis of Pyridoisoindoles through Diazotization Followed by Intramolecular Cyclization from Pyridinylarylacetates in One Pot

Cheol‐Eui Kim, Yonghyeon Baek, Sung Hong Kim and Phil Ho Lee

Adv Synth Catal, 2015, 357, 2903
DOI: 10.1002/adsc.201500433

“Sandwich” Diimine‐Copper Catalysts for C−H Functionalization by Carbene Insertion

Kristine Klimovica, Julius X. Heidlas, Irvin Romero, Thanh V. Le and Olafs Daugulis

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202200334

Copper-Catalyzed Annulation of Indolyl α-Diazocarbonyl Compounds Leads to Structurally Rearranged Carbazoles

Sima Alavi, Jian-Bin Lin and Huck K. Grover

Org. Lett., 2021, 23, 5559
DOI: 10.1021/acs.orglett.1c01965

Tetrylenes: Electronic Structure, Stability, Reactivity, and Ligand Properties—A Comparative DFT Study

Mikhail S. Nechaev

Organometallics, 2021, 40, 3408
DOI: 10.1021/acs.organomet.1c00440

Highly Efficient Synthesis of Mixed 3,3′-Bisindoles via Rh(II)-Catalyzed Three-Component Reaction of 3-Diazooxindoles with Indoles and Ethyl Glyoxylate

Dong Xing, Changcheng Jing, Xinfeng Li, Huang Qiu and Wenhao Hu

Org. Lett., 2013, 15, 3578
DOI: 10.1021/ol401414w

Chemoselective Carbophilic Addition of α‐Diazoesters through Ligand‐Controlled Gold Catalysis

Yumeng Xi, Yijin Su, Zhaoyuan Yu, Boliang Dong, Edward J. McClain, Yu Lan and Xiaodong Shi

Angewandte Chemie, 2014, 126, 9975
DOI: 10.1002/ange.201404946

Pyridine Group Assisted Addition of Diazo-Compounds to Imines in the 3-CC Reaction of 2-Aminopyridines, Aldehydes, and Diazo-Compounds

Anton V. Gulevich, Victoria Helan, Donald J. Wink and Vladimir Gevorgyan

Org. Lett., 2013, 15, 956
DOI: 10.1021/ol400148r

Cu(II)-NHC Catalyzed Insertion of Quinoid Carbenes into cis-Epoxides: Stereoselective Synthesis of trans-Dihydronaphthodioxine

Satabdi Bera, Subarna Pan and Rajarshi Samanta

Org. Lett., 2025, 27, 1293
DOI: 10.1021/acs.orglett.5c00020

Retracted: Copper‐Catalyzed Synthesis of Substituted Isoindolo[2,1‐a]quinoxalines and Isoindolo[2,1‐a]quinoxalin‐6(5H)‐ones

Subhasish Biswas and Sanjay Batra

Eur J Org Chem, 2013, 2013, 4895
DOI: 10.1002/ejoc.201300466

Rh‐Catalyzed Chemodivergent [3+3] Annulations of Diazoenals and α‐Aminoketones: Direct Synthesis of Functionalized 1,2‐Dihydropyridines and Fused 1,4‐Oxazines

Pratap Kumar Mandal and Sreenivas Katukojvala

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202303862

Dirhodium(II)‐Catalyzed Cyclopropanation of Alkyne‐Containing α‐Diazoacetates for the Synthesis of Cycloalkynes

Qian Zeng, Ciwang He, Su Zhou, Kuiyong Dong, Lihua Qiu and Xinfang Xu

Adv Synth Catal, 2020, 362, 3137
DOI: 10.1002/adsc.202000360

Copper(I)‐Catalyzed Stereoselective Synthesis of (E)‐α‐Alkynyl‐α,β‐unsaturated Esters from a Terminal Alkyne, Diazoesters and Aldehydes

Chenggui Wu, Zhenxing Liu, Zhikun Zhang, Fei Ye, Guisheng Deng, Yan Zhang and Jianbo Wang

Adv Synth Catal, 2016, 358, 2480
DOI: 10.1002/adsc.201600374

Selective Vinylogous Reactivity of Carbene Intermediate in Gold-Catalyzed Alkyne Carbocyclization: Synthesis of Indenols

Cheng Zhang, Hongli Li, Chao Pei, Lihua Qiu, Wenhao Hu, Xiaoguang Bao and Xinfang Xu

ACS Catal., 2019, 9, 2440
DOI: 10.1021/acscatal.8b04144

Nucleophilic (Radio)Fluorination of α-Diazocarbonyl Compounds Enabled by Copper-Catalyzed H–F Insertion

Erin E. Gray, Matthew K. Nielsen, Kimberly A. Choquette, Julia A. Kalow, Thomas J. A. Graham and Abigail G. Doyle

J. Am. Chem. Soc., 2016, 138, 10802
DOI: 10.1021/jacs.6b06770

Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C–N Bond Activation

Guiping Qin, Lixin Li, Jiawen Li and Hanmin Huang

J. Am. Chem. Soc., 2015, 137, 12490
DOI: 10.1021/jacs.5b08476

Synergistic Rhodium(II) Carboxylate and Brønsted Acid Catalyzed Multicomponent Reactions of Enalcarbenoids: Direct Synthesis of α-Pyrrolylbenzylamines

Sudam Ganpat Dawande, Vinaykumar Kanchupalli, Bapurao Sudam Lad, Jyoti Rai and Sreenivas Katukojvala

Org. Lett., 2014, 16, 3700
DOI: 10.1021/ol501508f

Functionalization of Unactivated C(sp3)−H Bonds Using Metal‐Carbene Insertion Reactions

Miguel Peña‐López and Matthias Beller

Angew Chem Int Ed, 2017, 56, 46
DOI: 10.1002/anie.201609033

Propargyl α-aryl-α-diazoacetates as robust reagents for the effective C H bond functionalization of 1,3-diketones via scandium catalysis

Balu S. Navale, Debasish Laha and Ramakrishna G. Bhat

Tetrahedron Letters, 2019, 60, 1899
DOI: 10.1016/j.tetlet.2019.06.026

Copper catalyzed oxidative coupling of ortho-vinylanilines with N-tosylhydrazones: Efficient synthesis of polysubstituted quinoline derivatives

Angula Chandra Shekar Reddy and Pazhamalai Anbarasan

Journal of Catalysis, 2018, 363, 102
DOI: 10.1016/j.jcat.2018.04.005

Metal‐Catalyzed Coupling of N‐Tosylhydrazones with Compounds Containing C−H/Heteroatom‐H Bonds

Akanksha, Ajaya K. Singh, Anupama Asthana, Rangnath Ravi and Abadh Kishor Jha

Asian J Org Chem, 2024, 13
DOI: 10.1002/ajoc.202400232

Synthesis of Allylboranes via Cu(I)-Catalyzed B–H Insertion of Vinyldiazoacetates into Phosphine–Borane Adducts

Denis Drikermann, Robert S. Mößel, Walid K. Al-Jammal and Ivan Vilotijevic

Org. Lett., 2020, 22, 1091
DOI: 10.1021/acs.orglett.9b04619

Synthesis of Naphthoquinolizinones through Rh(III)-Catalyzed Double C(sp2)–H Bond Carbenoid Insertion and Annulation of 2-Aryl-3-cyanopyridines with α-Diazo Carbonyl Compounds

Beibei Zhang, Bin Li, Xinying Zhang and Xuesen Fan

Org. Lett., 2017, 19, 2294
DOI: 10.1021/acs.orglett.7b00839

In Situ Kinetic Studies of Rh(II)-Catalyzed C–H Functionalization to Achieve High Catalyst Turnover Numbers

Bo Wei, Jack C. Sharland, Donna G. Blackmond, Djamaladdin G. Musaev and Huw M. L. Davies

ACS Catal., 2022, 12, 13400
DOI: 10.1021/acscatal.2c04115

Copper-Catalyzed Cascade Double C3-Indolations of 3-Diazoindolin-2-imines with Indoles: Convenient Access to 3,3-Diaryl-2-iminoindoles

Zao Du, Yanpeng Xing, Ping Lu and Yanguang Wang

Org. Lett., 2015, 17, 1192
DOI: 10.1021/acs.orglett.5b00089

Unprecedented cyclization of α -diazo hydrazones upon N-H functionalization: A Et 3 N base promoted one-step synthetic approach for the synthesis of N-amino-1,2,3-triazole derivatives from α -diazo hydrazone

Bharath Kumar Kuruba, Lourdusamy Emmanuvel, Balasubramanian Sridhar and Samuel Vasanthkumar

Tetrahedron, 2017, 73, 2674
DOI: 10.1016/j.tet.2017.03.061

Gold‐Catalyzed Formal [4+1]/[4+3] Cycloadditions of Diazo Esters with Triazines

Chenghao Zhu, Guangyang Xu and Jiangtao Sun

Angew Chem Int Ed, 2016, 55, 11867
DOI: 10.1002/anie.201606139

Hydrogen Bonding‐Assisted Deborylative Hydroxylation of Aryl Boronic Acids via Supramolecular Catalysis

Sai Srinivas Ponugoti, Abhishek Kardile, Ankita Kanhere, Sandip J. Detke, Abhinandan Chopada, Aditya Sunil Lade, Sheik Haseena, Prashant S. Kharkar and Shreerang V. Joshi

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202501154

Gold-Catalyzed Synthesis of Small Rings

Mauro Mato, Allegra Franchino, Cristina Garcı́a-Morales and Antonio M. Echavarren

Chem. Rev., 2021, 121, 8613
DOI: 10.1021/acs.chemrev.0c00697

Synthesis of 8-Alkoxy-5H-isochromeno[3,4-c]isoquinolines and 1-Alkoxy-4-arylisoquinolin-3-ols through Rh(III)-Catalyzed C–H Functionalization of Benzimidates with 4-Diazoisochroman-3-imines and 4-Diazoisoquinolin-3-ones

Zhenmin Li, Jianwei Xie, Ping Lu and Yanguang Wang

J. Org. Chem., 2020, 85, 5525
DOI: 10.1021/acs.joc.0c00283

Reductive coupling reactions: a new strategy for C(sp3)–P bond formation

Zi-Sheng Chen, Zhao-Zhao Zhou, Hui-Liang Hua, Xin-Hua Duan, Jian-Yi Luo, Jia Wang, Ping-Xin Zhou and Yong-Min Liang

Tetrahedron, 2013, 69, 1065
DOI: 10.1016/j.tet.2012.11.064

Diversity‐Oriented Three‐Component Reactions of Diazo Compounds with Anilines and 4‐Oxo‐Enoates

Changcheng Jing, Dong Xing, Yu Qian, Taoda Shi, Yun Zhao and Wenhao Hu

Angewandte Chemie, 2013, 125, 9459
DOI: 10.1002/ange.201303987

Synergistic Rhodium/Copper Catalysis: Synthesis of 1,3-Enynes and N-Aryl Enaminones

Nan-Nan Wang, Lei-Rong Huang, Wen-Juan Hao, Tian-Shu Zhang, Guigen Li, Shu-Jiang Tu and Bo Jiang

Org. Lett., 2016, 18, 1298
DOI: 10.1021/acs.orglett.6b00238

Synthesis of Pyrrolidines and Pyrrolizidines with α‐Pseudoquaternary Centers by Copper‐Catalyzed Condensation of α‐Diazodicarbonyl Compounds and Aryl γ‐Lactams

Sébastien Goudedranche, Céline Besnard, Léo Egger and Jérôme Lacour

Angewandte Chemie, 2016, 128, 13979
DOI: 10.1002/ange.201607574

Hemin‐Catalyzed, Cyclodextrin‐Assisted Insertion of Carbenoids into NH Bonds

Xiaofei Xu, Chang Li, Zhihao Tao and Yuanjiang Pan

Adv Synth Catal, 2015, 357, 3341
DOI: 10.1002/adsc.201500418

Access to Conjugated Dienes and Cyclic Allenes via a Diazo-Dithiane Rearrangement Cascade

Zhuzhu Zhang, Xiaomeng Gong, Yingze Jin, Rui-Peng Li and Shouchu Tang

Org. Lett., 2025, 27, 12868
DOI: 10.1021/acs.orglett.5c04254

Carbocation Lewis Acid TrBF4-Catalyzed 1,2-Hydride Migration: Approaches to (Z)-α,β-Unsaturated Esters and α-Branched β-Ketocarbonyls

Wansong Shang, Depeng Duan, Yongjun Liu and Jian Lv

Org. Lett., 2019, 21, 8013
DOI: 10.1021/acs.orglett.9b03005

Divergent reactivity of allene-containing α-diazoesters using Cu and Rh catalysis

Alicia M. Phelps, Nicholas S. Dolan, Nathan T. Connell and Jennifer M. Schomaker

Tetrahedron, 2013, 69, 5614
DOI: 10.1016/j.tet.2013.03.014

Palladium-Catalyzed Synthesis of 3-Haloindol-2-amines from 3-Diazoindolin-2-imines and Alkyl Halides

Yuxuan Zhou, Zhenmin Li, Fanghui Ma, Chang Zhao, Ping Lu and Yanguang Wang

J. Org. Chem., 2019, 84, 6655
DOI: 10.1021/acs.joc.9b00191

Copper-Catalyzed Radical Reaction of N-Tosylhydrazones: Stereoselective Synthesis of (E)-Vinyl Sulfones

Shuai Mao, Ya-Ru Gao, Xue-Qing Zhu, Dong-Dong Guo and Yong-Qiang Wang

Org. Lett., 2015, 17, 1692
DOI: 10.1021/acs.orglett.5b00461

Recent progress in insertion and cyclopropanation reactions of metal carbenoids from α-diazocarbonyl compounds

Getahun Tadesse Gurmessa and Girija Shankar Singh

Res Chem Intermed, 2017, 43, 6447
DOI: 10.1007/s11164-017-3000-x

Cu(II)-Catalyzed Construction of Heterobiaryls using 1-Diazonaphthoquinones: A General Strategy for the Synthesis of QUINOX and Related P,N Ligands

Aniruddha Biswas, Subarna Pan and Rajarshi Samanta

Org. Lett., 2022, 24, 1631
DOI: 10.1021/acs.orglett.2c00127

The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2012

James W. Herndon

Coordination Chemistry Reviews, 2014, 272, 48
DOI: 10.1016/j.ccr.2014.02.026

Palladium and Copper Cocatalyzed Intermolecular Cyclization Reaction: Synthesis of 5‐Aminopyrazole Derivatives

Chaowei Ma, Ping Wen, Jihui Li, Xu Han, Zhaoyang Wu and Guosheng Huang

Adv Synth Catal, 2016, 358, 1073
DOI: 10.1002/adsc.201500767

Rhodium(III)‐Catalyzed Regioselective Direct C4‐Alkylation and C2‐Annulation of Indoles: Straightforward Access to Indolopyridone

Aniruddha Biswas and Rajarshi Samanta

Eur J Org Chem, 2018, 2018, 1426
DOI: 10.1002/ejoc.201701755

Synthesis of 2-Arylimino-6,7-dihydrobenzo[d][1,3]oxathiol-4(5H)-ones via Rh2(OAc)4-Catalyzed Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates

Xinwei He, Yao Zhou, Yongjia Shang, Cheng Yang and Youpeng Zuo

ACS Omega, 2016, 1, 1277
DOI: 10.1021/acsomega.6b00295

Intrinsically Safe and Shelf-Stable Diazo-Transfer Reagent for Fast Synthesis of Diazo Compounds

Shibo Xie, Ziqiang Yan, Yuanheng Li, Qun Song and Mingming Ma

J. Org. Chem., 2018, 83, 10916
DOI: 10.1021/acs.joc.8b01587

Interceptive [4 + 1] Annulation of in Situ Generated 1,2-Diaza-1,3-dienes with Diazo Esters: Direct Access to Substituted Mono-, Bi-, and Tricyclic 4,5-Dihydropyrazoles

Orazio A. Attanasi, Lucia De Crescentini, Gianfranco Favi, Fabio Mantellini, Serena Mantenuto and Simona Nicolini

J. Org. Chem., 2014, 79, 8331
DOI: 10.1021/jo5016097

N‐heterocyclic carbene copper complexes catalyze the C1 polymerization of substituted diazomethanes

Songsu Kang, Sherilyn J. Lu, Minyeong Cho, Youngsang Cho, Prakash R. Sultane and Christopher W. Bielawski

Journal of Polymer Science, 2024, 62, 5553
DOI: 10.1002/pol.20240591

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

Xinghua Wang, Jing He, Ya-Nan Wang, Zhenyan Zhao, Kui Jiang, Wei Yang, Tao Zhang, Shiqi Jia, Kangbao Zhong, Linbin Niu and Yu Lan

Chem. Rev., 2024, 124, 10192
DOI: 10.1021/acs.chemrev.4c00188

Synthesis of Functionalized Indolobenzazepinones via Sc(OTf)3-Induced Ring Expansion/Annulation Reactions of 4-Diazoisoquinolin-3-ones with Isatins

Jianwei Xie, Muhammad Suleman, Ke Zhang, Ping Lu and Yanguang Wang

J. Org. Chem., 2022, 87, 15938
DOI: 10.1021/acs.joc.2c02076

Metal-Free Insertion Reactions of Diazo Carbonyls to Azlactones

Amanda C. de Mello, Patrícia B. Momo, Antonio C. B. Burtoloso and Giovanni W. Amarante

J. Org. Chem., 2018, 83, 11399
DOI: 10.1021/acs.joc.8b01683

Enantioselective Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds

Durga Prasad Hari and Jerome Waser

J. Am. Chem. Soc., 2017, 139, 8420
DOI: 10.1021/jacs.7b04756

Palladium Catalysis in the Intramolecular Carbene C–H Insertion of α‐Diazo‐α‐(methoxycarbonyl)acetamides to Form β‐Lactams

Daniel Solé, Ferran Pérez‐Janer, M.‐Lluïsa Bennasar and Israel Fernández

Eur J Org Chem, 2018, 2018, 4446
DOI: 10.1002/ejoc.201800666

Oxa‐TriQuinoline: A New Entry to Aza‐Oxa‐Crown Architectures**

Toi Kobayashi and Naoya Kumagai

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202307896

Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds with Hypervalent Iodine Reagents

Durga Prasad Hari and Jerome Waser

J. Am. Chem. Soc., 2016, 138, 2190
DOI: 10.1021/jacs.6b00278

A Copper‐Benzotriazole‐Based Coordination Polymer Catalyzes the Efficient One‐Pot Synthesis of (N′‐Substituted)‐hydrazo‐4‐aryl‐1,4‐dihydropyridines from Azines

Michael Kallitsakis, Edward Loukopoulos, Alaa Abdul‐Sada, Graham J. Tizzard, Simon J. Coles, George E. Kostakis and Ioannis N. Lykakis

Adv Synth Catal, 2017, 359, 138
DOI: 10.1002/adsc.201601072

Palladium(II)-Catalyzed Cross-Coupling of Diazo Compounds and Isocyanides to Access Ketenimines

Zhaohong Liu, Shanshan Cao, Jiayi Wu, Giuseppe Zanoni, Paramasivam Sivaguru and Xihe Bi

ACS Catal., 2020, 10, 12881
DOI: 10.1021/acscatal.0c02867

Oxidative CH Bond Functionalization and Ring Expansion with TMSCHN2: A Copper(I)‐Catalyzed Approach to Dibenzoxepines and Dibenzoazepines

Tobias Stopka, Leyre Marzo, Mercedes Zurro, Simon Janich, Ernst‐Ulrich Würthwein, Constantin G. Daniliuc, José Alemán and Olga García Mancheño

Angew Chem Int Ed, 2015, 54, 5049
DOI: 10.1002/anie.201411726

Hantzsch Ester-Mediated Benzannulation of Diazo Compounds under Visible Light Irradiation

Savita B. Nagode, Ruchir Kant and Namrata Rastogi

Org. Lett., 2019, 21, 6249
DOI: 10.1021/acs.orglett.9b02135

Enantioselective insertion of carbenoids into N–H bonds catalyzed by chiral bicyclobisoxazoline copper(I) complexes

Paul Le Maux and Gérard Simonneaux

Tetrahedron, 2015, 71, 9333
DOI: 10.1016/j.tet.2015.10.009

Transition-Metal-Catalyzed Cross-Couplings through Carbene Migratory Insertion

Ying Xia, Di Qiu and Jianbo Wang

Chem. Rev., 2017, 117, 13810
DOI: 10.1021/acs.chemrev.7b00382

Cu-Catalyzed Synthesis of Fluoroalkylated Isoxazoles from Commercially Available Amines and Alkynes

Xiao-Wei Zhang, Wen-Li Hu, Suo Chen and Xiang-Guo Hu

Org. Lett., 2018, 20, 860
DOI: 10.1021/acs.orglett.7b04028

Catalytic Asymmetric Fluorination of Copper Carbene Complexes: Preparative Advances and a Mechanistic Rationale

Michael Buchsteiner, Luis Martinez‐Rodriguez, Paul Jerabek, Iago Pozo, Michael Patzer, Nils Nöthling, Christian W. Lehmann and Alois Fürstner

Chemistry A European J, 2020, 26, 2509
DOI: 10.1002/chem.202000081

Asymmetric CuI-Catalyzed Insertion Reaction of 1-Aryl-2,2,2-trifluoro-1-diazoethanes into Si–H Bonds

Virginie Carreras, Claire Besnard, Vincent Gandon and Thierry Ollevier

Org. Lett., 2019, 21, 9094
DOI: 10.1021/acs.orglett.9b03480

Regiodivergent Synthesis of Pyrazolines with a Quaternary Carbon Center via Cycloaddition of Diazoesters to N-Purine-Substituted Allenes

Ming-Sheng Xie, Zhen Guo, Gui-Rong Qu and Hai-Ming Guo

Org. Lett., 2018, 20, 5010
DOI: 10.1021/acs.orglett.8b02161

Light Induced Cobalt(III) Carbene Radical Formation from Dimethyl Malonate As Carbene Precursor

Demi D. Snabilié, Rens Ham, Joost N. H. Reek and Bas de Bruin

Organometallics, 2024, 43, 1299
DOI: 10.1021/acs.organomet.4c00127

Rhodium-Catalyzed Regiodivergent [3 + 2] and [5 + 2] Cycloadditions of Quinolinium Ylides with Alkynes

Min He, Nuan Chen, Jian Wang and Shiyong Peng

Org. Lett., 2019, 21, 5167
DOI: 10.1021/acs.orglett.9b01765

Enantioselective Intramolecular Carbene C–H Insertion Catalyzed by a Chiral Iridium(III) Complex of D4-Symmetric Porphyrin Ligand

Jing-Cui Wang, Yan Zhang, Zhen-Jiang Xu, Vanessa Kar-Yan Lo and Chi-Ming Che

ACS Catal., 2013, 3, 1144
DOI: 10.1021/cs4001656

Formal [4+1] Annulation Reactions in the Synthesis of Carbocyclic and Heterocyclic Systems

Jia-Rong Chen, Xiao-Qiang Hu, Liang-Qiu Lu and Wen-Jing Xiao

Chem. Rev., 2015, 115, 5301
DOI: 10.1021/cr5006974

Catalyst‐Free Synthesis of α‐Diazoketones in Water by Microwave Promoted Enaminone C=C Double Bond Cleavage

Lu Gan, Li Wei and Jie‐Ping Wan

ChemistrySelect, 2020, 5, 7822
DOI: 10.1002/slct.202002247

Neue Ansätze für die Synthese von Metallcarbenen

Minqiang Jia and Shengming Ma

Angewandte Chemie, 2016, 128, 9280
DOI: 10.1002/ange.201508119

Stereoselective Synthesis of Tetrahydroindolizines through the Catalytic Formation of Pyridinium Ylides from Diazo Compounds

Jonathan Day, Ben McKeever‐Abbas and James Dowden

Angew Chem Int Ed, 2016, 55, 5809
DOI: 10.1002/anie.201511047

Three-component redox-neutral alkene difunctionalization by radical copper catalysis

Zhiming Feng, Jincai Zheng, Wei Zhou, Cong-Ying Zhou and Chengming Wang

Tetrahedron Chem, 2025, 15, 100144
DOI: 10.1016/j.tchem.2025.100144

Chemoselective Methionine Bioconjugation: Site-Selective Fluorine-18 Labeling of Proteins and Peptides

Daniel Lin, Michael Wallace, Alban J. Allentoff, David J. Donnelly, Erin Gomes, Kim Voronin, Sharon Gong, Richard Y.-C. Huang, Ho Kim, Janet Caceres-Cortes and Samuel Bonacorsi

Bioconjugate Chem., 2020, 31, 1908
DOI: 10.1021/acs.bioconjchem.0c00256

Cu(I)-Catalyzed Tandem Reaction of Carbene Coupling and Horner–Wadsworth–Emmons Type Olefination: Access toward Enynes

Yujing Zhou, Fei Ye, Qi Zhou, Yan Zhang and Jianbo Wang

Org. Lett., 2016, 18, 2024
DOI: 10.1021/acs.orglett.6b00631

One-pot synthesis of polyfunctional pyrazoles: an easy access to α-diazoketones from arylglyoxal monohydrates and tosylhydrazine

Wen-Ming Shu, Jun-Rui Ma, Kai-Lu Zheng, Hui-Ying Sun, Mei Wang, Yan Yang and An-Xin Wu

Tetrahedron, 2014, 70, 9321
DOI: 10.1016/j.tet.2014.10.044

Gold-Catalyzed Controllable C2-Functionalization of Benzofurans with Aryl Diazoesters

Guangyang Xu, Kai Liu and Jiangtao Sun

Org. Lett., 2018, 20, 72
DOI: 10.1021/acs.orglett.7b03390

Copper (I)‐BOX Catalyzed Asymmetric 3‐Component Reaction for the Synthesis of Trifluoromethylated Propargylic Ethers and Anilines**

Nieves P. Ramirez and Jerome Waser

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202305776

Copper-Catalyzed Coupling of Thioamides and Donor/Acceptor-Substituted Carbenoids: Synthesis of Enamino Esters and Enaminones

Arpan Pal and Syed Raziullah Hussaini

ACS Omega, 2019, 4, 269
DOI: 10.1021/acsomega.8b02633

Divergent Synthesis of Fused Tricyclic Compounds via a Tandem Reaction from Alkynyl-cyclohexadienones and Diazoesters

Guangyang Xu, Kai Liu and Jiangtao Sun

Org. Lett., 2017, 19, 6440
DOI: 10.1021/acs.orglett.7b03356

Funktionalisierung nichtaktivierter C(sp3)‐H‐Bindungen durch Metallcarben‐Insertionen

Miguel Peña‐López and Matthias Beller

Angewandte Chemie, 2017, 129, 46
DOI: 10.1002/ange.201609033

Efficient One‐Pot Synthesis of Multi‐Substituted Dihydrofurans by Ruthenium(II)‐Catalyzed [3+2] Cycloaddition of Cyclic or Acyclic Diazodicarbonyl Compounds with Olefins

Likai Xia and Yong Rok Lee

Adv Synth Catal, 2013, 355, 2361
DOI: 10.1002/adsc.201300245

A Rh(II)-catalyzed highly stereoselective [3 + 2] annulation of vinyl diazoacetates with indole-2-carbaldehyde for the synthesis of indolyl dihydrofurans

Rimei Zheng, Aimin Xu, Jiawu Huang, Zhijing Zhang, Xinru Yin, Tianyuan Zhang, Wenhao Hu and Yu Qian

Mol Divers, 2022, 26, 3379
DOI: 10.1007/s11030-022-10381-0

In Situ Generation of Quinolinium Ylides from Diazo Compounds: Copper-Catalyzed Synthesis of Indolizine

Rongxiang Chen, Yanwei Zhao, Hongmei Sun, Ying Shao, Yudong Xu, Meihua Ma, Liang Ma and Xiaobing Wan

J. Org. Chem., 2017, 82, 9291
DOI: 10.1021/acs.joc.7b01042

Transition-Metal-Catalyzed Ring Expansion of Diazocarbonylated Cyclic N-Hydroxylamines: A New Approach to Cyclic Ketonitrones

Evelyn Lieou Kui, Alice Kanazawa, Jean-François Poisson and Sandrine Py

Org. Lett., 2014, 16, 4484
DOI: 10.1021/ol502029z

Oxidation State Dichotomy in Copper‐Catalyzed Intramolecular Cyclization of α‐Diazoanilides: An Integrated Synthetic Platform for Oxindoles and Isatins Enabled by Oxygenase‐Type Reactivity

Parul Garg, Santosh D. Jadhav and Anand Singh

Asian J Org Chem, 2017, 6, 1019
DOI: 10.1002/ajoc.201700192

Asymmetric Construction of Spirooxindoles by Organocatalytic Multicomponent Reactions Using Diazooxindoles

Ming‐Yue Wu, Wei‐Wei He, Xin‐Yuan Liu and Bin Tan

Angewandte Chemie, 2015, 127, 9541
DOI: 10.1002/ange.201504640

Synthesis of 5-Iodo-1,2,3,4-tetrahydropyridines by Rhodium-Catalyzed Tandem Nucleophilic Attacks Involving 1-Sulfonyl-1,2,3-triazoles and Iodides

Zengming Man, Haican Dai, Yinping Shi, Dongdong Yang and Chuan-Ying Li

Org. Lett., 2016, 18, 4962
DOI: 10.1021/acs.orglett.6b02428

Synthesis of Pyridines by Carbenoid‐Mediated Ring Opening of 2H‐Azirines

Nicole S. Y. Loy, Alok Singh, Xianxiu Xu and Cheol‐Min Park

Angew Chem Int Ed, 2013, 52, 2212
DOI: 10.1002/anie.201209301

Copper(II) phthalocyanine as an efficient and versatile catalyst for click reactions at room temperature

Kumar Karitkey Yadav, Uma Narang, P. K. Sahu and S. M. S. Chauhan

J IRAN CHEM SOC, 2022, 19, 4359
DOI: 10.1007/s13738-022-02609-5

Access to Syn α‐Amino‐β‐Hydroxyesters by N−H Insertion on O‐Protected α‐Diazo‐β‐Hydroxyesters

Thomas Defuentes, Jérôme Lhoste, Catherine Gaulon‐Nourry, Anne‐Sophie Castanet and Anne‐Caroline Chany

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202400539

Yury V. Tomilov, Leonid G. Menchikov, Evgeny A. Shapiro, Valentin D. Gvozdev, Konstantin N. Shavrin, Nikolay V. Volchkov, Maria B. Lipkind, Mikhail P. Egorov, Sergey E. Boganov, Valery N. Khabashesku and Esfir G. Baskir

Mendeleev Communications, 2021, 31, 750
DOI: 10.1016/j.mencom.2021.11.002

Oxa‐TriQuinoline: A New Entry to Aza‐Oxa‐Crown Architectures**

Toi Kobayashi and Naoya Kumagai

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202307896

Nucleophilic Halogenations of Diazo Compounds, a Complementary Principle for the Synthesis of Halodiazo Compounds: Experimental and Theoretical Studies

Christian Schnaars, Martin Hennum and Tore Bonge-Hansen

J. Org. Chem., 2013, 78, 7488
DOI: 10.1021/jo401050c

Oxidative C‐H‐Funktionalisierung und Ringerweiterung mit TMSCHN2: ein Kupfer(I)‐katalysierter Zugang zu Dibenzoxepinen und Dibenzazepinen

Tobias Stopka, Leyre Marzo, Mercedes Zurro, Simon Janich, Ernst‐Ulrich Würthwein, Constantin G. Daniliuc, José Alemán and Olga García Mancheño

Angewandte Chemie, 2015, 127, 5137
DOI: 10.1002/ange.201411726

Synthesis of Pyridines by Carbenoid‐Mediated Ring Opening of 2H‐Azirines

Nicole S. Y. Loy, Alok Singh, Xianxiu Xu and Cheol‐Min Park

Angewandte Chemie, 2013, 125, 2268
DOI: 10.1002/ange.201209301

Gold(I)-catalyzed [4 + 1]/[4 + 3] annulations of diazo esters with hexahydro-1,3,5-triazines: Theoretical study of mechanism and regioselectivity

Luo-yi Zhou, Xian-ming Guo, Zhong-chao Zhang and Juan Li

Journal of Organometallic Chemistry, 2019, 897, 70
DOI: 10.1016/j.jorganchem.2019.06.032

Copper-Catalyzed [5 + 1] Cyclization of o-Pyrrolo Anilines and Heterocyclic N-Tosylhydrazones for Access to Spiro-dihydropyrrolo[1,2-a]quinoxaline Derivatives

Yan Long, Yun Wang, Yue-You Chen, Wen-Yong Han, Nan-Wei Wan, Wei-Cheng Yuan, Yong-Zheng Chen and Bao-Dong Cui

J. Org. Chem., 2022, 87, 4112
DOI: 10.1021/acs.joc.1c02909

Synthesis of Cyclopropanes via 1,3-Migration of Acyloxy Groups Triggered by Formation of α-Imino Rhodium Carbenes

Ze-Feng Xu, Jincheng Liu, Xin Chang, Tao Chen, Huaping Xu, Shengguo Duan and Chuan-Ying Li

Org. Lett., 2020, 22, 5163
DOI: 10.1021/acs.orglett.0c01764

Photo‐Induced Homologation of Carbonyl Compounds for Iterative Syntheses

Hua Wang, Shun Wang, Vincent George, Galder Llorente and Burkhard König

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202211578

Chemodivergent Synthesis of Oxazoles and Oxime Ethers Initiated by Selective C–N/C–O Formation of Oximes and Diazo Esters

Zhenjie Qi and Shaozhong Wang

Org. Lett., 2021, 23, 8549
DOI: 10.1021/acs.orglett.1c03252

Skeletal Editing: Ring Insertion for Direct Access to Heterocycles

Xue Li and Zhigang Xu

Molecules, 2024, 29, 1920
DOI: 10.3390/molecules29091920

Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions

Adam Cook and Stephen G. Newman

Chem. Rev., 2024, 124, 6078
DOI: 10.1021/acs.chemrev.4c00094

Reaction of Diazo Compounds with Difluorocarbene: An Efficient Approach towards 1,1‐Difluoroolefins

Zhikun Zhang, Weizhi Yu, Chenggui Wu, Chengpeng Wang, Yan Zhang and Jianbo Wang

Angew Chem Int Ed, 2016, 55, 273
DOI: 10.1002/anie.201509711

Copper(I) Oxide‐Mediated Cyclization of o‐Haloaryl N‐Tosylhydrazones: Efficient Synthesis of Indazoles

Meng Tang, Yuanfang Kong, Bingjie Chu and Dan Feng

Adv Synth Catal, 2016, 358, 926
DOI: 10.1002/adsc.201500953

Computational advances aiding mechanistic understanding of silver-catalyzed carbene/nitrene/silylene transfer reactions

Jing Zhang, Chunhui Shan, Tao Zhang, Jinshuai Song, Tao Liu and Yu Lan

Coordination Chemistry Reviews, 2019, 382, 69
DOI: 10.1016/j.ccr.2018.12.009

Copper-Catalyzed, Aerobic Oxidation of Hydrazone in a Three-Phase Packed Bed Reactor

Taylor A. Hatridge, Bo Wei, Huw M. L. Davies and Christopher W. Jones

Org. Process Res. Dev., 2021, 25, 1911
DOI: 10.1021/acs.oprd.1c00165

Non‐Canonical Reactivity of Gold Carbene with Alkyne: An Overview of the Mechanistic Premise

Shashank P. Sancheti and Nitin T. Patil

Eur J Org Chem, 2021, 2021, 1321
DOI: 10.1002/ejoc.202001528

Iron Porphyrin-Catalyzed Three-Component Reaction of Ethyl Diazoacetate with Aliphatic Amines and β,γ-Unsaturated α-Keto Esters

Chaoqun Ma, Dong Xing, Changwei Zhai, Jiuwei Che, Shunying Liu, Jue Wang and Wenhao Hu

Org. Lett., 2013, 15, 6140
DOI: 10.1021/ol403011r

Green Synthesis of 2‐Aminobenzothiazoles via Copper Catalysis under Microwave Irradiation

Padinjare Veetil Saranya, Salim Saranya, Raju Dhanya and Gopinathan Anilkumar

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202202718

Enantioselective Denitrogenative Annulation of 1H‐Tetrazoles with Styrenes Catalyzed by Rhodium

Takayuki Nakamuro, Kohei Hagiwara, Tomoya Miura and Masahiro Murakami

Angew Chem Int Ed, 2018, 57, 5497
DOI: 10.1002/anie.201801283

Copper(II)–acid catalyzed cyclopropanation of 1,3-dienamides by electrophilic activation of α-aryl diazoesters

Eiji Tayama, Kouki Horikawa, Hajime Iwamoto and Eietsu Hasegawa

Tetrahedron Letters, 2014, 55, 3041
DOI: 10.1016/j.tetlet.2014.03.115

Divergent pathways of β,γ-unsaturated α-diazocarbonyl compounds catalyzed by dirhodium and Lewis acids catalysts separately or in combination

Xin-Fang Xu and Michael P. Doyle

Chinese Chemical Letters, 2015, 26, 227
DOI: 10.1016/j.cclet.2014.12.014

Enzyme-catalyzed addition of diazo compounds to in-situ generated imines

Priya Kamboj and Vikas Tyagi

Tetrahedron, 2023, 137, 133389
DOI: 10.1016/j.tet.2023.133389

Asymmetric Construction of Spirooxindoles by Organocatalytic Multicomponent Reactions Using Diazooxindoles

Ming‐Yue Wu, Wei‐Wei He, Xin‐Yuan Liu and Bin Tan

Angew Chem Int Ed, 2015, 54, 9409
DOI: 10.1002/anie.201504640

Diversity‐Oriented Three‐Component Reactions of Diazo Compounds with Anilines and 4‐Oxo‐Enoates

Changcheng Jing, Dong Xing, Yu Qian, Taoda Shi, Yun Zhao and Wenhao Hu

Angew Chem Int Ed, 2013, 52, 9289
DOI: 10.1002/anie.201303987

Palladium-Catalyzed Denitrogenative Synthesis of Aryl Ketones from Arylhydrazines and Nitriles Using O2 as Sole Oxidant

Xu Wang, Yubing Huang, Yanli Xu, Xiaodong Tang, Wanqing Wu and Huanfeng Jiang

J. Org. Chem., 2017, 82, 2211
DOI: 10.1021/acs.joc.6b02697

Tandem Carbenoid C–H Functionalization/Conia-ene Cyclization of N-Propargyl Indoles Generates Pyrroloindoles under Cooperative Rh(II)/Zn(II) Catalysis

Aabid H. Bhat, Sima Alavi and Huck K. Grover

Org. Lett., 2020, 22, 224
DOI: 10.1021/acs.orglett.9b04210

Nucleophilic Addition of Amines to Ruthenium Carbenes: ortho‐(Alkynyloxy)benzylamine Cyclizations towards 1,3‐Benzoxazines

Carlos González‐Rodríguez, José Ramón Suárez, Jesús A. Varela and Carlos Saá

Angewandte Chemie, 2015, 127, 2762
DOI: 10.1002/ange.201410284

Application of carbene chemistry in the synthesis of organofluorine compounds

Xuyong Wang, Xi Wang and Jianbo Wang

Tetrahedron, 2019, 75, 949
DOI: 10.1016/j.tet.2019.01.016

Gold(I)-Catalyzed Hydroxy Group Assisted C(sp2)–H Alkylation of Enaminones with Diazo Compounds To Access 3-Alkyl Chromones

Pradip N. Bagle, Manoj V. Mane, Shashank P. Sancheti, Amol B. Gade, Samir R. Shaikh, Mu-Hyun Baik and Nitin T. Patil

Org. Lett., 2019, 21, 335
DOI: 10.1021/acs.orglett.8b03989

A Carbene‐Extended ATRA Reaction

Guojiao Wu, Jennifer Börger and Axel Jacobi von Wangelin

Angewandte Chemie, 2019, 131, 17401
DOI: 10.1002/ange.201909872

Copper-Catalyzed Carbenoid Insertion Reactions of α-Diazoesters and α-Diazoketones into Si–H and S–H Bonds

Hoda Keipour, Angela Jalba, Léo Delage-Laurin and Thierry Ollevier

J. Org. Chem., 2017, 82, 3000
DOI: 10.1021/acs.joc.6b02998

Copper-Catalyzed Denitrogenative Transannulation Reaction of Pyridotriazoles: Synthesis of Imidazo[1,5-a]pyridines with Amines and Amino Acids

Abhisek Joshi, Darapaneni Chandra Mohan and Subbarayappa Adimurthy

Org. Lett., 2016, 18, 464
DOI: 10.1021/acs.orglett.5b03509

Stereoselective Synthesis of Tetrahydroindolizines through the Catalytic Formation of Pyridinium Ylides from Diazo Compounds

Jonathan Day, Ben McKeever‐Abbas and James Dowden

Angewandte Chemie, 2016, 128, 5903
DOI: 10.1002/ange.201511047

Exploring the Metal‐Catalyzed Reactions of α‐Diazo‐β‐hydroxyamino Esters: Conversion of Cyclic Aldonitrones into Ketonitrones

Evelyn Lieou Kui, Alice Kanazawa, Christian Philouze, Jean‐François Poisson and Sandrine Py

Eur J Org Chem, 2017, 2017, 363
DOI: 10.1002/ejoc.201601255

Iodine-catalyzed diazo activation to access radical reactivity

Pan Li, Jingjing Zhao, Lijun Shi, Jin Wang, Xiaodong Shi and Fuwei Li

Nat Commun, 2018, 9
DOI: 10.1038/s41467-018-04331-4

Research Progress on Enantioselective Desymmetrization Reactions Involving Metal Carbenes

Ming-Yu Teng, Tao Han, En-He Huang and Long-Wu Ye

Chinese Journal of Organic Chemistry, 2022, 42, 3295
DOI: 10.6023/cjoc202206041

Catalyst Free Chemoselective Carbene Insertion Into COO─H Bond Over ─OH of Salicylic Acid

Gruhapriya Jelakam, Swaraj Dey, Vikiho Wotsa and Chinnappan Sivasankar

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202405088

Palladium-Catalyzed Intermolecular Carbene Insertion Prior to Intramolecular Heck Cyclization: Synthesis of 2-Arylidene-3-aryl-1-indanones

Dhanarajan Arunprasath, Pandi Muthupandi and Govindasamy Sekar

Org. Lett., 2015, 17, 5448
DOI: 10.1021/acs.orglett.5b02803

Photoinduced C–Cl Bond Activation of Polychloroalkanes with Triplet Carbenes: Synthetic Applications and Mechanistic Studies

Bina Das, Buddhadeb Sahana and Durga Prasad Hari

JACS Au, 2025, 5, 291
DOI: 10.1021/jacsau.4c00970

A New Reactivity Mode for the Diazo Group: Diastereoselective 1,3‐Aminoalkylation Reaction of β‐Amino‐α‐Diazoesters To Give Triazolines

Alexey Kuznetsov, Anton V. Gulevich, Donald J. Wink and Vladimir Gevorgyan

Angewandte Chemie, 2014, 126, 9167
DOI: 10.1002/ange.201404352

3d Transition Metals for C–H Activation

Parthasarathy Gandeepan, Thomas Müller, Daniel Zell, Gianpiero Cera, Svenja Warratz and Lutz Ackermann

Chem. Rev., 2019, 119, 2192
DOI: 10.1021/acs.chemrev.8b00507

Gold‐Catalyzed Formal [4+1]/[4+3] Cycloadditions of Diazo Esters with Triazines

Chenghao Zhu, Guangyang Xu and Jiangtao Sun

Angewandte Chemie, 2016, 128, 12046
DOI: 10.1002/ange.201606139

ChemInform Abstract: Recent Developments in Copper‐Catalyzed Reactions of Diazo Compounds

Xia Zhao, Yan Zhang and Jianbo Wang

ChemInform, 2013, 44
DOI: 10.1002/chin.201301174

Unusual reactions of diazocarbonyl compounds with α,β-unsaturated δ-amino esters: Rh(II)-catalyzed Wolff rearrangement and oxidative cleavage of N–H-insertion products

Valerij A Nikolaev, Jury J Medvedev, Olesia S Galkina, Ksenia V Azarova and Christoph Schneider

Beilstein J. Org. Chem., 2016, 12, 1904
DOI: 10.3762/bjoc.12.180

Borane Catalyzed Selective Diazo Cross‐Coupling Towards Pyrazoles

Ayan Dasgupta, Sanjukta Pahar, Rasool Babaahmadi, Lukas Gierlichs, Brian F. Yates, Alireza Ariafard and Rebecca L. Melen

Adv Synth Catal, 2022, 364, 773
DOI: 10.1002/adsc.202101312

Tunable Key [3 + 2] and [2 + 1] Cycloaddition of Enaminones and α-Diazo Compounds for the Synthesis of Isomeric Isoxazoles: Metal-Controlled Selectivity

Wenli Song, Yunyun Liu, Nan Yan and Jie-Ping Wan

Org. Lett., 2023, 25, 2139
DOI: 10.1021/acs.orglett.3c00636