Annette Frischmuth, Maitane Fernández, Nadja M. Barl, Florian Achrainer, Hendrik Zipse, Guillaume Berionni, Herbert Mayr, Konstantin Karaghiosoff and Paul Knochel

Angewandte Chemie, 2014, 126, 8062
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Suzuki‐Miyaura cross–coupling reaction in water: facile synthesis of (hetero) aryl uracil bases using potassiumorganotrifluoroborates under microwave irradiation.

Bhaskaran Savitha, Ayyiliath M. Sajith, Eeda Koti Reddy, C. S. Ananda Kumar and M. Syed Ali Padusha

ChemistrySelect, 2016, 1, 4721
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Recent applications of magnesium- and Zinc-TMP amides in the synthesis of bioactive targets

Rodolfo H.V. Nishimura, Artur de L.L. Vaz, Leandro A. Bozzini, Valter E. Murie and Giuliano C. Clososki

Tetrahedron, 2019, 75, 464
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Regioselective Functionalization of the Oxazole Scaffold Using TMP-Bases of Mg and Zn

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Org. Lett., 2013, 15, 6162
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New In Situ Trapping Metalations of Functionalized Arenes and Heteroarenes with TMPLi in the Presence of ZnCl2 and Other Metal Salts

Annette Frischmuth, Maitane Fernández, Nadja M. Barl, Florian Achrainer, Hendrik Zipse, Guillaume Berionni, Herbert Mayr, Konstantin Karaghiosoff and Paul Knochel

Angew Chem Int Ed, 2014, 53, 7928
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Preparations and Reactions of SF5‐Substituted Aryl and Heteroaryl Derivatives via Mg and Zn Organometallics

Annette Frischmuth, Andreas Unsinn, Klaus Groll, Heinz Stadtmüller and Paul Knochel

Chemistry A European J, 2012, 18, 10234
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Selective Magnesiation or Zincation of Highly Functionalized Alkenes and Cycloalkenes Using 2,2,6,6‐Tetramethylpiperidyl Bases

Tomke Bresser and Paul Knochel

Angew Chem Int Ed, 2011, 50, 1914
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Synthesis of Functionalized Pyridazin-3(2H)-ones via Selective Bromine–Magnesium Exchange and Lactam Directed Ortho C–H Magnesiation

Tom Verhelst, Jens Maes, Zuming Liu, Sergey Sergeyev and Bert U. W. Maes

J. Org. Chem., 2011, 76, 6670
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ChemInform Abstract: Regio‐ and Chemoselective Magnesiation of Protected Uracils and Thiouracils Using TMPMgCl×LiCl and TMP2Mg×2LiCl.

Marc Mosrin, Nadege Boudet and Paul Knochel

ChemInform, 2009, 40
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Directed Zincation with TMPZnCl·LiCl and Further Functionalization of the Tropolone Scaffold

Diana Haas, Daniela Sustac-Roman, Sophia Schwarz and Paul Knochel

Org. Lett., 2016, 18, 6380
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Scalable and Straightforward Synthesis of All Isomeric (Cyclo)alkylpiperidines

Andrii I. Subota, Anton O. Lutsenko, Bohdan V. Vashchenko, Dmitriy M. Volochnyuk, Vitalina Levchenko, Yurii V. Dmytriv, Eduard B. Rusanov, Alina O. Gorlova, Sergey V. Ryabukhin and Oleksandr O. Grygorenko

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Scaleable Preparation of Sensitive Functionalized Aromatics and Heteroaromatics via Directed Metalation Using tmpZnCl·LiCl

Tomke Bresser, Gabriel Monzon, Marc Mosrin and Paul Knochel

Org. Process Res. Dev., 2010, 14, 1299
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Regioselective Direct C–H Arylations of Protected Uracils. Synthesis of 5- and 6-Aryluracil Bases

Miroslava Čerňová, Igor Čerňa, Radek Pohl and Michal Hocek

J. Org. Chem., 2011, 76, 5309
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Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives

Julia Nafe, Florian Auras, Konstantin Karaghiosoff, Thomas Bein and Paul Knochel

Org. Lett., 2015, 17, 5356
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Transition‐Metal‐Free Transformation of Aryl Bromides into Aromatic Esters and Amides via Aryl Trichloromethyl Ketones

Souya Dohi, Katsuhiko Moriyama and Hideo Togo

Eur J Org Chem, 2013, 2013, 7815
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Luftstabile feste aromatische und heterocyclische Zinkreagentien durch hochselektive Metallierungen für Negishi‐Kreuzkupplungen

Christos I. Stathakis, Sebastian Bernhardt, Valentin Quint and Paul Knochel

Angewandte Chemie, 2012, 124, 9563
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Structurally Powered Synergic 2,2,6,6-Tetramethylpiperidine Bimetallics: New Reflections through Lithium-Mediated Ortho Aluminations

Robert E. Mulvey, David R. Armstrong, Ben Conway, Elaine Crosbie, Alan R. Kennedy and Stuart D. Robertson

Inorg. Chem., 2011, 50, 12241
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Synthesis of Pyrrolo[2,3‐d]pyrimidines by Copper‐Mediated Carbomagnesiations of N‐Sulfonyl Ynamides and Application to the Preparation of Rigidin A and a 7‐Azaserotonin Derivative

Johannes Nickel, Maitane Fernández, Lydia Klier and Paul Knochel

Chemistry A European J, 2016, 22, 14397
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An Expedient and Divergent Tandem One-Pot Synthesis of Pyrimidin-2,4-diones Using the Blaise Reaction Intermediate

Yu Sung Chun, Zi Xuan, Ju Hyun Kim and Sang-gi Lee

Org. Lett., 2013, 15, 3162
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Exploiting Coordination Effects for the Regioselective Zincation of Diazines Using TMPZnX⋅LiX (X=Cl, Br)

Alexander Kremsmair, Alisa S. Sunagatullina, Leonie J. Bole, Pasquale Mastropierro, Simon Graßl, Henrik R. Wilke, Edouard Godineau, Eva Hevia and Paul Knochel

Angew Chem Int Ed, 2022, 61
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Regioselective Metalations of Pyrimidines and Pyrazines by Using Frustrated Lewis Pairs of BF3⋅OEt2 and Hindered Magnesium– and Zinc–Amide Bases

Klaus Groll, Sophia M. Manolikakes, Xavier Mollat du Jourdin, Milica Jaric, Aleksei Bredihhin, Konstantin Karaghiosoff, Thomas Carell and Paul Knochel

Angew Chem Int Ed, 2013, 52, 6776
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Regio‐ and Chemoselective Metalation of Chloropyrimidine Derivatives with TMPMgCl⋅LiCl and TMP2Zn⋅2 MgCl2⋅2 LiCl

Marc Mosrin and Paul Knochel

Chemistry A European J, 2009, 15, 1468
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Regio‐ und chemoselektive Metallierung von Arenen und Heteroarenen mit gehinderten Metallamidbasen

Benjamin Haag, Marc Mosrin, Hiriyakkanavar Ila, Vladimir Malakhov and Paul Knochel

Angewandte Chemie, 2011, 123, 9968
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Switching the Regioselectivity of Direct C–H Arylation of 1,3‐Dimethyluracil

Miroslava Čerňová, Radek Pohl and Michal Hocek

Eur J Org Chem, 2009, 2009, 3698
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Ausnutzung von Koordinationseffekten für die Regioselektive Zinkierung von Diazinen mit TMPZnX⋅LiX (X=Cl, Br)

Alexander Kremsmair, Alisa S. Sunagatullina, Leonie J. Bole, Pasquale Mastropierro, Simon Graßl, Henrik R. Wilke, Edouard Godineau, Eva Hevia and Paul Knochel

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A Highly Efficient Catalyst for the Suzuki‐Miyaura Cross‐Coupling Reaction of 5‐(5‐chloropyridin‐3‐yl)‐3‐methyl‐1,3,4‐oxadiazol‐2(3H)‐one

Bhaskaran Savitha, Eeda Koti Reddy, D. Parthasarathi, Rajeesh Pakkath, Ayyiliath M. Sajith, C. S. Ananda kumar, Karickal R. Haridas and M. Syed Ali Padusha

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TMPZnCl·LiCl: A New Active Selective Base for the Directed Zincation of Sensitive Aromatics and Heteroaromatics

Marc Mosrin and Paul Knochel

Org. Lett., 2009, 11, 1837
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Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 2. Syntheses and Reactivities of Homo/HeteroMAAs

Florence Mongin and Anne Harrison-Marchand

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Regio- and Chemoselective Zincation of Sensitive and Moderately Activated Aromatics and Heteroaromatics Using TMPZnCl·LiCl

Tomke Bresser, Marc Mosrin, Gabriel Monzon and Paul Knochel

J. Org. Chem., 2010, 75, 4686
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Regioselektive Metallierungen von Pyrimidinen und Pyrazinen mit frustrierten Lewis‐Paaren aus BF3⋅OEt2 und sterisch gehinderten Mg‐ und Zn‐Amidbasen

Klaus Groll, Sophia M. Manolikakes, Xavier Mollat du Jourdin, Milica Jaric, Aleksei Bredihhin, Konstantin Karaghiosoff, Thomas Carell and Paul Knochel

Angewandte Chemie, 2013, 125, 6909
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Grignard Reactions Involving Halogenated Pyrimidines

Thomas J. Delia

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Improved Air‐Stable Solid Aromatic and Heterocyclic Zinc Reagents by Highly Selective Metalations for Negishi Cross‐Couplings

Christos I. Stathakis, Sebastian Bernhardt, Valentin Quint and Paul Knochel

Angew Chem Int Ed, 2012, 51, 9428
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Chemoselektivität und die eigentümlichen Reaktivitäten funktioneller Gruppen

Nicholas A. Afagh and Andrei K. Yudin

Angewandte Chemie, 2010, 122, 270
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Functionalization of 2,4-Dichloropyrimidines by 2,2,6,6-Tetramethylpiperidyl Zinc Base Enables Modular Synthesis of Antimalarial Diaminopyrimidine P218 and Analogues

Matheus A. Meirelles, Ian de Toledo, Samuel Thurow, Gabriela Barreiro, Rafael M. Couñago and Ronaldo A. Pilli

J. Org. Chem., 2023, 88, 9475
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Synthesis of Fully Substituted Pyrazoles via Regio- and Chemoselective Metalations

Christina Despotopoulou, Lydia Klier and Paul Knochel

Org. Lett., 2009, 11, 3326
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Deprotonative Metalation of Functionalized Aromatics Using Mixed Lithium–Cadmium, Lithium–Indium, and Lithium–Zinc Species

Katia Snégaroff, Jean‐Martial L'Helgoual'ch, Ghenia Bentabed‐Ababsa, Tan Tai Nguyen, Floris Chevallier, Mitsuhiro Yonehara, Masanobu Uchiyama, Aïcha Derdour and Florence Mongin

Chemistry A European J, 2009, 15, 10280
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