Bridging π-coordination of pyrrole and indole over a PdI–PdI bond

Tetsuro Murahashi; Seita Kimura; Kohei Takase; Sensuke Ogoshi; Koji Yamamoto

doi:10.1039/C2CC37554K

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Bridging π-coordination of pyrrole and indole over a Pd^I–Pd^I bond†‡

Tetsuro Murahashi,*^ab Seita Kimura,^ac Kohei Takase,^c Sensuke Ogoshi^c and Koji Yamamoto^a

Author affiliations

* Corresponding authors

^a Institute for Molecular Science, Myodaiji, Okazaki, Aichi, Japan
E-mail: mura@ims.ac.jp
Fax: +81-564-59-5582

^b PRESTO, Japan Science and Technology Agency (JST), Japan

^c Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka, Japan

Abstract

π-Coordination of pyrrole or indole which lack a chelating functionality to a dinuclear Pd^I–Pd^I center is revealed. The dinuclear sandwich Pd^I–Pd^I complexes of pyrrole, N-methylpyrrole, or indole were synthesized and structurally characterized by X-ray crystallographic analysis. Indole employs the carbons of the six-membered ring in bridging π-coordination to a Pd^I–Pd^I center.

This article is part of the themed collection: Emerging Investigators 2013

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Article information

DOI: https://doi.org/10.1039/C2CC37554K
Article type: Communication
Submitted: 17 Okt 2012
Accepted: 03 Dez 2012
First published: 20 Dez 2012

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Chem. Commun., 2013,49, 4310-4312

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Bridging π-coordination of pyrrole and indole over a Pd^I–Pd^I bond

T. Murahashi, S. Kimura, K. Takase, S. Ogoshi and K. Yamamoto, Chem. Commun., 2013, 49, 4310 DOI: 10.1039/C2CC37554K

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