Issue 45, 2012

Aromaticity and π-bond covalency: prominent intermolecular covalent bonding interaction of a Kekulé hydrocarbon with very significant singlet biradical character§

Abstract

An anthracene-linked bisphenalenyl Kekulé molecule with very significant singlet biradical character has shown a prominent covalent bonding interaction between molecules in a molecular aggregate. High aromatic stabilization energy in the anthracene linker is responsible for the significant singlet biradical character.

Graphical abstract: Aromaticity and π-bond covalency: prominent intermolecular covalent bonding interaction of a Kekulé hydrocarbon with very significant singlet biradical character

  • This article is part of the themed collection: Aromaticity

Supplementary files

Article information

Article type
Communication
Submitted
17 Mrz 2012
Accepted
03 Apr 2012
First published
10 Apr 2012

Chem. Commun., 2012,48, 5629-5631

Aromaticity and π-bond covalency: prominent intermolecular covalent bonding interaction of a Kekulé hydrocarbon with very significant singlet biradical character

A. Shimizu, Y. Hirao, K. Matsumoto, H. Kurata, T. Kubo, M. Uruichi and K. Yakushi, Chem. Commun., 2012, 48, 5629 DOI: 10.1039/C2CC31955A

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