Microwave assisted covalent functionalization of C60@SWCNT peapods

Nikolaos Karousis; Solon P. Economopoulos; Yoko Iizumi; Toshiya Okazaki; Zheng Liu; Kazu Suenaga; Nikos Tagmatarchis

doi:10.1039/C0CC04108D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Microwave assisted covalent functionalization of C₆₀@SWCNT peapods†‡

Nikolaos Karousis,^a Solon P. Economopoulos,^a Yoko Iizumi,^bc Toshiya Okazaki,^bc Zheng Liu,^c Kazu Suenaga^c and Nikos Tagmatarchis*^a

Author affiliations

* Corresponding authors

^a Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Ave., Athens 116 35, Greece
E-mail: tagmatar@eie.gr
Fax: +30 210 7273794
Tel: +30 210 7273835

^b Department of Chemistry, University of Tsukuba, Tsukuba 305-8577, Japan

^c Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Central 5, 1-1-1 Higashi, Japan

Abstract

The covalent functionalization of the external wall of C₆₀@SWCNT peapods, by in situ generated aryl diazonium salts, assisted by microwave irradiation is reported. Spectroscopic, thermal and microscopy characterization was performed. Electrochemistry revealed the three reversible reductions of encapsulated C₆₀, however, shifted towards positive potentials when compared with those of intact C₆₀.

This article is part of the themed collection: Carbon nanostructures

Download options Please wait...

Supplementary files

Experimental details, spectroscopic and microscopy data PDF (1906K)

Article information

DOI: https://doi.org/10.1039/C0CC04108D
Article type: Communication
Submitted: 28 Sep 2010
Accepted: 22 Okt 2010
First published: 16 Nov 2010

Download Citation

Chem. Commun., 2010,46, 9110-9112

Permissions

Request permissions

Microwave assisted covalent functionalization of C₆₀@SWCNT peapods

N. Karousis, S. P. Economopoulos, Y. Iizumi, T. Okazaki, Z. Liu, K. Suenaga and N. Tagmatarchis, Chem. Commun., 2010, 46, 9110 DOI: 10.1039/C0CC04108D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications