Issue 49, 2024

Aminoarylation of alkynes using diarylanilines

Abstract

Intermolecular aminoarylation of alkynes is described, via addition of diarylanilines to alkynes and Smiles–Truce rearrangement. The transformation manipulates the C–N bond of anilines directly, with no requirement for organometallic reagents or transition metal catalysis. The enaminoate products are versatile building blocks for different classes of heterocycles.

Graphical abstract: Aminoarylation of alkynes using diarylanilines

Supplementary files

Article information

Article type
Communication
Submitted
24 Apr 2024
Accepted
21 Mai 2024
First published
22 Mai 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 6296-6299

Aminoarylation of alkynes using diarylanilines

Z. Liu and M. F. Greaney, Chem. Commun., 2024, 60, 6296 DOI: 10.1039/D4CC01935K

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