Issue 9, 2023

Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

Abstract

A photoredox catalysed 1,3-oxylallylation of aryl cyclopropanes was accomplished by reaction with carboxylic acids and allyl sulfones. The redox-neutral reaction proceeded in a highly regioselective manner under mild conditions with good functional group compatibility. Simple operation and successful application to the late-stage functionalization of several natural product and pharmaceutical molecule related carboxylic acids add extra merits to the current protocol.

Graphical abstract: Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

Supplementary files

Article information

Article type
Research Article
Submitted
23 Feb 2023
Accepted
24 Mrz 2023
First published
01 Apr 2023

Org. Chem. Front., 2023,10, 2147-2154

Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

D. Wang, H. Wang, Y. Xu, C. Zhang and C. Feng, Org. Chem. Front., 2023, 10, 2147 DOI: 10.1039/D3QO00281K

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