Issue 5, 2023

Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction

Abstract

Rhodium-catalysed hydroformylation, effective tool in bulk and fine-chemical synthesis, predominantly uses soluble metal complexes. For that reason, the metal leaching and the catalyst recycling are still the major drawbacks of this process. Single-atom catalysts have emerged as a powerful tool to combine the advantages of both homogeneous and heterogeneous catalysts. Since using an appropriate support material is key to create stable, finely dispersed, single-atom catalysts, here we show that Rh atoms anchored on graphitic carbon nitride are robust catalysts for the hydroformylation reaction of styrene.

Graphical abstract: Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction

Supplementary files

Article information

Article type
Paper
Submitted
09 Dez 2022
Accepted
12 Jan 2023
First published
12 Jan 2023
This article is Open Access
Creative Commons BY-NC license

Catal. Sci. Technol., 2023,13, 1425-1436

Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction

L. Jurado, J. Esvan, L. A. Luque-Álvarez, L. F. Bobadilla, J. A. Odriozola, S. Posada-Pérez, A. Poater, A. Comas-Vives and M. R. Axet, Catal. Sci. Technol., 2023, 13, 1425 DOI: 10.1039/D2CY02094G

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