Issue 4, 2020

Plasmonic hole ejection involved in plasmon-induced charge separation

Abstract

Since the finding of plasmon-induced charge separation (PICS) at the interface between a plasmonic metal nanoparticle and a semiconductor, which has been applied to photovoltaics including photodetectors, photocatalysis including water splitting, sensors and data storage in the visible/near-infrared ranges, injection of hot electrons (energetic electrons) into semiconductors has attracted attention almost exclusively. However, it has recently been found that behaviours of holes are also important. In this review, studies on the hot hole ejection from plasmonic nanoparticles are described comprehensively. Hole ejection from plasmonic nanoparticles on electron transport materials including n-type semiconductors allows oxidation reactions to take place at more positive potentials than those involved in a charge accumulation mechanism. Site-selective oxidation is also one of the characteristics of the hole ejection and is applied to photoinduced nanofabrication beyond the diffraction limit. Hole injection into hole transport materials including p-type semiconductors (HTMs) in solid-state cells, hole ejection through a HTM for stabilization of holes, hole ejection to a HTM for efficient hot electron ejection, voltage up-conversion by the use of hot carriers and electrochemically assisted hole ejection are also described.

Graphical abstract: Plasmonic hole ejection involved in plasmon-induced charge separation

Article information

Article type
Review Article
Submitted
09 Okt 2019
Accepted
27 Nov 2019
First published
28 Nov 2019

Nanoscale Horiz., 2020,5, 597-606

Plasmonic hole ejection involved in plasmon-induced charge separation

T. Tatsuma and H. Nishi, Nanoscale Horiz., 2020, 5, 597 DOI: 10.1039/C9NH00649D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements