Issue 46, 2019

Beyond liquid crystals: new research trends for mesogenic molecules in liquids

Abstract

With a view to understand the supramolecular assemblies that bring together certain molecules to form innovative functional materials with high-potential applications, the present review focuses on recent examples of molecular structures that are capable of establishing self-assemblies both in bulk and in solvents. This review demonstrates that appropriate rod- and V-shaped, disc-like and star-shaped molecules as well as high-molecular-weight compounds, either dendrimers or polymers, exhibit a dual ability. Intermolecular interactions that provide liquid crystalline order in bulk may also manifest in solution and this can lead to nanomaterials in the form of nanoaggregates. Through bottom-up approaches that involve the self-assembly of molecules driven by hydrogen bonding, π–π stacking, electrostatic or hydrophilic–hydrophobic interactions, appropriate molecules are able to induce a variety of thermotropic mesophases in bulk as well as aggregates with morphologies such as nanoparticles, nanofibers, nanorods or nanotubes in liquid media including systems in which solvents are immobilized and form gel materials. The aim of this work is to highlight the versatility of mesogenic molecules, opening the door to a wide number of possibilities, as well as to help this topic to enter into a more mature period.

Graphical abstract: Beyond liquid crystals: new research trends for mesogenic molecules in liquids

Article information

Article type
Review Article
Submitted
30 Jul 2019
Accepted
20 Okt 2019
First published
22 Okt 2019

J. Mater. Chem. C, 2019,7, 14454-14470

Beyond liquid crystals: new research trends for mesogenic molecules in liquids

M. Castillo-Vallés, A. Martínez-Bueno, R. Giménez, T. Sierra and M. B. Ros, J. Mater. Chem. C, 2019, 7, 14454 DOI: 10.1039/C9TC04179F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements