Issue 8, 2016

Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane

Abstract

Mesopore incorporation into ZSM-5 enhances the dispersion of Pd nanoparticles throughout the hierarchical framework, significantly accelerating m-cresol conversion relative to a conventional microporous ZSM-5, and dramatically increasing selectivity towards the desired methylcyclohexane deoxygenated product. Increasing the acid site density further promotes m-cresol conversion and methylcyclohexane selectivity through efficient dehydration of the intermediate methylcyclohexanol.

Graphical abstract: Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane

Supplementary files

Article information

Article type
Communication
Submitted
30 Nov 2015
Accepted
28 Dez 2015
First published
29 Dez 2015
This article is Open Access
Creative Commons BY license

Catal. Sci. Technol., 2016,6, 2560-2564

Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane

J. A. Hunns, M. Arroyo, A. F. Lee, J. M. Escola, D. Serrano and K. Wilson, Catal. Sci. Technol., 2016, 6, 2560 DOI: 10.1039/C5CY02072G

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