Accessing perfluoroalkyl nickel(II), (III), and (IV) complexes bearing a readily attached [C4F8] ligand

S. Yu; Y. Dudkina; H. Wang; K. V. Kholin; M. K. Kadirov; Y. H. Budnikova; D. A. Vicic

doi:10.1039/C5DT01771H

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Accessing perfluoroalkyl nickel(ii), (iii), and (iv) complexes bearing a readily attached [C₄F₈] ligand†

S. Yu,^a Y. Dudkina,^b H. Wang,^a K. V. Kholin,^b M. K. Kadirov,^b Y. H. Budnikova^b and D. A. Vicic*^a

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* Corresponding authors

^a Department of Chemistry, Lehigh University, 6 E. Packer Ave., Bethlehem, PA 18015, USA
E-mail: vicic@lehigh.edu

^b A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, 8, Arbuzov Str., 420088 Kazan, Russian Federation

Abstract

The [C₄F₈] ligand was shown to support well-defined terpyridyl nickel complexes in the +2 and +3 oxidation states. Notably, a cyclic voltammetry study of the nickel(III) species indicates that an additional oxidation is accessible, providing a family of related fluoroalkyl nickel complexes spanning the +2 to +4 oxidation states.

This article is part of the themed collection: Fluorine

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Article information

DOI: https://doi.org/10.1039/C5DT01771H
Article type: Communication
Submitted: 11 Mai 2015
Accepted: 05 Jun 2015
First published: 05 Jun 2015

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Dalton Trans., 2015,44, 19443-19446

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Accessing perfluoroalkyl nickel(II), (III), and (IV) complexes bearing a readily attached [C₄F₈] ligand

S. Yu, Y. Dudkina, H. Wang, K. V. Kholin, M. K. Kadirov, Y. H. Budnikova and D. A. Vicic, Dalton Trans., 2015, 44, 19443 DOI: 10.1039/C5DT01771H

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