Issue 25, 2015

C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation

Abstract

We reported a remote control glycosylation method using the picoloyl protecting group for 2-deoxy-β-glycosidic bond formation. The method is applicable to various 2-deoxythioglycosyl donors and the utility is illustrated by the synthesis of a deoxytrisaccharide component of landomycins.

Graphical abstract: C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation

Supplementary files

Article information

Article type
Communication
Submitted
27 Okt 2014
Accepted
27 Nov 2014
First published
27 Nov 2014

Chem. Commun., 2015,51, 5394-5397

Author version available

C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation

J. Ruei, P. Venukumar, A. B. Ingle and K. T. Mong, Chem. Commun., 2015, 51, 5394 DOI: 10.1039/C4CC08465A

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