Issue 4, 2013
From the journal:

Journal of Materials Chemistry A

The reaction between Nafion sulfonyl fluoride precursor membrane and 1,4-dimethylpiperazine does not yield reliable anion-exchange membranes†

Donna M. Hillman,a   Susan H. Stephens,a   Simon D. Poynton,a   Sam Murphy,a   Ai Lien Onga  and  John R. Varcoe*a  

* Corresponding authors

a Department of Chemistry, Faculty of Engineering and Physical Sciences, University of Surrey, Guildford GU2 7XH, UK
E-mail: j.varcoe@surrey.ac.uk
Tel: +44 (0)1483 686838

Abstract

Recent reports that the reaction between Nafion sulfonyl fluoride precursor and the cyclic diamine 1,4-dimethylpiperazine yields stable anion-exchange membranes appear to be premature. On aqueous work up, membranes with high cation-exchange capacities and zero anion-exchange capacities are produced.

Graphical abstract: The reaction between Nafion sulfonyl fluoride precursor membrane and 1,4-dimethylpiperazine does not yield reliable anion-exchange membranes

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Article information

DOI
https://doi.org/10.1039/C2TA00955B
Article type
Communication
Submitted
02 Nov 2012
Accepted
23 Nov 2012
First published
23 Nov 2012
This article is Open Access
Creative Commons BY license

J. Mater. Chem. A, 2013,1, 1018-1021

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The reaction between Nafion sulfonyl fluoride precursor membrane and 1,4-dimethylpiperazine does not yield reliable anion-exchange membranes

D. M. Hillman, S. H. Stephens, S. D. Poynton, S. Murphy, A. L. Ong and J. R. Varcoe, J. Mater. Chem. A, 2013, 1, 1018 DOI: 10.1039/C2TA00955B

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