Issue 18, 2011

New insights into the aggregation of silver pyrazolides using sterically hindered bidentate pyrazole ligands

Abstract

Recrystallisation of Ag[L1] (HL1 = 3{5}-[pyrid-2-yl]-5{3}-tert-butylpyrazole) in the presence of halide anions leads to two polymorphs of [Ag3(μ-Br)(μ-L1)2], which differ in their mode of supramolecular association, and the cluster [Ag10(μ-L1)8]Cl2. In contrast, Ag[L2] (HL2 = 3{5}-[isoquinol-1-yl]-5{3}-tert-butyl-pyrazole) crystallises as a cyclic tetrameric molecule.

Graphical abstract: New insights into the aggregation of silver pyrazolides using sterically hindered bidentate pyrazole ligands

Supplementary files

Article information

Article type
Communication
Submitted
04 Jan 2011
Accepted
15 Mrz 2011
First published
30 Mrz 2011

Chem. Commun., 2011,47, 5187-5189

New insights into the aggregation of silver pyrazolides using sterically hindered bidentate pyrazole ligands

J. J. Henkelis, C. A. Kilner and M. A. Halcrow, Chem. Commun., 2011, 47, 5187 DOI: 10.1039/C1CC00054C

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