Issue 29, 2009
From the journal:

Chemical Communications

Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality†‡

Tsuneomi Kawasaki,ab   Masako Shimizu,a   Daisuke Nishiyama,a   Masateru Ito,a   Hitomi Ozawaa  and  Kenso Soai*ab  

* Corresponding authors

a Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
E-mail: soai@rs.kagu.tus.ac.jp
Fax: +81 3 5261 4631
Tel: +81 3 5228 8261

b Research Institute of Science and Technology, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan

Abstract

Achiral meteoritic amino acids, glycine and α-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols.

Graphical abstract: Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B908754K
Article type
Communication
Submitted
05 Mai 2009
Accepted
08 Jun 2009
First published
24 Jun 2009
This article is Open Access

Chem. Commun., 2009, 4396-4398

Permissions

Request permissions

Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

T. Kawasaki, M. Shimizu, D. Nishiyama, M. Ito, H. Ozawa and K. Soai, Chem. Commun., 2009, 4396 DOI: 10.1039/B908754K

This is an Open Access article. The full version of this article can be posted on a website/blog, posted on an intranet, photocopied, emailed, distributed in a course pack or distributed in Continuing Medical Education (CME) materials provided that it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements