Issue 60, 2022
From the journal:

Chemical Communications

Photoresponsive proton conduction in Zr-based metal–organic frameworks using the photothermal effect†

Ming-Feng Qin,a   Chang-Yu Wang,a   Song-Song Bao ORCID logo *a  and  Li-Min Zheng ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Centre of Advanced Microstructures, Nanjing University, Nanjing, P. R. China
E-mail: lmzheng@nju.edu.cn, baososo@nju.edu.cn

Abstract

A highly stable and porous MOF [Zr2(H4TPPP)(OH/F)2]·xH2O (1) containing a metal-free porphyrin-phosphonate ligand is reported. It shows high proton conductivity of 1.2 × 10−3 S·cm−1 at 25 °C and 95% RH, a photothermal effect over a wide spectral range from UV-vis to NIR, and photo-enhanced and switchable proton conductivity.

Graphical abstract: Photoresponsive proton conduction in Zr-based metal–organic frameworks using the photothermal effect

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D2CC02470E
Article type
Communication
Submitted
02 Mai 2022
Accepted
28 Jun 2022
First published
28 Jun 2022

Chem. Commun., 2022,58, 8372-8375

Permissions

Request permissions

Photoresponsive proton conduction in Zr-based metal–organic frameworks using the photothermal effect

M. Qin, C. Wang, S. Bao and L. Zheng, Chem. Commun., 2022, 58, 8372 DOI: 10.1039/D2CC02470E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements