Issue 18, 2016

Synthesis of polyquinolines via an AA/BB-type aza-Diels–Alder polymerization reaction

Abstract

Polyquinolines have attracted attention as functional materials due to their excellent combination of optical, electrical, chemical, thermal, and mechanical properties. However, only a handful of synthetic routes for the preparation of these polymers have been established to date. Here, we demonstrate the preparation of polyquinolines via an AA/BB-type aza-Diels–Alder polymerization reaction. This approach requires only commercial starting materials and two straightforward synthetic steps to furnish the desired products in high yield. Overall, our modular and general route may afford new opportunities for the rational design and preparation of quinoline-based materials.

Graphical abstract: Synthesis of polyquinolines via an AA/BB-type aza-Diels–Alder polymerization reaction

Supplementary files

Article information

Article type
Paper
Submitted
26 Nov 2015
Accepted
21 Mrz 2016
First published
08 Apr 2016

J. Mater. Chem. C, 2016,4, 4060-4066

Synthesis of polyquinolines via an AA/BB-type aza-Diels–Alder polymerization reaction

M. J. Umerani, D. J. Dibble, A. G. Wardrip, A. Mazaheripour, E. Vargas, J. W. Ziller and A. A. Gorodetsky, J. Mater. Chem. C, 2016, 4, 4060 DOI: 10.1039/C5TC03974F

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