Issue 24, 2009
From the journal:

Chemical Communications

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes†‡

Takahiro Kawamoto,a   Sho Hirabayashi,a   Xun-Xiang Guo,a   Takahiro Nishimura*a  and  Tamio Hayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Japan
E-mail: tnishi@kuchem.kyoto-u.ac.jp, thayashi@kuchem.kyoto-u.ac.jp
Fax: +81 75 753 3983
Tel: +81 75 753 3988

Abstract

The rhodium-catalyzed intermolecular asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes gave chiral allylicphosphine oxides substituted with vinylether and thioether moieties in high yields with high enantioselectivities.

Graphical abstract: Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B900976K
Article type
Communication
Submitted
16 Jan 2009
Accepted
17 Feb 2009
First published
13 Mrz 2009

Chem. Commun., 2009, 3528-3530

Permissions

Request permissions

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

T. Kawamoto, S. Hirabayashi, X. Guo, T. Nishimura and T. Hayashi, Chem. Commun., 2009, 3528 DOI: 10.1039/B900976K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements