Rate constants of the reactions between dimethyl amine (DMA) and NO2 are accurately determined using the advanced multi-path canonical variational theory with a small-curvature tunneling correction.
H-abstraction reactions of amines play crucial roles in understanding their degeneration fates under both atmospheric and combustion conditions.
China is a global hotspot of nitrogen (N) emissions and N deposition, which has implications for the N dynamics of ecosystems and stimulates the production of nitrous oxide (N2O).
Thioamidato Co(III) complexes catalyze the chemoselective reduction of nitroarenes to anilines by CH3NHNH2. Suggested reaction mechanism includes coordination-induced activation of CH3NHNH2 and Co(I)/Co-hydride intermediates.
The formation and transformation of a highly stable reactant-complex significantly enhance the atmospheric persistence of α-endosulfan, particularly at elevated temperatures.