Issue 45, 2020

Squeezing Bi: PNP and P2N3 pincer complexes of bismuth

Abstract

We report the first application of a rigid P2N3 pincer ligand in p-block chemistry by preparing its bismuth complex. We also report the first example of bismuth complexes featuring a flexible PNP pincer ligand, which shows phase-dependent structural dynamics. Highly electrophilic, albeit thermally unstable, Bi(III) complexes of the PNP ligand were also prepared.

Graphical abstract: Squeezing Bi: PNP and P2N3 pincer complexes of bismuth

Supplementary files

Article information

Article type
Communication
Submitted
18 Apr 2020
Accepted
11 Mai 2020
First published
20 Mai 2020

Dalton Trans., 2020,49, 16072-16076

Squeezing Bi: PNP and P2N3 pincer complexes of bismuth

M. B. Kindervater, T. Hynes, K. M. Marczenko and S. S. Chitnis, Dalton Trans., 2020, 49, 16072 DOI: 10.1039/D0DT01413C

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