Issue 46, 2009

Iron-catalyzed addition of Grignard reagents to activated vinyl cyclopropanes

Abstract

A highly regioselective iron-catalyzed addition of branched primary, secondary or tertiary alkyl Grignard reagents to activated vinyl cyclopropanes is described, which likely proceeds by a direct addition mechanism as opposed to single electron transfer or an iron-allyl based process.

Graphical abstract: Iron-catalyzed addition of Grignard reagents to activated vinyl cyclopropanes

Supplementary files

Article information

Article type
Communication
Submitted
10 Sep 2009
Accepted
05 Okt 2009
First published
29 Okt 2009

Chem. Commun., 2009, 7116-7118

Iron-catalyzed addition of Grignard reagents to activated vinyl cyclopropanes

B. D. Sherry and A. Fürstner, Chem. Commun., 2009, 7116 DOI: 10.1039/B918818E

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