Issue 23, 2024

Self-assembly of a supramolecular spin-crossover tetrahedron

Abstract

A new mononuclear iron(II) SCO compound featuring H-bonding donor and acceptor units has been synthesized and exploited to produce a purely supramolecular switchable [Fe4] tetrahedron. Magnetic and crystallographic measurements evidence a singular magnetic behavior for each of the four Fe(II) centers of the generated architecture and underscore the potential of this strategy to develop novel SCO materials.

Graphical abstract: Self-assembly of a supramolecular spin-crossover tetrahedron

Supplementary files

Article information

Article type
Paper
Submitted
27 Feb 2024
Accepted
20 Mai 2024
First published
20 Mai 2024
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2024,53, 9792-9797

Self-assembly of a supramolecular spin-crossover tetrahedron

H. H. Nielsen, P. Vilariño, G. Rodríguez, F. Trepard, O. Roubeau, G. Aromí and D. Aguilà, Dalton Trans., 2024, 53, 9792 DOI: 10.1039/D4DT00578C

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