Modulating the Guest Binding Ability within Mixed-Coordination Geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ Cage Architectures

Abstract

Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bonding-accepting or -donating properties are reported. They showed stimulus-responsive dis- and reassembly, while guest binding was found to be dependent on the complimentary properties of the guest to the host in terms of charge, size and H bonding properties.

Supplementary files

Article information

Article type
Communication
Submitted
19 Jul 2024
Accepted
30 Aug 2024
First published
30 Aug 2024

Chem. Commun., 2024, Accepted Manuscript

Modulating the Guest Binding Ability within Mixed-Coordination Geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ Cage Architectures

H. Gearing, T. Soehnel, P. G. Young, L. Lisboa, L. J. Wright, J. D. Crowley and C. Hartinger, Chem. Commun., 2024, Accepted Manuscript , DOI: 10.1039/D4CC03613A

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