Issue 21, 2023

Polyoxometalate-based frameworks for photocatalysis and photothermal catalysis

Abstract

Polyoxometalate-based frameworks (POM-based frameworks) are extended structures assembled from metal–oxide cluster units and organic frameworks that simultaneously possess the virtues of POMs and frameworks. They have been attracting immense attention because of their diverse architectures and charming topologies and also due to their probable application prospects in the areas of catalysis, separation, and energy storage. In this review, the recent progress in POM-based frameworks including POM-based metal organic frameworks (PMOFs), POM-based covalent organic frameworks (PCOFs), and POM-based supramolecular frameworks (PSFs) is systematically summarized. The design and construction of a POM-based framework and its application in photocatalysis and photothermal catalysis are introduced, respectively. Finally, our brief outlooks on the current challenges and future development of POM-based frameworks for photocatalysis and photothermal catalysis are provided.

Graphical abstract: Polyoxometalate-based frameworks for photocatalysis and photothermal catalysis

Article information

Article type
Review Article
Submitted
14 Mär 2023
Accepted
21 Apr 2023
First published
24 Apr 2023

Nanoscale, 2023,15, 9242-9255

Polyoxometalate-based frameworks for photocatalysis and photothermal catalysis

X. Chen, H. Wu, X. Shi and L. Wu, Nanoscale, 2023, 15, 9242 DOI: 10.1039/D3NR01176C

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