Issue 60, 2022

Photoresponsive proton conduction in Zr-based metal–organic frameworks using the photothermal effect

Abstract

A highly stable and porous MOF [Zr2(H4TPPP)(OH/F)2xH2O (1) containing a metal-free porphyrin-phosphonate ligand is reported. It shows high proton conductivity of 1.2 × 10−3 S·cm−1 at 25 °C and 95% RH, a photothermal effect over a wide spectral range from UV-vis to NIR, and photo-enhanced and switchable proton conductivity.

Graphical abstract: Photoresponsive proton conduction in Zr-based metal–organic frameworks using the photothermal effect

Supplementary files

Article information

Article type
Communication
Submitted
02 Mai 2022
Accepted
28 Jun 2022
First published
28 Jun 2022

Chem. Commun., 2022,58, 8372-8375

Photoresponsive proton conduction in Zr-based metal–organic frameworks using the photothermal effect

M. Qin, C. Wang, S. Bao and L. Zheng, Chem. Commun., 2022, 58, 8372 DOI: 10.1039/D2CC02470E

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